摘要:
The invention relates to surface-modified pearlescent pigments, the pearlescent pigments being provided on the surface with at least one organic phosphorus compound of the general formula (I) R1R2P(O)(OR3) (I) and/or of the general formula (II) R1P(O)(OR3)(OR4) (II) where R1 and R2 independently of one another are hydrogen or an organic radical having 1 to 30 carbon atoms, with the proviso that R1 and R2 are not simultaneously hydrogen, R3 and R4 independently of one another are H or alkyl having 1-10 carbon atoms. The invention further relates to a process for preparing these pearlescent pigments and also to their use.
摘要翻译:本发明涉及表面改性珠光颜料,表面上提供珠光颜料与至少一种通式(I)R 1 R 2 P(O)(OR 3)(I)和/或通式(I)的有机磷化合物 II)R1P(O)(OR3)(OR4)(II)其中R1和R2彼此独立地是氢或具有1至30个碳原子的有机基团,条件是R1和R2不同时为氢,R3和 R 4彼此独立地是H或具有1-10个碳原子的烷基。 本发明还涉及一种制备这些珠光颜料的方法及其用途。
摘要:
The invention relates to platelet-shaped pearlescent pigments that are coated with at least one mixed inorganic/organic layer for improving their application properties, and of these, particularly their mechanical properties, and to methods for the production thereof and to the use thereof. The said mixed inorganic/organic layer comprises at least one at least partially crosslinked inorganic metal-oxide component and an organic component. The organic component is at least one organic oligomer and/or polymer, which is covalently bonded, at least in part, to the inorganic network via network formers, wherein the coating comprises at least one mixed inorganic/organic layer, which mixed layer comprises, at least in part, an inorganic network having one or more inorganic oxide component(s) and at least one organic component, the organic component being, at least in part, an organic oligomer and/or polymer covalently bonded, at least in part, to the inorganic network via one or more organic network formers.The invention also relates to a method for the production of such pearlescent pigments.
摘要:
Multilayer pearlescent pigments with a silver interference color, based on platelet-shaped transparent substrates with an optically active coating, where the optically active coating includes at least a) a high-index layer A having a refractive index n≧1.8 b) a low-index layer B having a refractive index n
摘要翻译:具有银干涉色的多层珠光颜料,基于具有光学活性涂层的片状透明基底,其中光学活性涂层至少包括a)折射率n≥1.8b的高折射率层A) 具有折射率n <1.8c的折射率层B)具有折射率n≥1.8的高折射率层C,以及d)任选的外部保护层D.多层珠光颜料具有来自该层的珠光颜料D10,D50,D90 体积平均尺寸分布函数的累积频率分布,跨度&Dgr; D为0.7-1.4,跨度&Dgr; D根据公式Dgr计算; D =(D90-D10)/ D50。 本发明还涉及一种生产这些多层珠光颜料的方法,以及它们的用途。
摘要:
The invention relates to effect pigments comprising artificial platelet-shaped substrates which have at least one optically active coating, where the effect pigments have a volume-averaged cumulative undersize distribution curve with the characteristic numbers D10, D50 and D90, said cumulative undersize distribution curve having a span ΔD of 0.7-1.4, and the span ΔD being calculated in accordance with formula (I): ΔD=(D90−D10)/D50 (I), and the average thickness of the artificial platelet-shaped substrates being 500 nm to 2000 nm.
摘要翻译:本发明涉及包含具有至少一种光学活性涂层的人造血小板形基底的效果颜料,其中效果颜料具有特征数D10,D50和D90的体积平均累积分布分布曲线,所述累积分布分布曲线具有 D = D90(D90-D10)/ D50(I),平均厚度为0.7-1.4,跨度&Dgr; D根据式(I)计算: 形状的基底为500nm至2000nm。
摘要:
The invention relates to a pearlescent pigment comprising a metal oxide-containing, platelet-shaped substrate and having a first and a second protective layer, wherein the metal oxide has a refractive index greater than 1.8, and in which the first protective layer comprises cerium oxide and/or hydrated cerium oxide and/or cerium hydroxide, the second protective layer consists substantially, preferably completely, of SiO2, wherein the second protective layer is disposed on top of the first protective layer, and between the first and second protective layers there can be disposed metal oxide layers which differ from cerium oxide and/or hydrated cerium oxide and/or cerium hydroxide and SiO2, wherein the second protective layer has an organochemical aftercoat and the organochemical aftercoat comprises at least one silane bonded to the second protective layer by means of at least one oxygen atom, said α-silane having the formula —O(4−n−m)—Si(—R1)m(—CH2—Y)n (I), in which 1≦n+m≦3; m=0 to 2; n=1 to 3 and R1 is a hydrogen atom or an Si—C-bonded C1-C20-hydrocarbon radical or a C1-C15-hydrocarbonoxy radical, in which in each case one or more methylene units not adjacent to one another can be replaced by the groups —O—, —CO—, —COO—, —OCO—, or —OCOO—, —S—, or —NRx— and in which one or more methine units not adjacent to one another can be replaced by the groups —N═, —N═N—, or —P═, wherein R1 can independently be the same or different, Rx can be a hydrogen atom or a linear, branched and/or cyclic C1-C15-hydrocarbon radical or aryl radical, and Y is a functional binding group reactive with a binder system.
摘要翻译:本发明涉及包含含金属氧化物的片状基材并具有第一和第二保护层的珠光颜料,其中金属氧化物的折射率大于1.8,其中第一保护层包含氧化铈 和/或水合氧化铈和/或氢氧化铈,所述第二保护层基本上优选完全由SiO 2组成,其中所述第二保护层设置在所述第一保护层的顶部上,并且在所述第一和第二保护层之间可以 设置与氧化铈和/或水合氧化铈和/或氢氧化铈和SiO 2不同的金属氧化物层,其中第二保护层具有有机化学后涂层,有机化学后涂层包含通过装置结合到第二保护层的至少一个硅烷 的至少一个氧原子,所述α-硅烷具有式-O(4-nm)-Si(-R1)m(-CH2-Y)n(I),其中1 <= n + m <= 3 ; m = 0〜2; n = 1〜3,R 1为氢原子或Si-C键合的C 1 -C 20烃基或C 1 -C 15烃氧基,其中在各种情况下,一个或多个彼此不相邻的亚甲基可以是 被-O - , - CO - , - COO-,-OCO-或-OCOO-,-S-或-NRx-基团取代,并且其中不相邻的一个或多个次甲基单元可以被 基团-N-,-NN-或-P-,其中R 1可以独立地相同或不同,R x可以是氢原子或直链,支链和/或环状C 1 -C 15 - 烃基或芳基, Y是与粘合剂体系反应的功能性结合基团。
摘要:
Multilayer pearlescent pigments comprising platelet-shaped transparent substrates provided with an optically active coating, where the optically active coating includes at least a) an absorbing high-index layer A having a refractive index n≧1.8 b) a low-index layer B having a refractive index n
摘要:
Multilayer pearlescent pigments comprising platelet-shaped transparent substrates provided with an optically active coating, where the coating includes at least (a) a nonabsorbing high-index layer A having a refractive index n≧1.8, (b) a low-index layer B having a refractive index n
摘要翻译:多层珠光颜料包括具有光学活性涂层的片状透明基材,其中涂层至少包含(a)折射率n≥1.8的非吸收性高折射率层A,(b)低折射率层B具有 折射率n <1.8,(c)折射率n≥1.8的非吸收性高折射率层C,以及(d)任选的至少一个外保护层D,其中颜料具有体积平均值的累积频率分布 尺寸分布函数,具有指数D10,D50,D90和跨度&Dgr; D在0.7-1.4的范围内,跨度&Dgr; D根据公式(I)&Dgr计算; D =(D90-D10)/ D50(I)。 本发明进一步涉及一种生产这些多层珠光颜料的方法,以及它们的用途。
摘要:
Multilayer pearlescent pigments based on platelet-shaped transparent substrates with an optically active coating, where the optically active coating includes at least a) a nonabsorbing high-index layer A having a refractive index n≧1.8, b) a low-index layer B having a refractive index n 150 nm, c) an absorbing high-index layer C having a refractive index n≧1.8 and also, d) optionally an outer protective layer D, wherein the multilayer pearlescent pigments have a cumulative frequency distribution of the volume-averaged size distribution function, with the indices D10, D50, D90 and a span ΔD of 0.7-1.4, the span ΔD being calculated in accordance with the formula ΔD=(D90−D10)/D50. The disclosure further relates to a method for producing these multilayer pigments, and to their use.
摘要:
Glass particles colored with at least one colorant, where the colored glass particles are glass platelets with an average diameter of 1 to 500 μm and the colorants comprise or consist of at least one of metallic nanoparticles and metal oxides. The glass platelets are planar and the colorants are present in a concentration from 1% to 55% by weight, based on the total weight of the colored glass platelets. The disclosure further relates to a method for producing the colored glass particles and to the use thereof.
摘要:
Pearlescent pigments including a largely transparent platelet-shaped substrate having a density ρS and at least one optically active coating having a density ρM, the substrate having an average size d50 of 3 to 8 μm and an average height hS of 40 to 110 nm. The disclosure further relates to a method for producing the pearlescent pigments, and also to the use thereof.