Processing composition for silver halide color photographic material and
processing process including that composition
    14.
    发明授权
    Processing composition for silver halide color photographic material and processing process including that composition 失效
    卤化银彩色照相材料的加工组合物和包括该组合物的加工工艺

    公开(公告)号:US5250401A

    公开(公告)日:1993-10-05

    申请号:US737876

    申请日:1991-07-30

    IPC分类号: G03C7/42

    CPC分类号: G03C7/421

    摘要: Disclosed is a method for processing a silver halide color photographic material, which comprises the steps of:image-wise exposing a silver halide color photographic material,color developing the image-wise exposed silver halide photographic material, andprocessing the color developed silver halide photographic material, in the presence of a processing composition containing a metal chelating compound formed by a compound represented by following formula (I) and a salt of a metal belonging to group Ib, IIb, IIIb,IVb, Vb, VIb, VIIb, or VIII of the Periodic Table: ##STR1## wherein Z represents a heterocyclic group; L represents a divalent linkage group; R.sub.11 and R.sub.12 each represents a hydrogen atom, an aliphatic group, an aromatic group, or a heterocyclic group; and n represents 0 or 1. Also disclosed is the processing composition used in the above method.

    摘要翻译: 公开了一种处理卤化银彩色照相材料的方法,其包括以下步骤:以成像方式暴露卤化银彩色照相材料,彩色显影图像曝光的卤化银照相材料,以及处理显色的卤化银照相 在含有由下式(I)表示的化合物形成的金属螯合化合物和属于Ib,IIb,IIIb,IVb,Vb,VIb,VIIb或VIII族的金属的盐的处理组合物存在下, 的周期表:其中Z表示杂环基;(I)其中Z表示杂环基; L表示二价连接基团; R 11和R 12各自表示氢原子,脂肪族基团,芳香族基团或杂环基团; 并且n表示0或1.还公开了用于上述方法的处理组合物。

    Process for forming super high contrast negative images
    17.
    发明授权
    Process for forming super high contrast negative images 失效
    用于形成超高对比度负像的过程

    公开(公告)号:US5139921A

    公开(公告)日:1992-08-18

    申请号:US653480

    申请日:1991-02-12

    IPC分类号: G03C1/06

    CPC分类号: G03C1/061 G03C2001/108

    摘要: A process of forming super high contrast negative photographic materials in a developer having a pH of from 9.6 to 11.0 wherein the photographic material contains a hydrazine compound and a nucleation accelerator. The nucleation accelerator is represented by formula (Ia):Y[(A.sub.1).sub.p A.sub.2 --B].sub.m (Ia)wherein Y represents a group adsorbing onto silver halide; A.sub.1 represents a divalent linkage group composed of an atom or an atomic group selected from hydrogen, carbon, nitrogen, oxygen, and sulfur and selected from ##STR1## with a straight chain or branched alkylene group wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7, R.sub.8, R.sub.9 and R.sub.10 each represents hydrogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkenyl group or a substituted or unsubstituted aralkyl group; A.sub.2 represents a divalent linkage group selected from a straight chain or branched alkylene group, a straight chain or branched alkenylene group, a straight chain or branched aralkylene group or a straight chain or branched arylene group; B represents a substituted or unsubstituted amino group, an ammonium group, or a nitrogen-containing heterocyclic ring; m represents the integer 1, 2, or 3; and p represents 0 or the integer 1.

    摘要翻译: 在具有9.6至11.0的pH的显影剂中形成超高对比度负型照相材料的方法,其中照相材料含有肼化合物和成核促进剂。 成核促进剂由式(Ia)表示:Y [(A1)pA2-B] m(Ia)其中Y表示吸附在卤化银上的基团; A1表示由选自氢,碳,氮,氧和硫的原子或原子团组成的二价连接基团,并且选自具有直链或支链的 其中R1,R2,R3,R4,R5,R6,R7,R8,R9和R10各自表示氢,取代或未取代的烷基,取代或未取代的芳基,取代或未取代的烯基或取代或未取代的烯基 未取代的芳烷基; A2表示选自直链或支链亚烷基,直链或支链亚烯基,直链或支链亚芳基或直链或支链亚芳基的二价连接基团; B表示取代或未取代的氨基,铵基或含氮杂环; m表示整数1,2或3; p表示0或整数1。

    Silver halide photographic material with redox releaser
    18.
    发明授权
    Silver halide photographic material with redox releaser 失效
    卤化银照相材料与氧化还原剂

    公开(公告)号:US5132201A

    公开(公告)日:1992-07-21

    申请号:US789810

    申请日:1991-11-12

    IPC分类号: G03C7/305

    摘要: A silver halide photographic material composed of a support having thereon at least one light-sensitive silver halide emulsion layer, at least one layer of the material containing a compound represented by formula (I): ##STR1## wherein X represents hydrogen or a group capable of providing hydrogen upon hydrolysis; Time represents a divalent linking group; t is 0 or 1; PUG represents a photographically useful group; V represents a carbonyl group, a sulfonyl group, a sulfoxy group, an iminomethylene group, ##STR2## wherein W represents an electrophilic group, or V represents ##STR3## wherein R.sub.0 represents an alkoxy group or an aryloxy group; and R represents hydrogen, an aliphatic group, an aromatic group or ##STR4## wherein PUG, Time, t, and W are as defined above. The redox compound is capable of releasing a photographically useful reagent using any conventional developing agent, has excellent storage stability, and provides rapid release of the photographically useful reagent.

    摘要翻译: 一种由其上具有至少一个感光卤化银乳剂层的载体组成的卤化银照相材料,至少一层含有式(I)表示的化合物的材料:其中X表示氢或 水解时能够提供氢的基团; 时间表示二价连接基团; t为0或1; PUG代表一个摄影有用的组; V表示羰基,磺酰基,亚砜氧基,亚氨基亚甲基,其中W表示亲电子基团,或V表示其中R0表示烷氧基或芳氧基; 并且R表示氢,脂族基团,芳族基团或其中PUG,时间,t和W如上所定义。 氧化还原化合物能够使用任何常规的显影剂释放照相用试剂,具有优异的储存稳定性,并提供照相用试剂的快速释放。

    Silver halide photographic material
    19.
    发明授权
    Silver halide photographic material 失效
    卤化银照相材料

    公开(公告)号:US5006445A

    公开(公告)日:1991-04-09

    申请号:US343441

    申请日:1989-04-26

    IPC分类号: G03C1/06 G03C1/485

    CPC分类号: G03C1/061

    摘要: A silver halide photographic material comprising a support having thereon at least one hydrophilic colloid layer, at least one of which is a silver halide photographic emulsion layer, is disclosed. At least one of the silver halide emulsion layers or other hydrophilic colloid layers of the photographic material contains a compound represented by formula (I): ##STR1## wherein, A.sub.1 and A.sub.2 both represent hydrogen atoms or one represents a hydrogen atom and the other a sulfonyl group or an acyl group, R.sub.1 represents an aliphatic group, an aromatic group or a heterocyclic group, G.sub.1 represents a carbonyl group, a sulfonyl group, a sulfoxy group, a ##STR2## group wherein R.sub.2 represents an alkoxy group or an aryloxy group, a ##STR3## group or an iminomethylene group, X.sub.1 is a moiety which instigates a ring-forming reaction by cleaving the --G.sub.1 --X.sub.1 moiety from the residual molecule and forms a cyclic structure containing the atoms of the --G.sub.1 --X.sub.1 moiety, and at least one of R.sub.1 and X.sub.1 has a silver halide adsorption accelerating group.

    摘要翻译: 公开了一种卤化银照相材料,其包含其上具有至少一个亲水胶体层的载体,其中至少一个是卤化银照相乳剂层。 照相材料的卤化银乳剂层或其他亲水胶体层中的至少一种含有由式(I)表示的化合物:其中,A1和A2均代表氢原子或一个表示氢原子, 另一个是磺酰基或酰基,R 1表示脂族基团,芳族基团或杂环基团,G 1表示羰基,磺酰基,磺基氧基,其中R 2表示烷氧基或 一个芳氧基,一个“IMAGE”基团或一亚氨基亚甲基,X 1是通过从残留分子中切割-G1-X1部分并形成含有-G1-的原子的环状结构来引发成环反应的部分, X1部分,并且R1和X1中的至少一个具有卤化银吸附促进基团。

    Silver halide photographic material
    20.
    发明授权
    Silver halide photographic material 失效
    卤化银照相材料

    公开(公告)号:US4914002A

    公开(公告)日:1990-04-03

    申请号:US267469

    申请日:1988-11-04

    IPC分类号: G03C1/06 G03C1/16

    CPC分类号: G03C1/061 G03C1/16

    摘要: A silver halide negative photographic material comprising a support having thereon at least one silver halide emulsion layer, at least one hydrophilic colloidal layer thereof containing (1) a hydrazine derivative, (2) a compound substantially having no absorption maximum in the visible light region represented by formula (I): ##STR1## wherein Z.sup.11, Z.sup.12, R.sup.11, R.sup.12 X and n are as defined in the specification, and (3) at least one compound represented by formula (II) or (III): ##STR2## wherein R.sub.1, R.sub.2, R.sub.3 and Q are as defined in the specification; and ##STR3## wherein R.sub.21, R.sub.22, R.sub.23, and R.sub.24, are as defined in the specification. The photographic material can be processed with a stable developer to provide an ultra-high contrast image without reduction in sensitivity, gamma or maximum density or the appearance of black pepper. The photographic material is excellent in pressure properties and anti-blocking properties.

    摘要翻译: 一种卤化银负型照相材料,其包含其上具有至少一个卤化银乳剂层的载体,至少一种亲水性胶体层,其含有(1)肼衍生物,(2)在可见光区域中基本上不具有最大吸收的化合物 通式(I):其中Z11,Z12,R11,R12X和n如说明书中所定义,其中(I)至少一种由式(II)或(III)表示的化合物: (II)其中R1,R2,R3和Q如说明书中所定义; 和(III)其中R 21,R 22,R 23和R 24如说明书中所定义。 可以用稳定的显影剂处理照相材料以提供超高对比度图像,而不降低灵敏度,γ或最大密度或黑胡椒的外观。 照相材料的压力特性和防粘连性优异。