公开(公告)号：US20150321119A1

公开(公告)日：2015-11-12

申请号：US14317782

申请日：2014-06-27

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： Kenny Parker ,  Mesfin Janka ,  Ashfaq Shaikh ,  Lee Partin

IPC: B01D11/04

CPC classification number: B01J27/32 ,  B01D11/04 ,  B01D11/0446 ,  B01D17/00 ,  B01J10/002 ,  B01J23/8892 ,  B01J27/128 ,  B01J35/12 ,  B01J38/12 ,  C07D307/68 ,  Y02P20/584

Abstract: Disclosed is an oxidation process to produce a crude carboxylic acid product carboxylic acid product. The process comprises oxidizing a feed stream comprising at least one oxidizable compound to generate a crude carboxylic acid slurry comprising furan-2,5-dicarboxylic acid (FDCA) and compositions thereof. Also disclosed is a process to produce a dry purified carboxylic acid product by utilizing various purification methods on the crude carboxylic acid.

公开(公告)号：US09169229B2

公开(公告)日：2015-10-27

申请号：US14536387

申请日：2014-11-07

Applicant: Eastman Chemical Company

Inventor： Kenny Randolph Parker ,  Ashfaq Shaikh ,  Lee Reynolds Parton ,  Mesfin Ejerssa Janka

IPC: C07D307/68 ,  C07D307/46

CPC classification number: C07D307/68 ,  C07D307/46

Abstract: A process to produce a purified dimethyl-furan-2,5-dicarboxylate (DMFD) by feeding furan dicarboxylic acid and methanol to an esterification zone to generate a crude diester composition, and purifying the crude diester composition with a physical separation process followed by crystallization, solid liquid separation, and optionally drying to produce a purified DMFD composition. A portion of the stream generated by solid liquid separation can be dissolved and subjected to crystallization and solid liquid separation repeatedly. The process is useful to produce a purified DMFD composition having a low b*, at least 98 wt. % DAFD solids, and a low concentration of 5-(methoxycarbonyl)furan-2-carboxylic acid (MCFC) and methyl 5-formylfuran-2-carboxylate (MFFC).

Abstract translation: 通过将呋喃二甲酸和甲醇加入到酯化区以产生粗制二酯组合物，并通过物理分离方法纯化粗二酯组合物，然后结晶，从而生产纯化的二甲基 - 呋喃-2,5-二羧酸二甲酯（DMFD） ，固液分离，任选地干燥以制备纯化的DMFD组合物。 通过固液分离产生的一部分流可以溶解并重复进行结晶和固液分离。 该方法可用于生产具有低b *，至少98重量％的纯化的DMFD组合物。 ％DAFD固体，低浓度的5-（甲氧羰基）呋喃-2-羧酸（MCFC）和5-甲酰呋喃-2-羧酸甲酯（MFFC）。

公开(公告)号：US20150011783A1

公开(公告)日：2015-01-08

申请号：US14495785

申请日：2014-09-24

Applicant: Eastman Chemical Company

Inventor： Mesfin Janka ,  David Lange ,  Michael Morrow ,  Bradford Bowers ,  Kenny Parker ,  Ashfaq Shaikh ,  Lee Partin ,  Jason Jenkins ,  Paula Moody ,  Thomas Shanks ,  Charles Sumner

IPC: C07D307/68

CPC classification number: C07D307/68

Abstract: Disclosed is an oxidation process to produce a crude carboxylic acid product carboxylic acid product. The process comprises oxidizing a feed stream comprising at least one oxidizable compound to generate a crude carboxylic acid slurry comprising furan-2,5-dicarboxylic acid (FDCA) and compositions thereof. Also disclosed is a process to produce a dry purified carboxylic acid product by utilizing various purification methods on the crude carboxylic acid.

Abstract translation: 公开了一种生产粗制羧酸产物羧酸产物的氧化方法。 该方法包括将包含至少一种可氧化化合物的进料流氧化以产生包含呋喃-2,5-二羧酸（FDCA）及其组合物的粗羧酸浆料。 还公开了通过在粗羧酸上利用各种纯化方法来生产干燥的纯化羧酸产物的方法。

公开(公告)号：US11027219B2

公开(公告)日：2021-06-08

申请号：US16552313

申请日：2019-08-27

Applicant: Eastman Chemical Company

Inventor： Kenny Parker ,  Mesfin Janka ,  Ashfaq Shaikh ,  Lee Partin

IPC: B01D11/04 ,  B01D1/00 ,  B01D33/06 ,  B01D3/00 ,  B01D3/40 ,  B01J27/128 ,  B01J27/32 ,  C07D307/68 ,  B01J38/12 ,  B01J35/12

Abstract: Disclosed is an oxidation process to produce a crude carboxylic acid product carboxylic acid product. The process comprises oxidizing a feed stream comprising at least one oxidizable compound to generate a crude carboxylic acid slurry comprising furan-2,5-dicarboxylic acid (FDCA) and compositions thereof. Also disclosed is a process to produce a dry purified carboxylic acid product by utilizing various purification methods on the crude carboxylic acid.

公开(公告)号：US20190381421A1

公开(公告)日：2019-12-19

申请号：US16552313

申请日：2019-08-27

Applicant: Eastman Chemical Company

Inventor： Kenny Parker ,  Mesfin Janka ,  Ashfaq Shaikh ,  Lee Partin

IPC: B01D11/04 ,  B01D1/00 ,  B01D3/00 ,  B01D3/40 ,  B01J27/128 ,  B01J27/32 ,  C07D307/68 ,  B01D33/06

Abstract: Disclosed is an oxidation process to produce a crude carboxylic acid product carboxylic acid product. The process comprises oxidizing a feed stream comprising at least one oxidizable compound to generate a crude carboxylic acid slurry comprising furan-2,5-dicarboxylic acid (FDCA) and compositions thereof. Also disclosed is a process to produce a dry purified carboxylic acid product by utilizing various purification methods on the crude carboxylic acid.

公开(公告)号：US09604202B2

公开(公告)日：2017-03-28

申请号：US14317782

申请日：2014-06-27

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： Kenny Parker ,  Mesfin Janka ,  Ashfaq Shaikh ,  Lee Partin

IPC: C07D307/34 ,  B01J27/32 ,  B01D11/04 ,  B01D17/00 ,  C07D307/68

CPC classification number: B01J27/32 ,  B01D11/04 ,  B01D11/0446 ,  B01D17/00 ,  B01J10/002 ,  B01J23/8892 ,  B01J27/128 ,  B01J35/12 ,  B01J38/12 ,  C07D307/68 ,  Y02P20/584

Abstract: Disclosed is an oxidation process to produce a crude carboxylic acid product carboxylic acid product. The process comprises oxidizing a feed stream comprising at least one oxidizable compound to generate a crude carboxylic acid slurry comprising furan-2,5-dicarboxylic acid (FDCA) and compositions thereof. Also disclosed is a process to produce a dry purified carboxylic acid product by utilizing various purification methods on the crude carboxylic acid.

公开(公告)号：US09573120B2

公开(公告)日：2017-02-21

申请号：US14317588

申请日：2014-06-27

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： Kenny Parker ,  Mesfin Janka ,  Ashfaq Shaikh ,  Lee Partin

IPC: C07D307/68 ,  B01D17/00 ,  B01D11/04 ,  B01J27/32

CPC classification number: B01J27/32 ,  B01D11/04 ,  B01D11/0446 ,  B01D17/00 ,  B01J10/002 ,  B01J23/8892 ,  B01J27/128 ,  B01J35/12 ,  B01J38/12 ,  C07D307/68 ,  Y02P20/584

Abstract: Disclosed is an oxidation process to produce a crude carboxylic acid product carboxylic acid product. The process comprises oxidizing a feed stream comprising at least one oxidizable compound to generate a crude carboxylic acid slurry comprising furan-2,5-dicarboxylic acid (FDCA) and compositions thereof. Also disclosed is a process to produce a dry purified carboxylic acid product by utilizing various purification methods on the crude carboxylic acid.

Abstract translation: 公开了一种生产粗制羧酸产物羧酸产物的氧化方法。 该方法包括将包含至少一种可氧化化合物的进料流氧化以产生包含呋喃-2,5-二羧酸（FDCA）及其组合物的粗羧酸浆料。 还公开了通过在粗羧酸上利用各种纯化方法来生产干燥的纯化羧酸产物的方法。

公开(公告)号：US09504994B2

公开(公告)日：2016-11-29

申请号：US14317875

申请日：2014-06-27

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： Mesfin Janka ,  Kenny Parker ,  Ashfaq Shaikh ,  Lee Partin

IPC: B01J27/32 ,  B01D11/04 ,  B01D17/00 ,  C07D307/68

CPC classification number: B01J27/32 ,  B01D11/04 ,  B01D11/0446 ,  B01D17/00 ,  B01J10/002 ,  B01J23/8892 ,  B01J27/128 ,  B01J35/12 ,  B01J38/12 ,  C07D307/68 ,  Y02P20/584

Abstract: Disclosed is an oxidation process to produce a crude carboxylic acid product carboxylic acid product. The process comprises oxidizing a feed stream comprising at least one oxidizable compound to generate a crude carboxylic acid slurry comprising furan-2,5-dicarboxylic acid (FDCA) and compositions thereof. Also disclosed is a process to produce a dry purified carboxylic acid product by utilizing various purification methods on the crude carboxylic acid.

Abstract translation: 公开了一种生产粗制羧酸产物羧酸产物的氧化方法。 该方法包括将包含至少一种可氧化化合物的进料流氧化以产生包含呋喃-2,5-二羧酸（FDCA）及其组合物的粗羧酸浆料。 还公开了通过在粗羧酸上利用各种纯化方法来生产干燥的纯化羧酸产物的方法。

公开(公告)号：US09199958B2

公开(公告)日：2015-12-01

申请号：US14525624

申请日：2014-10-28

Applicant: Eastman Chemical Company

Inventor： Mesfin Ejerssa Janka ,  David Lange ,  Michael C. Morrow ,  Bradford Russell Bowers ,  Kenny Randolph Parker ,  Ashfaq Shaikh ,  Lee Reynolds Partin ,  Charles Sumner

IPC: C07D307/68

CPC classification number: C07D307/68

Abstract: Disclosed is an oxidation process to produce a crude carboxylic acid product carboxylic acid product. The process comprises oxidizing a feed stream comprising at least one oxidizable compound to generate a crude carboxylic acid slurry comprising furan-2,5-dicarboxylic acid (FDCA) and compositions thereof. Also disclosed is a process to produce a dry purified carboxylic acid product by utilizing various purification methods on the crude carboxylic acid.

Abstract translation: 公开了一种生产粗制羧酸产物羧酸产物的氧化方法。 该方法包括将包含至少一种可氧化化合物的进料流氧化以产生包含呋喃-2,5-二羧酸（FDCA）及其组合物的粗羧酸浆料。 还公开了通过在粗羧酸上利用各种纯化方法来生产干燥的纯化羧酸产物的方法。

公开(公告)号：US20150322028A1

公开(公告)日：2015-11-12

申请号：US14317692

申请日：2014-06-27

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： Mesfin Janka ,  Kenny Parker ,  Ashfaq Shaikh ,  Lee Partin

IPC: C07D307/68

CPC classification number: B01J27/32 ,  B01D11/04 ,  B01D11/0446 ,  B01D17/00 ,  B01J10/002 ,  B01J23/8892 ,  B01J27/128 ,  B01J35/12 ,  B01J38/12 ,  C07D307/68 ,  Y02P20/584

Abstract: Disclosed is an oxidation process to produce a crude carboxylic acid product carboxylic acid product. The process comprises oxidizing a feed stream comprising at least one oxidizable compound to generate a crude carboxylic acid slurry comprising furan-2,5-dicarboxylic acid (FDCA) and compositions thereof. Also disclosed is a process to produce a dry purified carboxylic acid product by utilizing various purification methods on the crude carboxylic acid.