METHODS FOR FORMING NEGATIVE ELECTRODE ACTIVE MATERIALS FOR LITHIUM-BASED BATTERIES
    13.
    发明申请
    METHODS FOR FORMING NEGATIVE ELECTRODE ACTIVE MATERIALS FOR LITHIUM-BASED BATTERIES 有权
    用于形成用于锂基电池的负极电极活性材料的方法

    公开(公告)号:US20160020453A1

    公开(公告)日:2016-01-21

    申请号:US14332184

    申请日:2014-07-15

    Abstract: In an example method, a transition metal precursor is selected so its transition metal has a diffusion rate that is slower than a diffusion rate of silicon. An aqueous mixture is formed by dissolving the precursor in an aqueous medium, and adding silicon particles to the medium. The mixture is exposed to a hydroxide, which forms a product including the silicon particles and a transition metal hydroxide precipitate. The product is dried. In an inert or reducing environment, silicon atoms of the silicon particles in the dried product are caused to diffuse out of, and form voids in and/or at a surface of, the particles. At least some silicon atoms react with the transition metal hydroxide in the dried product to form i) a SiOx (0

    Abstract translation: 在示例性方法中,选择过渡金属前体,使得其过渡金属具有比硅的扩散速率慢的扩散速率。 通过将前体溶解在水性介质中并将硅颗粒添加到介质中来形成含水混合物。 将混合物暴露于氢氧化物,其形成包括硅颗粒和过渡金属氢氧化物沉淀物的产物。 产品干燥。 在惰性或还原环境中,使干燥产物中的硅颗粒的硅原子扩散到颗粒内和/或表面上形成空隙。 至少一些硅原子与干燥产物中的过渡金属氢氧化物反应以形成i)硅颗粒上的SiO x(0

Patent Agency Ranking