公开(公告)号：US10460879B2

公开(公告)日：2019-10-29

申请号：US14713341

申请日：2015-05-15

Applicant: FUJIFILM Corporation

Inventor： Kousuke Watanabe ,  Yukio Tani ,  Kouitsu Sasaki ,  Hirotaka Satou ,  Kazuhiro Tsuna ,  Katsumi Kobayashi

IPC: H01G9/20 ,  C07D401/14 ,  C07D409/14 ,  C07D495/04 ,  C07D213/55 ,  C07D213/57 ,  C09B57/10 ,  C07F15/00 ,  H01L51/00 ,  C09B19/00 ,  C09B21/00 ,  C09B23/01 ,  C09B23/10 ,  C09B57/00 ,  C09B69/00

Abstract: A photoelectric conversion element, having a photoconductor layer containing semiconductor fine particles carrying a metal complex dye of Formula (I); a metal complex dye, a dye solution, a dye-adsorbed electrode, a dye-sensitized solar cell, and a method for producing the solar cell: M(LA)(LD)(LX)mX·(CI)mY  Formula (I) M represents a metal ion, LA represents a ligand of Formula (AL), LD represents a bidentate or tridentate ligand, at least one of coordinating atoms being an anion; LX represents a monodentate ligand; CI represents a counter ion; mX is 0 or 1; mY is 0 to 3; Rings A to C represent a heterocycle; Z1 and Z2 represent a carbon or nitrogen atom; Anc1 to Anc3 represent an acidic group; X1 to X3 represent a single bond or linking group; R1 to R3 represent a substituent; l1, l3, l2, m1, m3, m2, n1, n2, and n3 each are an integer.

公开(公告)号：US09947482B2

公开(公告)日：2018-04-17

申请号：US14879822

申请日：2015-10-09

Applicant: FUJIFILM Corporation

Inventor： Kohsuke Watanabe ,  Hirotaka Sato ,  Yukio Tani ,  Ryo Fujiwara ,  Kazuhiro Tsuna ,  Katsumi Kobayashi

IPC: H01G9/20 ,  C07F15/00 ,  C09B57/10 ,  H01L51/00 ,  C09B57/00

CPC classification number: H01G9/2059 ,  C07F15/0053 ,  C09B57/008 ,  C09B57/10 ,  H01G9/2031 ,  H01L51/0086 ,  Y02E10/542 ,  Y02E10/549

Abstract: A photoelectric conversion element has a conductive support, a photoreceptor layer containing an electrolyte, a charge carrier layer containing an electrolyte and a counter electrode, and the photoreceptor layer has semiconductor particles on which a metal complex dye represented by Formula (I) is carried. M1(LA)(LD)(Z1).CI  Formula (I) M1 represents a metal atom; Z1 represents a monodentate ligand; LA represents a tridentate ligand represented by Formula (AL-1); LD represents a bidentate ligand represented by Formula (DL-1); and CI represents a counterion necessary for neutralizing the charge.

公开(公告)号：US11785845B2

公开(公告)日：2023-10-10

申请号：US17503449

申请日：2021-10-18

Applicant: FUJIFILM Corporation ,  The University of Tokyo

Inventor： Koki Nakamura ,  Hiroki Sugiura ,  Yukio Tani ,  Tetsuya Matsushita ,  Tetsuya Watanabe ,  Junichi Takeya ,  Toshihiro Okamoto

IPC: H01B1/00 ,  C09D7/20 ,  H10K85/60 ,  C07D471/22 ,  C09D5/24 ,  H01B1/12 ,  H10K10/46

CPC classification number: H10K85/6572 ,  C07D471/22 ,  C09D5/24 ,  C09D7/20 ,  H01B1/121 ,  H10K10/466

Abstract: An object of the present invention is to provide a composition capable of manufacturing an organic thin film transistor having excellent carrier mobility even under low temperature conditions. The composition of the present invention contains a compound represented by Formula (1) and an alcohol represented by Formula (S1).

公开(公告)号：US10256048B2

公开(公告)日：2019-04-09

申请号：US15817413

申请日：2017-11-20

Applicant: FUJIFILM Corporation ,  Sharp Kabushiki Kaisha

Inventor： Yukio Tani ,  Katsumi Kobayashi ,  Ryohsuke Yamanaka ,  Atsushi Fukui ,  Norio Murofushi

IPC: H01G9/20 ,  C09B57/10 ,  H01L51/00

Abstract: Provided are a photoelectric conversion element and a dye sensitized solar cell having a supporting substrate, a conductive layer, a power generating layer having a porous semiconductor layer onto which a metal complex dye represented by Formula (1) is adsorbed, a porous insulating layer, and a counter electrode conductive layer, in which the layers are laminated in this order on the supporting substrate, and voids that each of the power generating layer, the porous insulating layer, and the counter electrode conductive layer has are filled with an electrolyte. R represents a hydrogen atom, an alkyl group, or an aryl group. G represents a group represented by any one of Formulae (G-1) to (G-4). A1 to A3 each represent a hydrogen atom, a carboxyl group, or a salt thereof. At least one of A1 to A3 is a carboxyl group or a salt thereof. X1 and X2 each represent —O—, —S—, and others. Ra represents an alkyl group and the like. Rb to Re each represent a hydrogen atom or a substituent. na represents 1 to 3. (G-1) to (G-4) are bonded to a pyridine ring in the portion of *.

公开(公告)号：US09564274B2

公开(公告)日：2017-02-07

申请号：US14301796

申请日：2014-06-11

Applicant: FUJIFILM Corporation

Inventor： Yukio Tani ,  Katsumi Kobayashi ,  Kimiatsu Nomura

IPC: H01G9/20 ,  C07D213/79 ,  C07D401/04 ,  C07D409/14 ,  C09B57/10

CPC classification number: H01G9/2059 ,  C07D213/79 ,  C07D401/04 ,  C07D409/14 ,  C09B57/10 ,  Y02E10/542

Abstract: A photoelectric conversion element, having: an electrically-conductive support; a photoconductor layer having a semiconductor fine-particle layer adsorbed a dye; a charge transfer layer containing an electrolyte; and a counter electrode; which are provided on one side of the support in this order, in which the dye has at least one terdentate ligand having at least one acidic group; at least one ligand coordinating to a metal atom M has an sp2 carbon atom; a cyclic group binds to the sp2 carbon atom; a specific substituent R is substituted at an atom of α- or β-position to the atom of the cyclic group directly binding to the sp2 carbon atom; and with the metal atom M, an atom G1 of the α- or β-position, and an atom G2 of the substituent R, an angle θ (∠MG1G2) is 150° or less.

Abstract translation: 一种光电转换元件，具有：导电支撑体; 具有吸附染料的半导体细粒层的感光体层; 含有电解质的电荷转移层; 和对电极; 其中所述染料具有至少一个具有至少一个酸性基团的特定配位体; 与金属原子M配位的至少一个配体具有sp2碳原子; 环状基团与sp2碳原子结合; 特定取代基R在α-或β-位的原子被直接与sp 2碳原子结合的环状基团的原子取代; 并且与金属原子M，α-或β-位的原子G1和取代基R的原子G2，角度θ（∠MG1G2）为150°以下。

公开(公告)号：US09424998B2

公开(公告)日：2016-08-23

申请号：US14136995

申请日：2013-12-20

Applicant: FUJIFILM Corporation

Inventor： Katsumi Kobayashi ,  Keizo Kimura ,  Tatsuya Susuki ,  Hirotaka Satou ,  Yukio Tani

IPC: C07D219/06 ,  C07D223/28 ,  C07D279/20 ,  C07D279/22 ,  C07D409/04 ,  C07D409/14 ,  C07D407/04 ,  C07D407/14 ,  C07D403/04 ,  C07D403/14 ,  C07D421/04 ,  C07D421/14 ,  H01G9/20 ,  C09B23/01 ,  C09B23/04 ,  C09B23/10 ,  H01M14/00

CPC classification number: H01G9/2059 ,  C09B23/0091 ,  C09B23/04 ,  C09B23/102 ,  H01M14/005

Abstract: A dye, having a structure represented by formula (1A): wherein A represents a group of atoms necessary for forming a ring together with the carbon-nitrogen bond; at least one of Y1A and Y2A represents an acidic group, in which when they each represent an acidic group, they may be the same as or different from each other, or when only one of them represents an acidic group, the other represents an electron-withdrawing group; D represents a group to give a dye; n represents an integer of 1 or greater; L represents a single bond or a divalent linking group; and Y3A represents an acidic group.

Abstract translation: 具有由式（1A）表示的结构的染料：其中A表示与碳 - 氮键一起形成环所需的一组原子; Y1A和Y2A中的至少一个表示酸性基团，当它们各自表示酸性基团时，它们可以彼此相同或不同，或者当其中仅一个表示酸性基团时，另一个表示电子 牵引组 D表示给出染料的基团; n表示1或更大的整数; L表示单键或二价连接基团; Y 3 A表示酸性基团。