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公开(公告)号：US20090072704A1
公开(公告)日：2009-03-19
申请号：US11911402
申请日：2006-04-14
IPC分类号： H01J1/63
CPC分类号： C09K11/7734 , C09K11/595 , C09K11/778 , C09K11/7787 , C09K11/7797 , H01J2211/42
摘要： The present invention provides a phosphor that has high luminance, a property of low luminance degradation during PDP driving, and chromaticity y comparable to that of BAM:Eu. The present invention is the phosphor that is represented by the general formula xAO.y1EuO.y2EuO3/2.DO.zSiO2 wherein A is at least one selected from Ca, Sr and Ba, D is at least one selected from Mg and Zn, and 2.970≦x≦3.500, 0.001≦y1+y2≦0.030, and 1.900≦z≦2.100 are satisfied, and that has 50 mol % or less of the divalent Eu ratio (ratio of the divalent Eu element to the total of the Eu elements) in the vicinity of the surface of the phosphor particle.
摘要翻译： 本发明提供了具有高亮度，PDP驱动时亮度劣化低的特性和与BAM：Eu相当的色度y的荧光体。 本发明是由通式xAO.y1EuO.y2EuO3 / 2.DO.zSiO2表示的荧光体，其中A是选自Ca，Sr和Ba中的至少一种，D是选自Mg和Zn中的至少一种，以及 2.970 <= x <= 3.500，0.001 <= y1 + y2 <= 0.030，并且满足1.900 <= z <= 2.100，并且具有50mol％以下的二价Eu比（二价Eu元素与 荧光体颗粒表面附近的Eu元素的总和）。
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12.发明申请Phosphor, method of manufacturing same, and plasma display panel using same 有权荧光体及其制造方法以及使用其的等离子体显示面板公开(公告)号：US20050077500A1
公开(公告)日：2005-04-14
申请号：US10929857
申请日：2004-08-30
申请人： Masahiro Sakai , Takehiro Zukawa , Seigo Shiraishi
发明人： Masahiro Sakai , Takehiro Zukawa , Seigo Shiraishi
IPC分类号： C09K11/80 , C09K11/08 , C09K11/64 , C09K11/77 , H01J1/63 , H01J11/12 , H01J11/22 , H01J11/24 , H01J11/26 , H01J11/34 , H01J11/42
CPC分类号： H01J1/63 , C09K11/7706
摘要： The present invention aims to provide a Eu-activated phosphor that maintains high wavelength conversion efficiency and suppresses deterioration with time due to vacuum ultraviolet irradiation, as well as a plasma display panel having superior display performance by suppressing sticking image caused by deterioration of the phosphor with time. To this end, the present invention provides a europium-activated phosphor where a divalent europium ratio of each phosphor particle constituting the phosphor is lower at and in a vicinity of a particle surface than for the particle as a whole. With such phosphor particles, it is possible to obtain the Eu-activated phosphor that has high maintaining ratio of emission intensity and high performance in suppressing deterioration with time in comparison with a conventional phosphor.
摘要翻译： 本发明的目的在于提供一种维持高波长转换效率并且抑制由于真空紫外线照射而随时间劣化的Eu活化荧光体，以及通过抑制由磷光体劣化引起的粘着影像而具有优异显示性能的等离子体显示面板， 时间。 为此，本发明提供一种铕激活的荧光体，其中构成荧光体的每个荧光体颗粒的二价铕比在颗粒表面附近低于整个颗粒。 通过这样的荧光体粒子，与以往的荧光体相比，可以获得具有高的发光强度保持率和高性能的抑制劣化的Eu活化荧光体。
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公开(公告)号：US20090200945A1
公开(公告)日：2009-08-13
申请号：US12301321
申请日：2007-05-25
申请人： Kojiro Okuyama , Masahiro Sakai , Seigo Shiraishi
发明人： Kojiro Okuyama , Masahiro Sakai , Seigo Shiraishi
CPC分类号： H01J11/42 , C09K11/7734 , H01J11/12 , H01J61/305 , H01J61/44 , H01J65/046
摘要： The present invention provides a phosphor having high luminance, a property of low luminance degradation during driving of a light-emitting device, and chromaticity y comparable to that of BAM:Eu. The present invention is a phosphor represented by the general formula aAO.bEuO.DO.cSiO2, where A is at least one selected from Ca, Sr and Ba, D is at least one selected from Mg and Zn, and 2.970≦a≦3.500, 0.001≦b≦0.030, and 1.900≦c≦2.100 are satisfied. In this phosphor, a peak intensity at 1490 cm−1 is 0.02 to 0.8 when a peak intensity at 565 cm−1 is set to 1 in a spectrum obtained by measurement using photoacoustic spectroscopy.
摘要翻译： 本发明提供一种具有高亮度，在发光装置的驱动期间的低亮度劣化的性质以及与BAM：Eu相当的色度y的荧光体。 本发明是由通式aAO.bEuO.DO.cSiO2表示的荧光体，其中A为选自Ca，Sr和Ba中的至少一种，D为选自Mg和Zn中的至少一种，2.970 <= a < = 3.500，0.001 <= b <= 0.030，并且满足1.900 <= c <= 2.100。 在该荧光体中，当使用光声光谱测定得到的光谱中，当在565cm -1处的峰值强度为1时，在1490cm -1处的峰强度为0.02〜0.8。
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公开(公告)号：US08236201B2
公开(公告)日：2012-08-07
申请号：US12438071
申请日：2008-03-28
CPC分类号： H01J11/42 , C09K11/7734 , H01J11/12
摘要： The present invention provides a phosphor having high luminance, a property of low luminance degradation during driving of a light-emitting device and manufacturing processes, and chromaticity y in PDP comparable to that of BAM:Eu. The present invention is the phosphor represented by the general formula xSrO.yEuO.MgO.zSiO2 where 2.970≦x≦3.500, 0.001 ≦y≦0.030, and 1.900≦z≦2.100 are satisfied, wherein a main peak is present in the range of diffraction angle 2θ=16.1 to 16.5 degree in the X-ray diffraction pattern obtained by measurement on the blue phosphor using an X-ray with a wavelength of 0.774 Å, and at least one condition of the following conditions (A1) and (A2) is satisfied: (A1) at least two peaks whose tops are located in the range of diffraction angle 2θ=15.3 to 16.1 degree are present; and (A2) at least two peaks whose tops are located in the range of diffraction angle 2θ=22.2 to 23.3 degree are present.
摘要翻译： 本发明提供一种具有高亮度，在发光装置的驱动期间的低亮度劣化和制造工艺以及与BAM：Eu相当的PDP中的色度y的特性的荧光体。 本发明是由通式xSrO.yEuO.MgO·zSiO 2表示的荧光体，其中满足2.970＆nlE; x＆nlE; 3.500,0.001和nlE; y＆nlE; 0.030和1.900＆lt; lE; z＆nlE; 2.100，其中主峰存在于 在通过使用波长为0.774的X射线对蓝色荧光体进行测量而获得的X射线衍射图中的衍射角2的范围= 16.1〜16.5度，以及以下条件（A1）的至少一个条件， 和（A2）：（A1）存在顶部位于衍射角2的范围内的至少两个峰值= 15.3〜16.1度; 和（A2）存在其顶部位于衍射角2的范围内的至少两个峰值; = 22.2至23.3度。
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公开(公告)号：US08129905B2
公开(公告)日：2012-03-06
申请号：US12301321
申请日：2007-05-25
申请人： Kojiro Okuyama , Masahiro Sakai , Seigo Shiraishi
发明人： Kojiro Okuyama , Masahiro Sakai , Seigo Shiraishi
CPC分类号： H01J11/42 , C09K11/7734 , H01J11/12 , H01J61/305 , H01J61/44 , H01J65/046
摘要： The present invention provides a phosphor having high luminance, a property of low luminance degradation during driving of a light-emitting device, and chromaticity y comparable to that of BAM:Eu. The present invention is a phosphor represented by the general formula aAO.bEuO.DO.cSiO2, where A is at least one selected from Ca, Sr and Ba, D is at least one selected from Mg and Zn, and 2.970≦a≦3.500, 0.001≦b≦0.030, and 1.900≦c≦2.100 are satisfied. In this phosphor, a peak intensity at 1490 cm−1 is 0.02 to 0.8 when a peak intensity at 565 cm−1 is set to 1 in a spectrum obtained by measurement using photoacoustic spectroscopy.
摘要翻译： 本发明提供一种具有高亮度，在发光装置的驱动期间的低亮度劣化的性质以及与BAM：Eu相当的色度y的荧光体。 本发明是由通式aAO.bEuO.DO.cSiO 2表示的荧光体，其中A是选自Ca，Sr和Ba中的至少一种，D是选自Mg和Zn中的至少一种，以及2.970和nlE; a＆ 3.500，0.001＆nlE; b＆nlE; 0.030和1.900＆nlE; c＆nlE; 2.100。 在该荧光体中，当使用光声光谱测定得到的光谱中，当在565cm -1处的峰值强度为1时，在1490cm -1处的峰强度为0.02〜0.8。
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公开(公告)号：US20100164360A1
公开(公告)日：2010-07-01
申请号：US12438071
申请日：2008-03-28
CPC分类号： H01J11/42 , C09K11/7734 , H01J11/12
摘要： The present invention provides a phosphor having high luminance, a property of low luminance degradation during driving of a light-emitting device and manufacturing processes, and chromaticity y in PDP comparable to that of BAM:Eu. The present invention is the phosphor represented by the general formula xSrO.yEuO.MgO.zSiO2 where 2.970≦x≦3.500, 0.001≦y≦0.030, and 1.900≦z≦2.100 are satisfied, wherein a main peak is present in the range of diffraction angle 2θ=16.1 to 16.5 degree in the X-ray diffraction pattern obtained by measurement on the blue phosphor using an X-ray with a wavelength of 0.774 Å, and at least one condition of the following conditions (A1) and (A2) is satisfied: (A1) at least two peaks whose tops are located in the range of diffraction angle 2θ=15.3 to 16.1 degree are present; and (A2) at least two peaks whose tops are located in the range of diffraction angle 2θ=22.2 to 23.3 degree are present.
摘要翻译： 本发明提供一种具有高亮度，在发光装置的驱动期间的低亮度劣化和制造工艺以及与BAM：Eu相当的PDP中的色度y的特性的荧光体。 本发明是由通式xSrO.yEuO.MgO·zSiO 2表示的荧光体，其中满足2.970＆nlE; x＆nlE; 3.500,0.001和nlE; y＆nlE; 0.030和1.900＆lt; lE; z＆nlE; 2.100，其中主峰存在于 在通过使用波长为0.774的X射线对蓝色荧光体进行测量而获得的X射线衍射图中的衍射角2的范围= 16.1〜16.5度，以及以下条件（A1）的至少一个条件， 和（A2）：（A1）存在顶部位于衍射角2的范围内的至少两个峰值= 15.3〜16.1度; 和（A2）存在其顶部位于衍射角2的范围内的至少两个峰值; = 22.2至23.3度。
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17.发明授权Phosphors and related manufacturing method, display device, and fluorescent lamp 有权荧光体及相关制造方法，显示装置和荧光灯公开(公告)号：US07153451B2
公开(公告)日：2006-12-26
申请号：US10867121
申请日：2004-06-14
IPC分类号： C09K11/64
CPC分类号： H01J1/63 , C09K11/7734
摘要： Phosphors having high luminescence characteristics are provided while achieving manufacturing cost reductions by minimizing the usage amount of Eu, the luminescence center. Also provided are a display device (PDP, etc) and a fluorescent lamp having excellent display and/or luminescence characteristics as a result of using the phosphors, while achieving manufacturing cost reductions by minimizing the Eu usage amount.
摘要翻译： 提供具有高发光特性的荧光体，同时通过使Eu的发光中心的使用量最小化来实现制造成本的降低。 还提供了作为使用荧光体的结果，具有优异的显示和/或发光特性的显示装置（PDP等）和荧光灯，同时通过使Eu使用量最小化来实现制造成本的降低。
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18.发明申请Phosphors and related manufacturing method, display device, and fluorescent lamp 有权荧光体及相关制造方法，显示装置和荧光灯公开(公告)号：US20050017218A1
公开(公告)日：2005-01-27
申请号：US10867121
申请日：2004-06-14
CPC分类号： H01J1/63 , C09K11/7734
摘要： Phosphors having high luminescence characteristics are provided while achieving manufacturing cost reductions by minimizing the usage amount of Eu, the luminescence center. Also provided are a display device (PDP, etc) and a fluorescent lamp having excellent display and/or luminescence characteristics as a result of using the phosphors, while achieving manufacturing cost reductions by minimizing the Eu usage amount.
摘要翻译： 提供具有高发光特性的荧光体，同时通过使Eu的发光中心的使用量最小化来实现制造成本的降低。 还提供了作为使用荧光体的结果，具有优异的显示和/或发光特性的显示装置（PDP等）和荧光灯，同时通过使Eu使用量最小化来实现制造成本的降低。
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公开(公告)号：US07465413B2
公开(公告)日：2008-12-16
申请号：US11121662
申请日：2005-05-04
CPC分类号： C09K11/7797 , C09K11/676 , C09K11/685 , C09K11/7734 , H01J11/12 , H01J11/42
摘要： A phosphor of the present invention is characterized by: having a phosphor main portion containing zinc silicate as a base material and manganese as an activator; and having at least one element from among titanium (Ti), zirconium (Zr), and hafnium (Hf), or having at least one element from among molybdenum (Mo) and tungsten (W), added to the phosphor main portion. The phosphor with such a composition is capable of precisely controlling the composition of a surface region (i.e. the surface including the vicinity) of each phosphor particle and improving the crystallinity, which leads to a high luminous efficiency and a reduction in time-lapse degradation.
摘要翻译： 本发明的荧光体的特征在于：具有含有硅酸锌作为基体的荧光体主体部分，锰作为活化剂; 并且具有钛（Ti），锆（Zr）和铪（Hf）中的至少一种元素，或者在钼（Mo）和钨（W）中）具有至少一种元素。 具有这种组成的荧光体能够精确地控制每个荧光体颗粒的表面区域（即包括附近的表面）的组成并提高结晶度，这导致高发光效率和延时降解的减少。
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20.发明申请公开(公告)号：US20050263742A1
公开(公告)日：2005-12-01
申请号：US11130905
申请日：2005-05-17
CPC分类号： C09K11/7797 , C09K11/595 , C09K11/7734 , H01J11/12 , H01J11/42
摘要： A manganese-activated zinc silicate phosphor according to the present invention satisfies 0
摘要翻译： 根据本发明的锰活化的硅酸锌荧光体满足0≤β≤α≤0.5和1.7≤β，其中α是表面区域中锌原子数与硅原子数之比 的荧光体颗粒，包括荧光体颗粒的表面及其附近，值β是整个荧光体颗粒中的锌原子数与硅原子数的比率。
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