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公开(公告)号:US20240182383A1
公开(公告)日:2024-06-06
申请号:US18411055
申请日:2024-01-12
Applicant: FUJIFILM Corporation
Inventor: Kenji SHIROKANE , Yuji YOSHIMITSU , Naoka HAMADA
IPC: C07B59/00
CPC classification number: C07B59/008 , C07B2200/05
Abstract: There are provided a compound having at least two phosphor moieties and a structure represented by General Formula (I), and a labeled biological substance.
In the formula, X1 to X3 represent —O—, —S—, >NR1, or >CR2R3. R1 to R3 represent a hydrogen atom or a substituent. La and Lb represents a single bond or a divalent linking group. n is an integer of 2 or more.
However, at least one among R1 to R3, which are contained in a structure parenthesized in ( )n, La, and Lb includes -(L-O)gRE, where -(L-O)gRE in each of these groups is not bonded to at least any one of a phosphor or a biological substance.
L represents an alkylene group, RE represents a hydrogen atom or an alkyl group, and g is 1 to 24.
* represents a bonding site.-
公开(公告)号:US20240173437A1
公开(公告)日:2024-05-30
申请号:US18411057
申请日:2024-01-12
Applicant: FUJIFILM Corporation
Inventor: Kenji SHIROKANE , Yuji Yoshimitsu , Naoka Hamada , Yoshinori Kanazawa , Hiroaki Tanaka
CPC classification number: A61K49/0015 , A61K47/545 , A61K47/548 , A61K47/65 , A61K47/6873 , A61K51/1096 , G01N33/582
Abstract: There are provided a compound having two or more phosphor moieties of which light absorption characteristics are equivalent to each other, in which the phosphor moieties adjacent to each other are each linked through a group including a structure represented by General Formula (I), and a labeled biological substance using the compound.
In the formula, X1 to X3 represent —O—, —S—, >NR1, or >CR2R3.
R1 to R3 represent a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heteroaryl group, an acyl group, —NR8R9, —OR10, or an anionic group.
R1 to R10 represent a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an acyl group, an aryl group, a heteroaryl group, or an anionic group.
n is an integer of 2 or more.
* represents a bonding site.-
公开(公告)号:US20220283170A1
公开(公告)日:2022-09-08
申请号:US17742378
申请日:2022-05-11
Applicant: FUJIFILM Corporation
Inventor: Kousuke WATANABE , Yoshinori KANAZAWA , Ryo FUJIWARA , Kenji SHIROKANE , Hiroaki TANAKA , Yuki ARAI , Kazuoki KOMIYAMA
Abstract: Provided are any one of the following compounds and a fluorescently labeled biological substance having this compound. R1 to R27, L11, L12, and X+ represent a specific group, and at least one of R1 to R4 represents a substituted alkyl group.
In a case where at least one of R1 to R4 is an alkyl group having a carboxy group or a substituent capable of being bonded to a biological substance, at least one of R11 to R27 is an alkyl group or an aryl group, or at least one of R1 to R4, which does not correspond to the alkyl group having a carboxy group or an alkyl group having a substituent capable of being bonded to a biological substance, is an alkyl group having a sulfoalkyl group through a single bond or a linking group.
The total of n1 to n4 is an integer of 3 or more, and m=n1+n2+n3+n4−1 is satisfied.
At least one of R1 to R4, R13, L11 or L12 in Formula (1) and at least one of R1 to R4, R24, L11, or L12 in Formula (2) have a specific substituent.-
公开(公告)号:US20220143998A1
公开(公告)日:2022-05-12
申请号:US17582222
申请日:2022-01-24
Applicant: FUJIFILM Corporation
Inventor: Takeshi MIYATO , Michio ARAI , Yusuke FUJII , Kenji SHIROKANE
IPC: B41M5/00 , C09D11/30 , C09D11/104 , C09D11/107 , B41M7/00
Abstract: Provided is an image recording method including applying a pretreatment liquid containing water and a resin X and an ink containing water and a colorant onto a resin base material A which has a specific distortion rate and to which a tension is applied, to obtain an image, heating the image to a temperature Td and drying the image, and cooling the image to a temperature Tr, in which σtotal calculated by Equation (1) is 40 kgf/cm2 or less. E(Td) represents an elastic modulus of the resin X at the temperature Td, ε(Td) represents an expansion coefficient of the resin base material A under specific conditions, E(T) represents an elastic modulus of the resin X at a temperature T of the image in the cooling, αr(T) represents a linear expansion coefficient of the resin X at the temperature T, and αs(T) represents a linear expansion coefficient of the resin base material A under specific conditions. σ total = σ dry + σ cool Equation ( 1 ) σ dry = E ( T d ) ɛ ( T d ) Equation ( 2 ) σ cool = ∫ T r T d E ( T ) ( α r ( T ) - α s ( T ) ) dT Equation ( 3 )
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公开(公告)号:US20200376877A1
公开(公告)日:2020-12-03
申请号:US16997944
申请日:2020-08-20
Applicant: FUJIFILM CORPORATION
Inventor: Kenji SHIROKANE , Yusuke FUJII
Abstract: Provided are a pretreatment liquid for recording an image on an impermeable base material with an aqueous ink, the pretreatment liquid including an aqueous medium, a resin a having a glass transition temperature of lower than 25° C., and particles of a resin b having a glass transition temperature of 25° C. or higher; an ink set; a base material for image recording; an image recorded material; a method of producing a base material for image recording; and an image recording method.
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公开(公告)号:US20180144877A1
公开(公告)日:2018-05-24
申请号:US15874951
申请日:2018-01-19
Applicant: FUJIFILM Corporation
Inventor: Hirotaka SATOU , Naoyuki HANAKI , Toshihiro ISE , Kenji SHIROKANE
IPC: H01G9/20 , H01L51/42 , H01L51/44 , C07D513/04 , H01L51/00
CPC classification number: H01G9/2018 , C07D513/04 , H01G9/0029 , H01G9/2009 , H01L51/0003 , H01L51/0067 , H01L51/0068 , H01L51/0069 , H01L51/0071 , H01L51/0073 , H01L51/0074 , H01L51/4273 , H01L51/442 , Y02E10/542 , Y02E10/549
Abstract: Provided is a photoelectric conversion element including at least a first electrode that includes a conductive support, a photosensitive layer that contains a light absorbing agent, a hole transport layer that contains an organic hole transporting material, and a second electrode. At least one of the photosensitive layer or the hole transport layer is provided on the conductive support to constitute the first electrode in combination with the conductive support. The photosensitive layer includes at least a compound having a perovskite-type crystal structure that includes a cation of an element of Group 1 in the periodic table or a cationic organic group A, a cation of a metal atom M other than elements of Group 1 in the periodic table, and an anion of an anionic atom or atomic group X as the light absorbing agent. The hole transport layer includes at least a compound represented by the following Formula 1 as the organic hole transporting material.
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公开(公告)号:US20170330694A1
公开(公告)日:2017-11-16
申请号:US15658995
申请日:2017-07-25
Applicant: FUJIFILM Corporation
Inventor: Hirotaka SATOU , Kenji SHIROKANE , Toshihiro ISE , Katsumi KOBAYASHI
CPC classification number: H01G9/2059 , H01G9/2027 , H01L51/0047 , H01L51/0094 , H01L51/422 , Y02E10/549 , Y02P70/521
Abstract: Provided are a photoelectric conversion element including a first electrode having a photosensitive layer including a light absorber on a conductive support and a second electrode facing the first electrode, in which the light absorber includes a compound having a perovskite-type crystal structure including organic cations, cations of a metallic atom other than elements belonging to Group I of the periodic table, and anions, and at least some of the organic cations constituting the compound are organic cations having a silyl group and a solar cell using the photoelectric conversion element.Also provided is a composition containing a compound represented by Formula (1a) and a halogenated metal. R13Si-L-NR23Hal Formula (1a) In the formula, R1, R2, and L are specific groups. Hal represents a halogen atom.
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公开(公告)号:US20220186056A1
公开(公告)日:2022-06-16
申请号:US17582775
申请日:2022-01-24
Applicant: FUJIFILM Corporation
Inventor: Kenji SHIROKANE , Ayato SATO
IPC: C09D11/107 , C09D11/033 , C09D11/037 , C09D11/30 , B41M5/00
Abstract: Provided are an ink for an impermeable base material, including an aqueous medium and resin particles, in which a resin of the resin particles has a glass transition temperature of −40° C. or higher and 85° C. or lower, the resin has at least one selected from the group consisting of a unit (1) to a unit (3), and at least one of an acid group or a salt of the acid group, an acid value of the resin is 0.10 mmol/g or greater and 2.65 mmol/g or less, and a proportion of a solvent having a boiling point of 250° C. or higher in the aqueous medium is 3% by mass or less, and an image recording method. R2 represents a hydrogen atom or a C1 to C4 alkyl group, A2 represents —NH— or —N(L4-Y4)—, L2 and L4 represent a divalent group or a single bond, L3 represents a divalent group, and Y2 to Y4 represent a monovalent group.
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公开(公告)号:US20200343451A1
公开(公告)日:2020-10-29
申请号:US16924003
申请日:2020-07-08
Applicant: FUJIFILM Corporation , The University of Tokyo
Inventor: Yukio TANI , Kenji SHIROKANE , Tetsuya WATANABE , Toshihiro OKAMOTO , Junichi TAKEYA
IPC: H01L51/00 , C09D5/24 , C09D165/00 , C08G61/12 , C08F220/68
Abstract: Provided are an organic thin film transistor element comprising an organic semiconductor layer containing a specific polymer which has a repeating unit including a structure represented by a specific formula, an organic semiconductor film suitable as the organic semiconductor layer and a method of manufacturing the same, and a polymer and a composition suitable as a constituent material of the organic semiconductor film.
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公开(公告)号:US20200035419A1
公开(公告)日:2020-01-30
申请号:US16590400
申请日:2019-10-02
Applicant: FUJIFILM Corporation
Inventor: Hirotaka SATO , Kenji SHIROKANE , Kimiatsu NOMURA
Abstract: A photoelectric conversion element includes a first electrode that has a photosensitive layer containing a light absorbing agent on a conductive support; and a second electrode that is opposite to the first electrode, in which the light absorbing agent contains a perovskite compound, and a compound represented by Formula (A-0), (G)p-L, Formula (A-0) in the formula, G represents a group or a salt such as —P(═O)(ORa)2 and —P(═O)(O−Ya+)2; Ra represents a hydrogen atom or a substituent; Ya represents a counter salt; p is an integer of 1 or more; and L represents an aliphatic hydrocarbon group not having an amino group.
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