公开(公告)号：US20220073658A1

公开(公告)日：2022-03-10

申请号：US17419266

申请日：2019-12-27

Applicant: Dow Global Technologies LLC

Inventor： Lixin Sun ,  Endre Szuromi ,  Edmund M. Carnahan

IPC: C08F210/14 ,  C08F210/06 ,  C08F210/02 ,  C08F210/08 ,  C08F2/38

Abstract: The present disclosure relates to novel telechelic polyolefins of the formula (I) and processes for preparing the same. In at least one aspect, the telechelic polyolefins of the formula (I) comprise unsaturations at both termini.

公开(公告)号：US11174329B2

公开(公告)日：2021-11-16

申请号：US16338232

申请日：2017-09-29

Applicant: Dow Global Technologies LLC

Inventor： Lixin Sun ,  Zhe Zhou ,  Jaclyn Murphy ,  Edmund M. Carnahan

IPC: C08F4/10 ,  C08F4/52 ,  C08F110/02 ,  C08F12/34 ,  C07C13/465

Abstract: The present disclosure relates to a multi- or dual-headed composition having the formula (I) or (II). The present disclosure also relates to a process for preparing the multi- or dual-headed composition having the formula (I) or (II), the process including combining 1,2,4-trivinylcyclochexane, an organometallic compound, and a catalyst precursor. The present disclosure further relates to use of the composition having the formula (I) or (II) in olefin polymerization.

公开(公告)号：US20210017311A1

公开(公告)日：2021-01-21

申请号：US16982503

申请日：2019-03-18

Applicant: Dow Silicones Corporation ,  Rohm and Haas Electronic Materials LLC ,  Dow Global Technologies LLC

Inventor： Jongwook Choi ,  David D. Devore ,  Robert David Grigg ,  Phillip D. Hustad ,  Jaclyn Murphy ,  Mark E. Ondari ,  Jordan Reddel ,  Lixin Sun

IPC: C08F210/16 ,  C08F8/42 ,  C08F8/12 ,  C08F4/659

Abstract: The present disclosure is directed to a silicon-terminated telechelic polyolefin composition comprising a compound of formula (I). Embodiments related to a process for preparing the silicon-terminated telechelic polyolefin composition comprising a compound of formula (I), the process comprising combining starting materials comprising (A) a silicon-terminated organo-metal compound and (B) a silicon-based functionalization agent, thereby obtaining a product comprising the silicon-terminated telechelic polyolefin composition. In further embodiments, the starting materials of the process may further comprise (C) a nitrogen containing heterocycle. In further embodiments, the starting materials of the process may further comprise (D) a solvent.

公开(公告)号：US20210002315A1

公开(公告)日：2021-01-07

申请号：US16982520

申请日：2019-03-18

Applicant: Dow Global Technologies LLC

Inventor： Lixin Sun ,  Phillip D. Hustad

IPC: C07F19/00 ,  C08F110/02

Abstract: The present disclosure is directed to a silicon-terminated organo-metal composition comprising a compound of formula (I). Embodiments relate to a process for preparing the silicon-terminated organo-metal composition comprising the compound of formula (I), the process comprising combining starting materials comprising (A) a vinyl-terminated silicon-based compound and (B) a chain shuttling agent, thereby obtaining a product comprising the silicon-terminated organo-metal composition. In further embodiments, the starting materials of the process may further comprise (C) a solvent.

公开(公告)号：US20210002308A1

公开(公告)日：2021-01-07

申请号：US16982516

申请日：2019-03-18

Applicant: Dow Global Technologies LLC

Inventor： Lixin Sun ,  Phillip D. Hustad

IPC: C07F7/08 ,  C07F3/02 ,  C07F3/04 ,  C07F3/06

Abstract: The present disclosure is directed to a silicon-terminated organo-metal composition comprising a compound of formula (I). Embodiments relate to a process for preparing the silicon-terminated organo-metal composition comprising the compound of formula (I), the process comprising combining starting materials comprising (A) a vinyl-terminated silicon-based compound, (B) a chain shuttling agent, (C) a procatalyst, and (D) an activator, thereby obtaining a product comprising the silicon-terminated organo-metal composition. In further embodiments, the starting materials of the process may further comprise (E) a solvent and/or (F) a scavenger.

公开(公告)号：US20190225719A1

公开(公告)日：2019-07-25

申请号：US16338232

申请日：2017-09-29

Applicant: Dow Global Technologies LLC

Inventor： Lixin Sun ,  Zhe Zhou ,  Jaclyn Murphy ,  Edmund M. Carnahan

IPC: C08F110/02 ,  C07C13/465

Abstract: The present disclosure relates to a multi- or dual-headed composition having the formula (I) or (II). The present disclosure also relates to a process for preparing the multi- or dual-headed composition having the formula (I) or (II), the process including combining 1,2,4-trivinylcyclochexane, an organometallic compound, and a catalyst precursor. The present disclosure further relates to use of the composition having the formula (I) or (II) in olefin polymerization.

公开(公告)号：US20180201696A1

公开(公告)日：2018-07-19

申请号：US15923780

申请日：2018-03-16

Applicant: Dow Global Technologies LLC

Inventor： Lixin Sun ,  Daniel D. VanderLende

IPC: C08F4/52 ,  C07F5/02 ,  C08F10/00

Abstract: A method for preparing ammonium tetrakis(pentafluorophenyl)borate salt comprising reacting a secondary amine with an aldehyde to form an iminium ion; hydrogenating the iminium ion by reaction with a reducing agent to form a tertiary amine; reacting the tertiary amine with a mineral acid to form an amine salt; and reacting the amine salt with K[B(C6F5)4], Li[B(C6F5)4], or combinations thereof to form an ammonium tetrakis(pentafluorophenyl)borate salt, wherein the secondary amine is derived from a non-animal source and the aldehyde has seven or more carbon atoms; wherein the ammonium tetrakis(pentafluorophenyl)borate salt is characterized by a solubility at 25° C. in hexane, cyclohexane or methylcyclohexane of at least 10 weight percent; and wherein the tertiary amine has a molecular weight of at least 450 g/mole is provided.

公开(公告)号：US20180105626A1

公开(公告)日：2018-04-19

申请号：US15553356

申请日：2016-03-01

Applicant: Dow Global Technologies LLC

Inventor： Philip P. Fontaine ,  Lixin Sun ,  Colin Li Pi Shan ,  Juan C. Tuberquia ,  Susan G. Brown ,  Edward O. Madenjian ,  Gregory J. Brennan

IPC: C08F210/18 ,  C08F236/20 ,  C08F4/64 ,  C08F2/01 ,  C08L23/16

CPC classification number: C08F210/18 ,  C08F2/01 ,  C08F4/64189 ,  C08F4/64193 ,  C08F4/64196 ,  C08F4/659 ,  C08F4/65908 ,  C08F4/65912 ,  C08F236/20 ,  C08F2500/01 ,  C08L23/16 ,  C08F2/001 ,  C08F210/06 ,  C08F2500/03 ,  C08F2500/17 ,  C08F2500/25

Abstract: The invention provides a process to form a polymer composition comprising at least one ethylene/α-olefin/non-conjugated polyene interpolymer, and wherein the polymer composition has at least the following properties: a) a Mw/V0.1 ratio greater than, or equal to, 1.80 (g/mol)/(Pa·s); said process comprising polymerizing one or more mixture(s) comprising ethylene, an α-olefin and a non-conjugated polyene in the presence of a catalyst system comprising a metal-ligand complex of Formula (I), as described herein.

公开(公告)号：US12098160B2

公开(公告)日：2024-09-24

申请号：US17419272

申请日：2019-12-27

Applicant: Dow Global Technologies LLC

Inventor： Lixin Sun ,  Endre Szuromi ,  Edmund M. Carnahan

IPC: C07F5/06 ,  C07F3/06 ,  C08F2/38 ,  C08F210/06 ,  C08F210/16

CPC classification number: C07F5/062 ,  C07F3/06 ,  C08F2/38 ,  C08F210/06 ,  C08F210/16

Abstract: Embodiments relate to organometallic compositions that are useful for chain transfer during olefin polymerization. Such compositions are chain transfer agents comprising an organoaluminum compound of the formula Al(CH2CH(Y2)A2)3 and an organozinc compound of the formula Zn(CH2CH(Y2)A2)2.

公开(公告)号：US11732064B2

公开(公告)日：2023-08-22

申请号：US15764554

申请日：2016-09-28

Applicant: Dow Global Technologies LLC

Inventor： Lixin Sun ,  David D. Devore

IPC: C08F4/52 ,  C08F4/64 ,  C08F8/00 ,  C08F8/32 ,  C07C209/66 ,  C08F110/14 ,  C08F8/30 ,  C08F210/16 ,  C08F8/28 ,  C07C213/02 ,  C08F4/659

CPC classification number: C08F8/32 ,  C07C209/66 ,  C07C213/02 ,  C08F8/28 ,  C08F8/30 ,  C08F110/14 ,  C08F210/16 ,  C08F4/65908 ,  C08F4/65912 ,  C08F2410/01 ,  C08F2800/20 ,  C08F2810/40 ,  C08F210/16 ,  C08F210/14 ,  C08F10/00 ,  C08F4/659 ,  C08F8/32 ,  C08F8/28 ,  C08F110/14 ,  C08F8/32 ,  C08F8/28 ,  C08F210/16 ,  C08F8/30 ,  C08F110/14 ,  C08F8/30 ,  C08F210/16 ,  C07C209/66 ,  C07C211/27 ,  C07C213/02 ,  C07C217/58

Abstract: The present disclosure relates to a one-pot process for synthesizing functional compounds or functional polymers by reacting an aldehyde with an alkyl-zinc or polymeryl-zinc composition in the presence of a specific Lewis acid, wherein the reaction is rapid and facile at high temperatures.