公开(公告)号：US09199942B2

公开(公告)日：2015-12-01

申请号：US14666826

申请日：2015-03-24

Applicant: Dow AgroSciences LLC

Inventor： Qiang Yang ,  Beth Lorsbach ,  Gregory T. Whiteker ,  Carl DeAmicis ,  Joseck M. Muhuhi

IPC: C07D231/40 ,  A01N43/56 ,  C07D401/04 ,  C07D231/38

CPC classification number: A01N43/56 ,  C07D231/38 ,  C07D231/40 ,  C07D401/04

Abstract: The present application provides processes for making pesticidal compounds and compounds useful both as pesticides and in the making of pesticidal compounds.

公开(公告)号：US09102655B2

公开(公告)日：2015-08-11

申请号：US14517600

申请日：2014-10-17

Applicant: Dow AgroSciences LLC

Inventor： Qiang Yang ,  Beth Lorsbach ,  Gregory T. Whiteker ,  Gary Roth ,  Carl DeAmicis ,  Thomas P. Clark ,  Kaitlyn Gray ,  Belgin Canturk ,  Elisabeth J. Kane ,  Yu Zhang ,  Joseck M. Muhuhi

IPC: C07D401/04 ,  C07D231/40 ,  A01N43/56

CPC classification number: C07D231/38 ,  A01N43/56 ,  C07C321/14 ,  C07C321/16 ,  C07C2601/02 ,  C07D231/40 ,  C07D401/04

Abstract: The present application provides processes for making pesticidal compounds and compounds useful both as pesticides and in the making of pesticidal compounds.

Abstract translation: 本申请提供了制备杀虫化合物和化合物作为农药和制备杀虫化合物的方法。

公开(公告)号：US20150191428A1

公开(公告)日：2015-07-09

申请号：US14667109

申请日：2015-03-24

Applicant: Dow AgroSciences LLC

Inventor： James M. Renga ,  Yang Cheng ,  Joseck M. Muhuhi ,  David E. Podhorez ,  Gary A. Roth ,  Scott P. West ,  Gregory T. Whiteker ,  Yuanming Zhu

IPC: C07D213/55

CPC classification number: C07D213/55 ,  C07D213/78 ,  C07D213/803 ,  C07D213/807

Abstract: Provided herein are fluoropicolinoyl fluorides and processes for their preparation. In some embodiments, provided herein is a process for the preparation of 5-fluoro-6-aryl-picolinoyl fluorides from chloropicolinoyl chlorides.

Abstract translation: 本文提供氟吡唑啉基氟化物及其制备方法。 在一些实施方案中，本文提供了一种从氯吡啶酰氯制备5-氟-6-芳基 - 吡啶甲酰基氟化物的方法。

公开(公告)号：US09044017B2

公开(公告)日：2015-06-02

申请号：US14517328

申请日：2014-10-17

Applicant: Dow AgroSciences LLC

Inventor： Qiang Yang ,  Beth Lorsbach ,  Gregory T. Whiteker ,  Carl DeAmicis ,  Joseck M. Muhuhi

IPC: C07D231/40 ,  A01N43/56 ,  C07D401/04

CPC classification number: A01N43/56 ,  C07D231/38 ,  C07D231/40 ,  C07D401/04

Abstract: The present application provides processes for making pesticidal compounds and compounds useful both as pesticides and in the making of pesticidal compounds.

公开(公告)号：US08993772B2

公开(公告)日：2015-03-31

申请号：US14222912

申请日：2014-03-24

Applicant: Dow AgroSciences LLC

Inventor： Yuanming Zhu ,  Gregory T. Whiteker ,  James M. Renga ,  Kim E. Arndt ,  Gary Roth ,  David E. Podhorez ,  Scott P. West ,  Yang Cheng

IPC: C07D213/803 ,  C07D213/81 ,  C07D213/78 ,  C07D213/79

CPC classification number: C07D213/81 ,  C07D213/78 ,  C07D213/79 ,  C07D213/803

Abstract: 4-Amino-5-fluoro-3-halo-6-(substituted)picolinates are conveniently prepared from 4,5,6-trichloropicolinonitrile by a series of steps involving fluorine exchange, amination, halogen exchange, halogenation, nitrile hydrolysis, esterification, and transition metal assisted coupling.

Abstract translation: 通过一系列涉及氟交换，胺化，卤素交换，卤化，腈水解，酯化等步骤的方法，可以方便地从4,5,6-三氯吡啶腈制备4-氨基-5-氟-3-卤代-6-（取代的） 和过渡金属辅助耦合。

公开(公告)号：US20140274688A1

公开(公告)日：2014-09-18

申请号：US14208457

申请日：2014-03-13

Applicant: DOW AGROSCIENCES LLC

Inventor： Lindsey G. Fischer ,  Erich W. Baum ,  Gary D. Crouse ,  Carl DeAmicis ,  Beth Lorsbach ,  Jeff Petkus ,  Thomas C. Sparks ,  Gregory T. Whiteker

IPC: A01N47/36 ,  A01N47/34 ,  A01N25/00 ,  A01N47/12 ,  A01N53/00 ,  A01N25/32 ,  A01N55/08 ,  A01N43/653

CPC classification number: C07D417/12 ,  A01N25/00 ,  A01N25/32 ,  A01N43/653 ,  A01N47/12 ,  A01N47/34 ,  A01N47/36 ,  A01N47/40 ,  A01N47/42 ,  A01N53/00 ,  A01N55/08 ,  C07C211/45 ,  C07C267/00 ,  C07C335/02 ,  C07C335/16 ,  C07C335/26 ,  C07D249/08 ,  C07D277/54 ,  C07D285/01 ,  C07D403/10 ,  C07D405/10 ,  C07F5/04

Abstract: This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Nematoda, Arthropoda, and/or Mollusca, processes to produce such molecules and intermediates used in such processes, compositions containing such molecules, and processes of using such molecules against such pests. These molecules may be used, for example, as nematicides, acaricides, insecticides, miticides, and/or molluscicides. This document discloses molecules having the following formula (“Formula One”).

Abstract translation: 本公开涉及具有杀虫效力的分子领域，用于在叶螨（Phyla Nematoda），节肢动物（Arthropoda）和/或软体动物（Mollusca）中的害虫，产生这种分子的方法和用于该方法的中间体，含有这些分子的组合物，以及使用这种分子对这种害虫 。 这些分子可以用作例如杀线虫剂，杀螨剂，杀虫剂，杀螨剂和/或杀软体动物剂。 该文献公开了具有下式（“一级方程式”）的分子。

公开(公告)号：US20140031558A1

公开(公告)日：2014-01-30

申请号：US13949053

申请日：2013-07-23

Applicant: Dow AgroSciences LLC

Inventor： James M. Renga ,  Yang Cheng ,  Joseck M. Muhuhi ,  David E. Podhorez ,  Gary A. Roth ,  Scott P. West ,  Gregory T. Whiteker ,  Yuanming Zhu

IPC: C07D213/78 ,  C07D213/807

CPC classification number: C07D213/55 ,  C07D213/78 ,  C07D213/803 ,  C07D213/807

Abstract: Provided herein are fluoropicolinoyl fluorides and processes for their preparation. In some embodiments, provided herein is a process for the preparation of 5-fluoro-6-aryl-picolinoyl fluorides from chloropicolinoyl chlorides.

Abstract translation: 本文提供氟吡唑啉基氟化物及其制备方法。 在一些实施方案中，本文提供了一种从氯吡啶酰氯制备5-氟-6-芳基 - 吡啶甲酰基氟化物的方法。

公开(公告)号：US10035772B2

公开(公告)日：2018-07-31

申请号：US15642728

申请日：2017-07-06

Applicant: Dow AgroSciences LLC

Inventor： Gregory T. Whiteker ,  Nakyen Choy ,  Peter Borromeo ,  Nicholas R. Babij

IPC: C07D213/81 ,  C07C271/22 ,  C07C229/08

CPC classification number: C07D213/81 ,  C07C227/18 ,  C07C229/08 ,  C07C269/06 ,  C07C271/22

Abstract: A fungicidal 4-methoxy-3-acetyloxypicolinamide may be conveniently prepared in processes that include the coupling together of 4-methoxy-3-acetyloxypicolinic acid or 4-methoxy-3-hydroxypicolinic acid with a key 2-aminopropanoate ester derived from a 1,1-bis(4-fluorophenyl)propane-1,2-diol.

公开(公告)号：US20180009756A1

公开(公告)日：2018-01-11

申请号：US15642728

申请日：2017-07-06

Applicant: Dow AgroSciences LLC

Inventor： Gregory T. Whiteker ,  Nakyen Choy ,  Peter Borromeo ,  Nicholas R. Babij

IPC: C07D213/81 ,  C07C271/22 ,  C07C229/08

CPC classification number: C07D213/81 ,  C07C227/18 ,  C07C229/08 ,  C07C271/22

Abstract: A fungicidal 4-methoxy-3-acetyloxypicolinamide may be conveniently prepared in processes that include the coupling together of 4-methoxy-3-acetyloxypicolinic acid or 4-methoxy-3-hydroxypicolinic acid with a key 2-aminopropanoate ester derived from a 1,1-bis(4-fluorophenyl)propane-1,2-diol.

公开(公告)号：US20170174582A1

公开(公告)日：2017-06-22

申请号：US15129282

申请日：2015-03-27

Applicant: Dow Global Technologies LLC ,  Dow AgroSciences LLC

Inventor： Patrick S. Hanley ,  Gregory T. Whiteker ,  Matthias S. Ober ,  William J. Kruper, Jr. ,  Arkady L. Krasovskiy

IPC: C07C1/32 ,  C07B37/04 ,  C07D213/16 ,  C07C22/04 ,  C07C233/00 ,  C07C211/45 ,  C07C22/08 ,  C07C15/14 ,  C07D263/54

CPC classification number: C07C1/322 ,  C07B37/04 ,  C07C1/321 ,  C07C15/14 ,  C07C17/263 ,  C07C22/04 ,  C07C22/08 ,  C07C41/30 ,  C07C45/70 ,  C07C67/343 ,  C07C211/45 ,  C07C231/12 ,  C07C233/00 ,  C07C253/30 ,  C07C2531/22 ,  C07C2531/24 ,  C07C2531/28 ,  C07D213/127 ,  C07D213/16 ,  C07D263/54 ,  C07C233/65 ,  C07C255/50 ,  C07C43/205 ,  C07C49/784 ,  C07C69/76

Abstract: In one aspect, there is provided a method of coupling a first aromatic compound having a fluorosulfonate substituent to a second aromatic compound having a boron-containing substituent. In another aspect, there is provided a method of coupling a first aromatic compound having a hydroxyl substituent to a second aromatic compound having a boron-containing substituent in a one-pot reaction.