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11.发明授权Photographic materials and process comprising a particular acylacetanilide yellow dye-forming coupler 失效包含特定酰基乙酰替苯胺黄染料成色剂的摄影材料和方法
公开(公告)号：US5851748A
公开(公告)日：1998-12-22
申请号：US766194
申请日：1996-12-12
CPC分类号： G03C7/30535
摘要： The invention provides a photographic element comprising a silver halide emulsion layer having associated therewith a yellow dye-forming coupler having the formula: ##STR1## wherein X, Y, Z, W are independently selected from the group consisting of H, alkyl, aryl, halogen, alkoxy and aryloxy groups, provided that X and W may join to form a saturated ring; Each A is selected from the group consisting of halogen, alkoxy and aryloxy groups; m is an integer from 1 to 3; each B is independently selected from the group consisting of --C(O)OR.sub.2 and --NHSO.sub.2 R.sub.3 wherein R.sub.2 and R.sub.3 are independently selected from the group consisting of alkyl and aryl groups;n is an integer from 1 to 3; and R.sub.1 is a substituent group.
摘要翻译： 本发明提供一种照相元件，其包含卤化银乳剂层，其具有下式的黄色染料形成成色剂：其中X，Y，Z，W独立地选自H，烷基，芳基， 卤素，烷氧基和芳氧基，条件是X和W可以连接形成饱和环; 每个A选自卤素，烷氧基和芳氧基; m为1〜3的整数; 每个B独立地选自-C（O）OR 2和-NHSO 2 R 3，其中R 2和R 3独立地选自烷基和芳基; n为1〜3的整数， 并且R 1是取代基。
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公开(公告)号：US06261755B1
公开(公告)日：2001-07-17
申请号：US09514632
申请日：2000-02-28
申请人： Danuta Gibson , James S. Honan , Thomas A. Rosiek
发明人： Danuta Gibson , James S. Honan , Thomas A. Rosiek
IPC分类号： G03C108
CPC分类号： G03C7/342 , G03C1/34 , G03C1/815 , G03C7/3006 , G03C7/3212 , G03C7/34 , G03C7/3885 , G03C7/39216 , G03C7/39256
摘要： The invention provides a photographic element comprising at least one light-sensitive silver halide emulsion layer having associated therewith: (A) a phenolic cyan dye-forming narrow bandwidth “NB coupler”; (B) a phenolic cyan dye-forming coupler of formula (II): wherein: R3 is an unsubstituted or substituted alkyl or aryl group or a 5-10 membered heterocyclic ring which contains one or more heteroatoms selected from nitrogen, oxygen and sulfur, which ring is unsubstituted or substituted; R4 is an unsubstituted or substituted alkyl group; R5 is hydrogen, halogen or an unsubstituted or substituted alkyl or aryl group or a 5-10 membered heterocyclic ring which contains one or more heteroatoms selected from nitrogen, oxygen and sulfur, which ring is unsubstituted or substituted; and Z is a hydrogen atom or a group which can be split off by the reaction of the coupler with an oxidized color-developing agent; and (C) a stabilizer of formula (III) wherein: each Y is an independently selected substituent and m is 0 to 4; and each T is an independently selected substituent and p is 0 to 4. Preferably the element has associated therewith one or more high-boiling solvents of formula (IV) wherein: R1 is an unsubstituted or substituted alkyl or aryl group; and G is an unsubstituted or substituted alkyl group.
摘要翻译： 本发明提供了一种照相元件，其包含至少一种与之相关的感光卤化银乳剂层：（A）形成苯酚青色染料的窄带宽“NB成色剂”;（B）式（B）的酚青色染料成色剂 II）：其中：R3是未取代或取代的烷基或芳基或含有一个或多个选自氮，氧和硫的杂原子的5-10元杂环，该环是未取代或取代的; R4是未取代或取代的 烷基; R5是氢，卤素或未取代或取代的烷基或芳基或含有一个或多个选自氮，氧和硫的杂原子的5-10元杂环，该环是未取代的或被取代的; Z为氢原子或可通过偶合剂与氧化显色剂的反应而分离的基团; 和（C）式（III）的稳定剂，其中：每个Y是独立选择的取代基，m是0-4; 所述T是独立选择的取代基，p是0至4.优选所述元素与一种或多种式（Ⅳ）的高沸点溶剂缔合，其中：R 1为未取代或取代的烷基或芳基; G是未取代或取代的烷基。
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13.发明授权Cyan coupler and combination solvent-containing photographic element and process 失效青色耦合剂和组合溶剂的照相元件和工艺
公开(公告)号：US6110658A
公开(公告)日：2000-08-29
申请号：US266234
申请日：1999-03-10
CPC分类号： G03C7/39296 , G03C7/3006 , G03C7/346 , G03C7/39232 , G03C7/39256
摘要： Disclosed is a photographic element having a reduced rate of crystal formation comprising a silver halide emulsion layer having associated therewith:(a) a phenolic cyan dye-forming "NB coupler";(b) a first high boiling solvent having Formula (IV):G--C--OO--R.sup.1 (IV) wherein:R.sup.1 is an alkyl or aryl groups; andG is an alkyl (including cycloalkyl and aralkyl) containing linking group; and(c) one or more second high boiling solvents selected from phosphates, phosphonates, phosphine oxides, sulfoxides, and carbonamides, said second high boiling solvent being present in amounts (by weight) sufficient to reduce crystal formation in a dispersion of the coupler compared to a dispersion of the same coupler in a dispersion where the second solvent is replaced with a like amount of the first solvent.
摘要翻译： 公开了具有降低的晶体形成速率的照相元件，其包含与之相关的卤化银乳剂层：（a）形成苯酚青色染料的“NB成色剂”; （b）具有式（IV）的第一高沸点溶剂：G-C-OO-R 1（IV）其中：R 1是烷基或芳基; 并且G是含有连接基团的烷基（包括环烷基和芳烷基） 和（c）选自磷酸盐，膦酸盐，氧化膦，亚砜和碳酰胺的一种或多种第二高沸点溶剂，所述第二高沸点溶剂以足以减少成色剂分散体中的结晶形成的量（重量比） 到相同成色剂在分散体中的分散体，其中第二溶剂被等量的第一溶剂代替。
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14.发明授权Method for forming photographic dispersions comprising loaded latex polymers 失效用于形成包含负载胶乳聚合物的照相分散体的方法
公开(公告)号：US5594047A
公开(公告)日：1997-01-14
申请号：US390400
申请日：1995-02-17
CPC分类号： G03C7/3882
摘要： Loaded latex dispersions of hydrophobic photographically useful compounds with a wide variety of polymer latices are prepared by preparing an oil phase solution of the hydrophobic compound or compounds, preferably essentially free of water-miscible or volatile solvent, combining the oil solution with one or more aqueous solutions, at least one of which contains a polymer latex, and mixing the combination of oil solution, aqueous solution and latex under high shear or turbulence sufficient to cause loading of the photographically useful compound into the dispersed polymer latex wherein the pH of the mixture does not need to be significantly changed.
摘要翻译： 通过制备疏水性化合物或化合物的油相溶液，优选基本上不含水混溶性或挥发性溶剂，将油溶液与一种或多种水溶液合并，制备具有各种各样的聚合物胶乳的疏水照相有用化合物的负载胶乳分散体 溶液，其中至少一个含有聚合物胶乳，并在高剪切或湍流下混合油溶液，水溶液和胶乳的组合，足以使照相有用化合物加载到分散的聚合物胶乳中，其中混合物的pH 不需要明显改变。
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15.发明授权Method for preparing photographic elements comprising loaded latex compositions 失效用于制备包含负载的胶乳组合物的照相元件的方法
公开(公告)号：US5558980A
公开(公告)日：1996-09-24
申请号：US390722
申请日：1995-02-17
CPC分类号： G03C1/005 , G03C7/388 , Y10S430/136
摘要： Photographic elements comprising loaded latex compositions are prepared by (a) combining under conditions of low or moderate shear, in the presence of surfactant, and in the substantial absence of water-miscible or volatile organic solvents, a liquid organic composition comprising at least one photographically useful compound with an aqueous polymer latex, (b) holding the combination resulting from (a) in a liquid state for sufficient time for substantial loading of the organic coposition into the polymer latex to occur, and (c) coating the loaded latex resulting from (b) on a support.
摘要翻译： 包含加载的胶乳组合物的照相元件通过（a）在表面活性剂存在下和基本上不存在水混溶性或挥发性有机溶剂的条件下，在低或中等剪切条件下组合，制备包含至少一种照相的液体有机组合物 （b）将由（a）液体状态产生的组合物保持足够的时间以使有机相变体大量加载到聚合物胶乳中进行，和（c）将由 （b）支持。
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公开(公告)号：US5262292A
公开(公告)日：1993-11-16
申请号：US872577
申请日：1992-04-23
申请人： Sundaram Krishnamurthy , Thomas A. Rosiek , Vincent J. Flow , David S. Bailey , David J. Giacherio , John L. Pawlak , Stephen P. Singer
发明人： Sundaram Krishnamurthy , Thomas A. Rosiek , Vincent J. Flow , David S. Bailey , David J. Giacherio , John L. Pawlak , Stephen P. Singer
CPC分类号： G03C7/3885 , G03C7/3003 , G03C7/3012
摘要： Pyrazolone magenta dye-forming couplers having a particular arylthio coupling-off group enhance the photographic properties and improve the manufacturing and handling characteristics of materials and processes employing such couplers. The coupler contains an N-phenyl group, a 3-anilino group and a 4-(arylthio) coupling off group containing a particular aryloxymethylacylamino group as an ortho substituent. A broad range of improvements are realized including stability, reactivity, hue, and dye density in addition to simplified and safer manufacture.The coupler may be represented by the following formula where the substituents and variables are as defined in the specification: ##STR1##
摘要翻译： 具有特定芳硫基偶联离去基团的吡唑啉酮品红色染料形成成色剂提高了照相性能并改善了采用这种成色剂的材料和方法的制造和处理特性。 成色剂含有N-苯基，3-苯胺基和含有特定的芳氧基甲酰基氨基作为邻位取代基的4-（芳硫基）偶联离去基团。 除了简化和安全的制造之外，实现了广泛的改进，包括稳定性，反应性，色调和染料密度。 成色剂可以由下式表示，其中取代基和变量如说明书中所定义：
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