Manufacturing method of polyaspartic acid using maleic anhydride
    11.
    发明授权
    Manufacturing method of polyaspartic acid using maleic anhydride 有权
    使用马来酸酐制备聚天冬氨酸的方法

    公开(公告)号:US08729218B2

    公开(公告)日:2014-05-20

    申请号:US12442886

    申请日:2007-04-17

    IPC分类号: C08G73/10 C08G69/00

    CPC分类号: C08G73/1092

    摘要: The present invention relates to a manufacturing method of polyaspartic acid. More particularly, the present invention relates to a manufacturing method of polyaspartic acid comprising steps of carrying out condensation polymerization of maleic anhydride and ammonia in the presence of a polar solvent without active hydrogen to give polysuccinimide and hydrolyzing the resulting polysuccinimide to obtain polyaspartic acid. Specifically, the present invention is characterized in that the quality of the synthetic product, polysuccinimide and polyaspartic acid, is improved by minimizing the decomposition and the degradation of the maleic acid during the process of the polymerization resulted from the introduction of substituent to maleic acid.

    摘要翻译: 本发明涉及聚天冬氨酸的制造方法。 更具体地说,本发明涉及聚天冬氨酸的制造方法,其特征在于,在极性溶剂的存在下,在没有活性氢的情况下,进行马来酸酐和氨的缩聚反应,得到聚琥珀酰亚胺,水解得到的聚琥珀酰亚胺,得到聚天冬氨酸。 具体地说,本发明的特征在于,通过使由马来酸引入取代基引起的聚合过程中马来酸的分解和降解最小化来改善合成产物,聚琥珀酰亚胺和聚天冬氨酸的质量。

    Selective membrane having a high fouling resistance
    12.
    发明授权
    Selective membrane having a high fouling resistance 有权
    选择性膜具有高耐污性

    公开(公告)号:US07913857B2

    公开(公告)日:2011-03-29

    申请号:US11702917

    申请日:2007-02-06

    摘要: A selective membrane having a high fouling resistance. In one embodiment, the selective membrane is a composite polyamide reverse osmosis membrane in which a hydrophilic coating is applied to the polyamide layer of the membrane, the hydrophilic coating being made by covalently bonding a hydrophilic compound to residual acid chlorides of the polyamide membrane, the hydrophilic compound including (i) at least one reactive group that is adapted to covalently bond directly to the polyamide membrane, the at least one reactive group being at least one of a primary amine and a secondary amine; and (ii) at least one non-terminal hydroxyl group.

    摘要翻译: 具有高耐污性的选择性膜。 在一个实施方案中,选择性膜是复合聚酰胺反渗透膜,其中将亲水涂层施加到膜的聚酰胺层,亲水性涂层通过将亲水性化合物共价结合到聚酰胺膜的残留酰氯上而制备, 亲水性化合物,包括(i)至少一种适于与聚酰胺膜直接共价结合的反应性基团,所述至少一种反应性基团是伯胺和仲胺中的至少一种; 和(ii)至少一个非末端羟基。

    Manufacturing Method of Polyaspartic Acid Using Maleic Anhydride
    13.
    发明申请
    Manufacturing Method of Polyaspartic Acid Using Maleic Anhydride 有权
    使用马来酸酐制备聚天冬氨酸的方法

    公开(公告)号:US20100076161A1

    公开(公告)日:2010-03-25

    申请号:US12442886

    申请日:2007-04-17

    IPC分类号: C08G69/48

    CPC分类号: C08G73/1092

    摘要: The present invention relates to a manufacturing method of polyaspartic acid. More particularly, the present invention relates to a manufacturing method of polyaspartic acid comprising steps of carrying out condensation polymerization of maleic anhydride and ammonia in the presence of a polar solvent without active hydrogen to give polysuccinimide and hydrolyzing the resulting polysuccinimide to obtain polyaspartic acid. Specifically, the present invention is characterized in that the quality of the synthetic product, polysuccinimide and polyaspartic acid, is improved by minimizing the decomposition and the degradation of the maleic acid during the process of the polymerization resulted from the introduction of substituent to maleic acid.

    摘要翻译: 本发明涉及聚天冬氨酸的制造方法。 更具体地说,本发明涉及聚天冬氨酸的制造方法,其特征在于,在极性溶剂的存在下,在没有活性氢的情况下,进行马来酸酐和氨的缩聚反应,得到聚琥珀酰亚胺,水解得到的聚琥珀酰亚胺,得到聚天冬氨酸。 具体地说,本发明的特征在于,通过使由马来酸引入取代基引起的聚合过程中马来酸的分解和降解最小化来改善合成产物,聚琥珀酰亚胺和聚天冬氨酸的质量。

    Selective membrane having a high fouling resistance
    14.
    发明授权
    Selective membrane having a high fouling resistance 有权
    具有高耐污性的选择性膜

    公开(公告)号:US07537697B2

    公开(公告)日:2009-05-26

    申请号:US11345192

    申请日:2006-02-01

    摘要: A selective membrane having a high fouling resistance. In one embodiment, the selective membrane is a composite polyamide reverse osmosis membrane in which a hydrophilic coating is applied to the polyamide layer of the membrane, the hydrophilic coating being made by covalently bonding a hydrophilic compound to residual acid chlorides of the polyamide membrane, the hydrophilic compound including (i) at least one reactive group that is adapted to covalently bond directly to the polyamide membrane, the at least one reactive group being at least one of a primary amine and a secondary amine; and (ii) at least one hydrophilic group, the at least one hydrophilic group being selected from the group consisting of a hydroxyl group, a carbonyl group, a trialkoxysilane group, an anionic group and a tertiary amino group; (iii) wherein the hydrophilic compound is devoid of a polyalkylene oxide group.

    摘要翻译: 具有高耐污性的选择性膜。 在一个实施方案中,选择性膜是复合聚酰胺反渗透膜,其中将亲水涂层施加到膜的聚酰胺层,亲水性涂层通过将亲水性化合物共价结合到聚酰胺膜的残留酰氯上而制备, 亲水性化合物,包括(i)至少一种适于与聚酰胺膜直接共价结合的反应性基团,所述至少一种反应性基团是伯胺和仲胺中的至少一种; 和(ii)至少一个亲水基团,所述至少一个亲水基团选自羟基,羰基,三烷氧基硅烷基,阴离子基和叔氨基; (iii)其中亲水性化合物没有聚环氧烷基团。

    Composite polyamide reverse osmosis membrane and method of producing the same
    15.
    发明授权
    Composite polyamide reverse osmosis membrane and method of producing the same 失效
    复合聚酰胺反渗透膜及其制备方法

    公开(公告)号:US07479300B2

    公开(公告)日:2009-01-20

    申请号:US11094562

    申请日:2005-03-30

    IPC分类号: B01D5/00 B29C65/00 B29C67/20

    摘要: A composite polyamide reverse osmosis membrane and method of producing same. In a preferred embodiment, the membrane is made by coating a porous polysulfone support with an aqueous solution containing 2 wt % m-phenylenediamine (MPD), and 0.1 wt % di(ethylene glycol) hexyl methyl ether. Next, the excess solution is removed, and the coated support is dipped in 0.1 wt % organic solvent solution of trimesoyl chloride (TMC) in a mixture of alkanes having from 8 to 12 carbon atoms. After draining the TMC solution off, the resulting composite membrane is air dried and then rinsed in a basic aqueous solution. The resultant membrane exhibits a flux of 21.3 gfd and a salt rejection of 98.9% when used at 225 psi for an aqueous solution containing 2000 ppm of NaCl.

    摘要翻译: 一种复合聚酰胺反渗透膜及其制造方法。 在优选的实施方案中,膜是通过用含有2重量%间苯二胺(MPD)和0.1重量%二(乙二醇)己基甲基醚的水溶液涂覆多孔聚砜载体而制成的。 接下来,除去过量的溶液,将涂覆的载体浸渍在具有8至12个碳原子的烷烃的混合物中的均苯三酰氯(TMC)的0.1重量%有机溶剂溶液中。 排出TMC溶液后,将得到的复合膜进行空气干燥,然后在碱性水溶液中漂洗。 对于含有2000ppm NaCl的水溶液,当在225psi下使用时,得到的膜表现出21.3gfd的通量和98.9%的拒水率。

    ASCENDING/DESCENDING APPARATUS AND COMPLEX SINTERING FURNACE USING THE SAME
    16.
    发明申请
    ASCENDING/DESCENDING APPARATUS AND COMPLEX SINTERING FURNACE USING THE SAME 失效
    升级/降低设备和复合烧结炉使用相同

    公开(公告)号:US20070284793A1

    公开(公告)日:2007-12-13

    申请号:US11761752

    申请日:2007-06-12

    IPC分类号: C21C5/46

    摘要: Provided is a complex sintering furnace to sequentially perform a bake-out process and a sintering process for molding ceramic products. The complex sintering furnace includes: a support frame; a pair of furnace bodies supported on the top of the support frame and having a built-in heat insulator covered by a disc-shaped cover; a pair of rails arranged under the support frame in parallel in a length direction along arrangement of the furnace bodies; a rotating base horizontally transferred along the rails and rotatably connected to bottoms of the furnace bodies when the rotating base is vertically transferred directly under the bottoms of the furnace bodies, the rotating base including a separately rotating setter mounted the top thereof; and an ascending/descending apparatus mounted under the rotating bases and having a ball-screw type rotation shaft to vertically ascend/descend the rotating base at the same time of the separate rotation of the setters. Accordingly, the production efficiency of the ceramic products can be significantly improved by rapidly transferring to the post-processes and simultaneously performing the bake-out process and the sintering process.

    摘要翻译: 提供了一种复杂的烧结炉,用于顺序地进行烘烤工艺和用于模制陶瓷产品的烧结工艺。 复合烧结炉包括:支架; 一对炉体,其支撑在支撑框架的顶部上,并具有由盘状盖子覆盖的内置隔热材料; 一对轨道,其沿着所述炉体的排列沿长度方向平行布置在所述支撑框架下方; 当旋转底座直接在炉体底部垂直转移时,沿着轨道水平传递的旋转底座可旋转地连接到炉体的底部,旋转底座包括安装在其顶部的单独旋转的固定器; 以及安装在旋转底座下方并具有滚珠丝杠式旋转轴的上升/下降装置,以在固定器的分离旋转的同时垂直地上升/下降旋转底座。 因此,通过快速转移到后处理并同时进行烘焙处理和烧结工艺,可以显着提高陶瓷产品的生产效率。

    Selective membrane having a high fouling resistance
    17.
    发明申请
    Selective membrane having a high fouling resistance 有权
    具有高耐污性的选择性膜

    公开(公告)号:US20070175821A1

    公开(公告)日:2007-08-02

    申请号:US11702917

    申请日:2007-02-06

    IPC分类号: B01D39/00

    摘要: A selective membrane having a high fouling resistance. In one embodiment, the selective membrane is a composite polyamide reverse osmosis membrane in which a hydrophilic coating is applied to the polyamide layer of the membrane, the hydrophilic coating being made by covalently bonding a hydrophilic compound to residual acid chlorides of the polyamide membrane, the hydrophilic compound including (i) at least one reactive group that is adapted to covalently bond directly to the polyamide membrane, the at least one reactive group being at least one of a primary amine and a secondary amine; and (ii) at least one non-terminal hydroxyl group.

    摘要翻译: 具有高耐污性的选择性膜。 在一个实施方案中,选择性膜是复合聚酰胺反渗透膜,其中将亲水涂层施加到膜的聚酰胺层,亲水性涂层通过将亲水性化合物共价结合到聚酰胺膜的残留酰氯上而制备, 亲水性化合物,包括(i)至少一种适于与聚酰胺膜直接共价结合的反应性基团,所述至少一种反应性基团是伯胺和仲胺中的至少一种; 和(ii)至少一个非末端羟基。