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    Methyl-5-(trimethoxy silyl propylthio) norbornane-2,3-dicarboxylic anhydride
    14.
    发明授权
    Methyl-5-(trimethoxy silyl propylthio) norbornane-2,3-dicarboxylic anhydride 失效
    甲基-5-（三甲氧基甲硅烷基丙硫基）降冰片烷-2,3-二羧酸酐

    公开(公告)号：US3899515A

    公开(公告)日：1975-08-12

    申请号：US42332273

    申请日：1973-12-10

    Applicant: DOW CORNING

    Inventor： SPEIER JOHN L ,  LEGROW GARY E

    IPC: C07F7/18 ,  C08G77/28 ,  C07D307/89

    CPC classification number: C08G77/28 ,  C07F7/182 ,  C07F7/1836

    Abstract: ORGANOSILICON CARBOXYLIC ACID ANHYDRIDES ARE PREPARED BY REACTING MERCAPTOSILANES OR SILOXANES WITH UNSATURATED CARBOXYLIC ACID ANHYDRIDES IN THE PRESENCE OF FREE RADICAL GENERATORS. FOR EXAMPLE, GAMMA-MERCAPTOPROPYL TRIMETHOXYSILANE IS ADDED TO NADIC METHYL ANHYDRIDE UNDER THE INFLUENCE OF AZO-BIS-ISOBUTYRONITRILE TO GIVE

    Abstract translation: 有机硅羧酸酐通过巯基硅烷或硅氧烷与不饱和羧酸酐在自由基发生剂存在下反应制备。 例如，在偶氮二异丁腈的影响下，将γ-巯基丙基三甲氧基硅烷加入到无水甲基酸酐中，得到

    Novel mercaptoaryl silicon compounds
    17.
    发明授权
    Novel mercaptoaryl silicon compounds 失效
    新颖的MERCAPTOARYL硅化合物

    公开(公告)号：US3465015A

    公开(公告)日：1969-09-02

    申请号：US3465015D

    申请日：1966-12-16

    Applicant: DOW CORNING

    Inventor： SPEIER JOHN L

    IPC: C07F7/08 ,  C07F7/18 ,  C08G77/28 ,  C07F7/02 ,  C03C17/30 ,  C07D1/00

    CPC classification number: C07F7/0858 ,  C07F7/0856 ,  C07F7/182 ,  C07F7/1896 ,  C08G77/28

    Abstract: 1,217,848. Glass cloth coating with silicon compound. DOW CORNING CORP. 13 Dec., 1967 [16 Dec., 1966], No. 56541/67. Heading B2E. [Also in Division C3] Glass cloth, particularly for use in laminates, can be coated with a mercaptoaryl silicon compound of the formula: where R is a monovalent hydrocarbon radical free of aliphatic unsaturation, R' is an arylene, alkarylene or alkylene arylene radical, X is halogen, OH, alkoxy, aryloxy or acyloxy, m is 0 to 2, n is 1 to 3 and m + n cannot exceed 3.

    Organosilyl alcohols
    19.
    发明授权
    Organosilyl alcohols 失效
    有机硅烷醇

    公开(公告)号：US2629727A

    公开(公告)日：1953-02-24

    申请号：US17607150

    申请日：1950-07-26

    Applicant: DOW CORNING

    Inventor： SPEIER JOHN L

    IPC: C07F7/08

    CPC classification number: C07F7/0818

    Abstract: The invention comprises organo-silicon compounds of the general formula RaSi[(CH2)6OH]4-a wherein a is 2 or 3, b is 3, 4 or 5 and R represents an alkyl or phenyl radical, and a process for preparing the above compounds by reacting a compound of the general formula R3SiO (CH2)bCl, wherein R represents an alkyl or phenyl radical and b has a value of from 3 to 5, with sodium, lithium or magnesium and hydrolysing the reaction product R3Si(CH2)bOM to give compounds where a is 3, or by reacting a compound of the general formula R1aSi[O (CH2)bCl]4-a, wherein R1 represents a phenyl or alkyl radical, a is 2 or 3 and b has a value of from 3 to 5, a silane of the general formula R3SiCl wherein R represents an alkyl or phenyl radical, and sodium, lithium or magnesium and hydrolysing the reaction product R1aSiO(CH2)bSiR3 to give compounds where a is 2 or 3 (and a hexaorganodisiloxane). The former reaction is preferably carried out at temperatures of 30 DEG C. and above when sodium and lithium is used, and above 55 DEG C. when magnesium is used. The group R may be the methyl, ethyl, octadecyl or phenyl radical. In the examples the following compounds are prepared by the first reaction referred to above: bis-(3-propanol - 1) dimethylsilane, 3 - trimethylsilylpropanol - 1, 4 - trimethylsilylbutanol - 1, 5 - trimethylsilylpentanol - 1, and 5 - phenyldimethylsilylpentanol-1, and the following compounds are prepared by the second reaction referred to above: 3-ethyldimethylsilylpropanol-1 and 5-ethyldimethylsilylpentanol-1 (3-ethyldimethylsilylpropoxy - 1 - ethyldimethyl silane and 5 - ethyldimethylsilylpentoxy - 1 - ethyldimethylsilane are formed as intermediate compounds respectively, and diethyltetramethyldisiloxane is also formed after the hydrolysis in each case). Specification 692,660 is referred to.

    Abstract translation: 本发明包括通式为RaSi [（CH 2）6 OH] 4-a的有机硅化合物，其中a为2或3，b为3,4或5，R为烷基或苯基，以及制备 通过使通式为R 3 SiO（CH 2）b Cl的化合物（其中R表示烷基或苯基）和b具有3至5的值与钠，锂或镁反应，并水解反应产物R 3 Si（CH 2） 得到化合物，其中a为3，或通过使通式R 1a a [O（CH 2）b Cl] 4-a的化合物与其中R 1表示苯基或烷基，a为2或3并且b的值为 3至5的通式为R 3 SiCl的硅烷，其中R表示烷基或苯基，以及钠，锂或镁，并水解反应产物R 1aSiO（CH 2）b SiR 3，得到其中a为2或3的化合物（和六有机二硅烷 ）。 前者的反应优选在使用钠和锂的情况下在30℃以上的温度下进行，当使用镁时，优选在55℃以上。 基团R可以是甲基，乙基，十八烷基或苯基。 在实施例中，通过上述第一反应制备以下化合物：双 - （3-丙醇-1）二甲基硅烷，3-三甲基甲硅烷基丙醇-1,4-三甲基甲硅烷基丁醇-1,5-三甲基甲硅烷基戊醇-1和5-苯基二甲基甲硅烷基戊醇 - 1，通过上述第二反应制备以下化合物：分别形成3-乙基二甲基甲硅烷基丙醇-1和5-乙基二甲基甲硅烷基戊醇-1（3-乙基二甲基甲硅烷基丙氧基-1-乙基二甲基硅烷和5-乙基二甲基甲硅烷基戊氧基-1-乙基二甲基硅烷作为中间体化合物 ，并且在每种情况下水解后也形成二乙基四甲基二硅氧烷）。 参考说明书692,660。

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