公开(公告)号：US06383971B1

公开(公告)日：2002-05-07

申请号：US09529767

申请日：2000-04-18

申请人： Heike Windisch

发明人： Heike Windisch

IPC分类号： B01J3100

CPC分类号： C08F4/54 ,  C08F36/04 ,  C08F4/545

摘要： The invention relates to new catalysts based on compounds of the rare earth metals containing a compound of the rare earth metals, a cyclopentadiene, and an alumoxane, as well as the use of new catalysts for the polymerisation of unsaturated compounds, particularly conjugated dienes. With the new catalyst system it is possible in the polymerisation of conjugated dienes to obtain a substantially higher proportion of laterally bound vinyl groups in the polymers.

摘要翻译： 本发明涉及基于含有稀土金属化合物，环戊二烯和铝氧烷的稀土金属化合物的新型催化剂，以及使用用于不饱和化合物，特别是共轭二烯的聚合的新催化剂。 使用新的催化剂体系，共轭二烯的聚合可能在聚合物中获得显着更高比例的横向结合的乙烯基。

公开(公告)号：US06310151B1

公开(公告)日：2001-10-30

申请号：US09743630

申请日：2001-01-12

申请人： Heike Windisch ,  Werner Obrecht ,  Gisbert Michels ,  Norbert Steinhauser

发明人： Heike Windisch ,  Werner Obrecht ,  Gisbert Michels ,  Norbert Steinhauser

IPC分类号： C08F470

CPC分类号： C08F36/04 ,  C08F4/7096

摘要： Conjugated diolefins, optionally in combination with other unsaturated compounds which may be copolymerized with the diolefins, are polymerized by performing the polymerization of the diolefins in the presence of catalysts based on cobalt compounds, organoaluminum compounds and modifiers in the presence of aromatic vinyl compounds at temperatures of −30° C. to +80° C. By means of the process according to the invention, it is possible straightforwardly to produce solutions of polydiolefins, such as polybutadiene, having different 1,2 unit contents in aromatic vinyl compounds, which solutions may then, for example, be further processed to yield ABS or HIPS.

摘要翻译： 任选与可与二烯烃共聚的其它不饱和化合物组合的共轭二烯烃通过在芳族乙烯基化合物存在下，在芳族乙烯基化合物存在下，在基于钴化合物，有机铝化合物和改性剂的催化剂的存在下进行二烯烃的聚合， -30℃至+ 80℃。通过本发明的方法，可以直接在芳族乙烯基化合物中产生具有不同1,2-单元含量的聚二烯烃如聚丁二烯的溶液，该溶液 然后可以例如进一步加工以产生ABS或HIPS。