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12 条记录 (耗时 0.022 秒)

    Method for polymerizing conjugated diolefins (dienes) with catalysts based on vanadium compounds in the presence of vinylaromatic solvents
    1.
    发明授权
    Method for polymerizing conjugated diolefins (dienes) with catalysts based on vanadium compounds in the presence of vinylaromatic solvents 失效
    在乙烯基芳族溶剂存在下，使用基于钒化合物的催化剂聚合共轭二烯烃（二烯）的方法

    公开(公告)号：US06566465B1

    公开(公告)日：2003-05-20

    申请号：US09743535

    申请日：2001-01-11

    申请人： Heike Windisch ,  Werner Obrecht ,  Gisbert Michels ,  Norbert Steinhauser

    发明人： Heike Windisch ,  Werner Obrecht ,  Gisbert Michels ,  Norbert Steinhauser

    IPC分类号： C08F468

    CPC分类号： C08F36/04 ,  C08F4/68

    摘要： Conjugated diolefins, optionally in combination with other unsaturated compounds which may be copolymerized with the diolefins, are polymerized by performing the polymerization of the diolefins in the presence of catalysts based on monocyclopentadienyl compounds of vanadium and alumoxanes in the presence of aromatic vinyl compounds as the solvent at temperatures of −30 C. to +80 C. By means of the process according to the invention, it is possible to straightforwardly produce solutions of polydiolefins, such as polybutadiene, having 1,2 unit contents of 10 to 30% in aromatic vinyl compounds, which solutions may then, for example, be further processed to yield ABS or HIPS.

    摘要翻译： 任选与可与二烯烃共聚的其它不饱和化合物组合的共轭二烯烃通过在芳族乙烯基化合物作为溶剂存在下，在基于钒和铝氧烷的单环戊二烯基化合物的催化剂存在下进行二烯烃的聚合而聚合 在-30℃至+ 80℃的温度下进行。通过本发明的方法，可以直接生产聚二烯烃如聚丁二烯的溶液，其中1,2-单体含量为10-30％，芳族乙烯基 化合物，然后可以将该溶液进一步加工以产生ABS或HIPS。

    Method for polymerizing conjugated diolefins (dienes) with catalysts based on cobalt compounds in the presence of vinylaromatic solvents
    2.
    发明授权
    Method for polymerizing conjugated diolefins (dienes) with catalysts based on cobalt compounds in the presence of vinylaromatic solvents 失效
    在乙烯基芳烃溶剂存在下，使用基于钴化合物的催化剂聚合共轭二烯烃（二烯）的方法

    公开(公告)号：US06310151B1

    公开(公告)日：2001-10-30

    申请号：US09743630

    申请日：2001-01-12

    申请人： Heike Windisch ,  Werner Obrecht ,  Gisbert Michels ,  Norbert Steinhauser

    发明人： Heike Windisch ,  Werner Obrecht ,  Gisbert Michels ,  Norbert Steinhauser

    IPC分类号： C08F470

    CPC分类号： C08F36/04 ,  C08F4/7096

    摘要： Conjugated diolefins, optionally in combination with other unsaturated compounds which may be copolymerized with the diolefins, are polymerized by performing the polymerization of the diolefins in the presence of catalysts based on cobalt compounds, organoaluminum compounds and modifiers in the presence of aromatic vinyl compounds at temperatures of −30° C. to +80° C. By means of the process according to the invention, it is possible straightforwardly to produce solutions of polydiolefins, such as polybutadiene, having different 1,2 unit contents in aromatic vinyl compounds, which solutions may then, for example, be further processed to yield ABS or HIPS.

    摘要翻译： 任选与可与二烯烃共聚的其它不饱和化合物组合的共轭二烯烃通过在芳族乙烯基化合物存在下，在芳族乙烯基化合物存在下，在基于钴化合物，有机铝化合物和改性剂的催化剂的存在下进行二烯烃的聚合， -30℃至+ 80℃。通过本发明的方法，可以直接在芳族乙烯基化合物中产生具有不同1,2-单元含量的聚二烯烃如聚丁二烯的溶液，该溶液 然后可以例如进一步加工以产生ABS或HIPS。

    Two-component supported catalysts and their use for gas-phase polymerization
    3.
    发明授权
    Two-component supported catalysts and their use for gas-phase polymerization 失效
    双组分负载催化剂及其在气相聚合中的应用

    公开(公告)号：US06365537B1

    公开(公告)日：2002-04-02

    申请号：US09151828

    申请日：1998-09-11

    申请人： Heike Windisch ,  Norbert Steinhauser

    发明人： Heike Windisch ,  Norbert Steinhauser

    IPC分类号： B01J3100

    CPC分类号： C08F36/06 ,  C08F4/02 ,  C08F4/545 ,  C08F4/54 ,  C08F4/7096

    摘要： The present invention relates to a two-component supported catalyst, consisting of a) at least one transition metal compound applied on to an inorganic or polymeric organic supporting material, the metal being selected from the group of the d and f elements of the periodic table according to Mendeleev, b) at least one organometallic compound applied on to an inorganic or polymeric organic supporting material, the metal being selected from the group of the IIa, IIb and IIIb elements of the periodic table (F. A. Cotton, G. Wilkinson, Anorganische Chemie, 4th edition, VCH Verlagsgesellschaft mbH, Weinheim, 1985) and c) optionally at least one modifier which is supported on a) and/or on b), the transition metal compound in component a) being used in quantities of 0.1 to 100 mmol, based on 100 g of the supporting material, and the organometallic compound in component b) being used in quantities of 0.1 to 100 mmol, based on 100 g of the supporting material, and component c) being used in quantities of 0.01 to 500 mmol, based on 100 g of the supporting material, and the supporting materials of components a) to b) being used in quantitative ratios by weight (g/g) of 1.10−3 to 1000, and at least one of components a) or b) having a supporting material with an average particle size before or during polymerisation of

    摘要翻译： 本发明涉及一种双组分负载型催化剂，由以下组成：a）至少一种应用于无机或聚合物有机支撑材料的过渡金属化合物，该金属选自周期表的d和f元素，根据 至Mendeleev，b）至少一种应用于无机或聚合有机载体材料的有机金属化合物，该金属选自周期表IIa，IIb和IIIb族元素（FA Cotton，G.Wilkinson，Anorganische Chemie ，第4版，VCH Verlagsgesellschaft mbH，Weinheim，1985）和c）任选地至少一种负载在a）和/或b）上的改性剂，组分a）中的过渡金属化合物的用量为0.1至100mmol， 基于100g支撑材料，组分b）中的有机金属化合物的用量为0.1至100mmol，基于100g支撑材料，组分c）用于定量 0.01至500mmol，基于100g支撑材料，组分a）至b）的支撑材料以1.10-3至1000的重量比（g / g）和至少一种 的组分a）或b）在聚合<25μm之前或期间具有平均粒度的支撑材料。

    Block copolymer based on conjugated diolefins and polar monomers
    4.
    发明授权
    Block copolymer based on conjugated diolefins and polar monomers 有权
    基于共轭二烯烃和极性单体的嵌段共聚物

    公开(公告)号：US06734257B2

    公开(公告)日：2004-05-11

    申请号：US10102761

    申请日：2002-03-21

    申请人： Heike Windisch ,  Werner Obrecht ,  Cristina Stere ,  Thomas Scholl ,  Oskar Nuyken ,  Lars Friebe ,  Mario Vierle

    发明人： Heike Windisch ,  Werner Obrecht ,  Cristina Stere ,  Thomas Scholl ,  Oskar Nuyken ,  Lars Friebe ,  Mario Vierle

    IPC分类号： C08L5300

    CPC分类号： C08F297/06

    摘要： The block copolymers according to the invention which are based on conjugated diolefins and polar monomers and are prepared in the presence of catalysts based on the rare earth metals have a high cis-1,4 content in the polydiene block and, because of their polar polymer part and their non-polar diene polymer part, can be used as agents which impart compatibility in the preparation of vulcanizates with a filler content for the production of tires and tire component in the preparation of thermoplastic elastomers or in the modification of thermoplastics.

    摘要翻译： 根据本发明的基于共轭二烯烃和极性单体并且在基于稀土金属的催化剂存在下制备的嵌段共聚物在聚二烯嵌段中具有高顺式-1,4的含量，并且由于它们的极性聚合物 部分和它们的非极性二烯聚合物部分可以用作在制备热塑性弹性体或在热塑性塑料的改性中赋予轮胎和轮胎组分的制备中的填料含量的硫化橡胶制剂相容性的试剂。

    Supported cobalt catalyst, production thereof and use thereof for the polymerization of unsaturated compounds
    8.
    发明授权
    Supported cobalt catalyst, production thereof and use thereof for the polymerization of unsaturated compounds 失效
    负载钴催化剂，其制备方法及其用途，用于不饱和化合物的聚合

    公开(公告)号：US6093674A

    公开(公告)日：2000-07-25

    申请号：US132370

    申请日：1998-08-11

    申请人： Heike Windisch ,  Gerd Sylvester

    发明人： Heike Windisch ,  Gerd Sylvester

    IPC分类号： C08F4/02 ,  C08F4/602 ,  C08F4/70 ,  C08F36/04 ,  B01J31/00

    CPC分类号： C08F36/04

    摘要： The present invention relates to a supported cobalt catalyst consisting of(a) cobalt compounds,(b) organoaluminium compounds,(c) water or OH-acidic compounds,(d) inorganic or polymeric organic support materials and(e) modifiers selected from the group comprising tertiary phosphines,to the production thereof and to the use thereof for the polymerization of unsaturated compounds, in particular of conjugated dienes, in the gas phase. With the assistance of the catalysts according to the invention, it is possible to achieve gas phase polymerization of conjugated dienes with an elevated content of lateral double bonds in the polymers.

    摘要翻译： 本发明涉及由（a）钴化合物，（b）有机铝化合物，（c）水或OH-酸性化合物，（d）无机或聚合有机载体材料和（e）选自 包括叔膦的组，其生产方法及其在气相中聚合不饱和化合物，特别是共轭二烯的用途。 在本发明的催化剂的帮助下，可以实现聚合物中侧链双键含量升高的共轭二烯的气相聚合。