Chromium-enriched oxide containing material and preoxidation method of making the same to mitigate corrosion and fouling associated with heat transfer components
    11.
    发明授权
    Chromium-enriched oxide containing material and preoxidation method of making the same to mitigate corrosion and fouling associated with heat transfer components 失效
    富含铬的氧化物材料和预氧化方法,以减少与传热组分相关的腐蚀和结垢

    公开(公告)号:US08037928B2

    公开(公告)日:2011-10-18

    申请号:US11641750

    申请日:2006-12-20

    IPC分类号: F28F19/00 F28D7/10

    摘要: A heat transfer component that is resistant to corrosion and fouling is disclosed. The heat transfer component includes a heat exchange surface formed from a chromium-enriched oxide containing material formed from the composition δ, ε, and ζ, wherein ζ is a steel containing at least about 5 to about 40 wt. % chromium, ε is a chromium enriched oxide (M3O4 or M2O3 or mixtures thereof) formed on the surface of the steel ζ, wherein M is a metal containing at least 5 wt. % Cr based on the total weight of the metal M, and δ is a top layer formed on the surface of the chromium-enriched oxide ε, comprising sulfide, oxide, oxysulfide, and mixtures thereof. The top layer δ comprises iron sulfide (Fe1-xS), iron oxide (Fe3O4), iron oxysulfide, iron-chromium sulfide, iron-chromium oxide, iron-chromium oxysulfide, and mixtures thereof. The metal M of the chromium enriched oxide (M3O4 or M2O3 or mixtures thereof) may comprise Fe, Cr, and constituting elements of the steel ζ. The steel ζ may be selected from low chromium steels, ferritic stainless steels, martensitic stainless steels, austenitic stainless steels, duplex stainless steels and precipitation-hardenable alloys.

    摘要翻译: 公开了耐腐蚀和结垢的传热部件。 传热组分包括由组合物δ,&egr和ζ形成的含铬富氧材料形成的热交换表面,其中ζ是含有至少约5至约40重量% %铬, 是在钢ζ的表面上形成的富含铬的氧化物(M3O4或M2O3或其混合物),其中M是含有至少5wt。 %Cr,基于金属M的总重量,δ是在富含铬的氧化物的表面上形成的顶层,其包含硫化物,氧化物,硫氧化物及其混合物。 顶层δ包括硫化铁(Fe1-xS),氧化铁(Fe3O4),硫氧化铁,铁 - 硫化铬,铁 - 铬氧化物,铁 - 硫氧化铬及其混合物。 富含铬的氧化物(M3O4或M2O3或其混合物)的金属M可以包含Fe,Cr和构成元素的ζ。 钢ζ可以选自低铬钢,铁素体不锈钢,马氏体不锈钢,奥氏体不锈钢,双相不锈钢和沉淀硬化合金。

    Chromiun-enriched oxide containing material and preoxidation method of making the same to mitigate corrosion and fouling associated with heat transfer components
    15.
    发明授权
    Chromiun-enriched oxide containing material and preoxidation method of making the same to mitigate corrosion and fouling associated with heat transfer components 失效
    富含氧化铬的氧化物材料和预氧化方法,以减少与传热组分相关的腐蚀和结垢

    公开(公告)号:US08465599B2

    公开(公告)日:2013-06-18

    申请号:US13193223

    申请日:2011-07-28

    IPC分类号: C23C8/14

    摘要: A method of providing sulfidation corrosion resistance and corrosion induced fouling resistance for a heat transfer component is disclosed. The heat transfer component includes a heat exchange surface formed from a chromium-enriched oxide containing material formed from the composition δ, ε, and ζ, wherein ζ is a steel containing at least about 5 to about 40 wt. % chromium, ε is a chromium enriched oxide (M3O4 or M2O3 or mixtures thereof) formed on the surface of the steel ζ, wherein M is a metal containing at least 5 wt. % Cr based on the total weight of the metal M, and δ is a top layer formed on the surface of the chromium-enriched oxide ε, comprising sulfide, oxide, oxysulfide, and mixtures thereof. The top layer δ comprises iron sulfide (Fe1-xS), iron oxide (Fe3O4), iron oxysulfide, iron-chromium sulfide, iron-chromium oxide, iron-chromium oxysulfide, and mixtures thereof. The metal M of the chromium enriched oxide (M3O4 or M2O3 or mixtures thereof) may comprise Fe, Cr, and constituting elements of the steel ζ. The steel ζ may be selected from low chromium steels, ferritic stainless steels, martensitic stainless steels, austenitic stainless steels, duplex stainless steels and precipitation-hardenable alloys.

    摘要翻译: 公开了一种提供耐热性和耐腐蚀性的传热部件的耐污性的方法。 传热组件包括由组合物δ,ε和zeta形成的含铬富含氧化物材料形成的热交换表面,其中ζ是含有至少约5至约40wt。 %铬,ε是形成在钢ζ表面上的富铬氧化物(M3O4或M2O3或其混合物),其中M是含有至少5wt。 %Cr,基于金属M的总重量,δ是在富含铬的氧化物ε的表面上形成的顶层,其包含硫化物,氧化物,氧硫化物及其混合物。 顶层delta包括硫化铁(Fe1-xS),氧化铁(Fe3O4),硫氧化铁,铁 - 硫化铬,铁 - 氧化铬,铁 - 硫氧化铬及其混合物。 富含铬的氧化物(M3O4或M2O3或其混合物)的金属M可以包含Fe,Cr和钢ζ的构成元素。 钢ζ可选自低铬钢,铁素体不锈钢,马氏体不锈钢,奥氏体不锈钢,双相不锈钢和沉淀硬化合金。