公开(公告)号：US20070010630A1

公开(公告)日：2007-01-11

申请号：US10569139

申请日：2004-08-27

申请人： Ryo Aburatani ,  Masanori Sera ,  Yutaka Minami

发明人： Ryo Aburatani ,  Masanori Sera ,  Yutaka Minami

IPC分类号： C08F10/00

CPC分类号： C08F8/20 ,  C08F2/00 ,  C08F14/02 ,  Y10S526/943 ,  C08F10/06

摘要： A chlorinated propylene-based polymer of the present invention having a weight average molecular weight (Mw) as measured by gel permeation chromatography (GPC) of 5,000 to 100,000 and a chlorine content of 0.1 to 70% by mass has the following properties: (1) it has a high solubility in a non-aromatic solvent having a low environmental burden even when it has a low degree of chlorination, and (2) it can be inhibited from suffering a decrease in the properties inherent to polypropylenes, such as durability, mechanical properties, appearance and hydrophobicity, by regulating its degree of chlorination at a low value.

摘要翻译： 通过凝胶渗透色谱法（GPC）测定的重均分子量（Mw）为5,000〜100,000，氯含量为0.1〜70质量％的本发明的氯化丙烯系聚合物具有以下性质：（1 ）即使氯化程度低，也具有环境负荷低的非芳香族溶剂的高溶解性，（2）能够抑制聚丙烯固有的性能降低等耐久性， 机械性能，外观和疏水性，通过将其氯化度调节到较低值。

公开(公告)号：US07109283B2

公开(公告)日：2006-09-19

申请号：US11324304

申请日：2006-01-04

申请人： Yutaka Minami ,  Takenori Fujimura ,  Masanori Sera ,  Tomoaki Takebe

发明人： Yutaka Minami ,  Takenori Fujimura ,  Masanori Sera ,  Tomoaki Takebe

IPC分类号： C08F10/14

CPC分类号： C08F210/14 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65927 ,  C08F2500/20 ,  C08F2500/03

摘要： The present invention provides a crystalline higher α-olefin copolymer obtained by copolymerizing at least two higher α-olefins having 10 or more carbon atoms or at least one higher α-olefin having 10 or more carbon atoms with at least one other olefin, wherein it satisfies certain conditions.

摘要翻译： 本发明提供通过使至少两种具有10个或更多个碳原子的高级α-烯烃或至少一个具有10个或更多个碳原子的高级α-烯烃与至少一种其它烯烃共聚得到的结晶高级α-烯烃共聚物，其中 满足一定条件。

公开(公告)号：US07019091B2

公开(公告)日：2006-03-28

申请号：US10925037

申请日：2004-08-25

申请人： Yutaka Minami ,  Takenori Fujimura ,  Masanori Sera ,  Tomoaki Takebe

发明人： Yutaka Minami ,  Takenori Fujimura ,  Masanori Sera ,  Tomoaki Takebe

IPC分类号： C08F4/642 ,  C08F210/14

CPC分类号： C08F210/14 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65927 ,  C08F2500/20 ,  C08F2500/03

摘要： The present invention provides a crystalline higher α-olefin copolymer obtained by copolymerizing at least two higher α-olefins having 10 or more carbon atoms or at least one higher α-olefin having 10 or more carbon atoms with at least one other olefin, wherein it satisfies certain conditions.

公开(公告)号：US07569642B2

公开(公告)日：2009-08-04

申请号：US10575109

申请日：2004-09-28

申请人： Ryo Aburatani ,  Masanori Sera ,  Yutaka Minami

发明人： Ryo Aburatani ,  Masanori Sera ,  Yutaka Minami

IPC分类号： C08F8/18 ,  C08F8/46 ,  C08F8/00 ,  C08F10/14

CPC分类号： C08F255/08 ,  C08F8/20 ,  C08F110/14 ,  C08F222/02 ,  C08F220/06

摘要： A higher olefin polymer having a polar group which is produced by subjecting to an incorporation reaction of a polar compound or halogen compound into a higher α-olefin polymer satisfying the requirements of the following (1) and (2), which is obtained by polymerizing one or more higher α-olefins having 10 or more carbon atoms or copolymerizing one or more higher α-olefins having 10 or more carbon atoms with one or more other olefins and a method for producing a higher olefin polymer having a polar group which is obtained by polymerizing one or more higher α-olefins having 10 or more carbon atoms or copolymerizing one or more higher α-olefins having 10 or more carbon atoms with one or more other olefins to form a higher α-olefins polymer satisfying the requirements of the following (1) and (2) and subsequently subjecting to an incorporation reaction of a polar compound or halogen compound into the higher α-olefin polymer. (1) The content of units of a higher α-olefins having 10 or more carbon atoms is 50 mol % or more. (2) A single peak X1 which is ascribed to the side chain crystallization and observed at 15 deg

摘要翻译： 具有极性基团的高级烯烃聚合物，其通过将极性化合物或卤素化合物的引入反应进入满足以下（1）和（2）的要求的高级α-烯烃聚合物中制备，所述高级α-烯烃聚合物通过聚合 一种或多种具有10个或更多个碳原子的高级α-烯烃或使一种或多种具有10个或更多碳原子的高级α-烯烃与一种或多种其它烯烃共聚，以及制备具有极性基团的高级烯烃聚合物的方法 通过聚合一种或多种具有10个或更多个碳原子的高级α-烯烃或将一个或多个具有10个或更多个碳原子的高级α-烯烃与一种或多种其它烯烃共聚以形成满足以下要求的较高级α-烯烃聚合物 （1）和（2），然后将极性化合物或卤素化合物的引入反应进入较高级的α-烯烃聚合物。 （1）碳原子数为10以上的高级α-烯烃的单元含量为50摩尔％以上。 （2）观察到归属于侧链结晶并在广角X射线散射强度分布中在15度<2度<30度观察到的单峰X1。

公开(公告)号：US20090018288A1

公开(公告)日：2009-01-15

申请号：US11718834

申请日：2005-11-07

申请人： Ryo Aburatani ,  Yutaka Obata ,  Tomoaki Takebe ,  Masanori Sera ,  Yutaka Minami

发明人： Ryo Aburatani ,  Yutaka Obata ,  Tomoaki Takebe ,  Masanori Sera ,  Yutaka Minami

IPC分类号： C08F10/14 ,  C08F8/00

CPC分类号： C08F10/14 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65927 ,  C08F8/00 ,  C08F110/14 ,  C08F210/14 ,  C08F2500/20 ,  C08F2500/04 ,  C08F2500/03

摘要： Crosslinked olefin polymers which are reduced in stickiness and improved in rigidity, heat resistance, light resistance, and water resistance while retaining the molding properties such as injection moldability, spinnability, film-forming properties and the physical properties such as toughness (including elongation and break strength) and tackiness; and a process for the production thereof. Crosslinked olefin polymers which are obtained by reacting an α-olefin polymer produced by polymerization of at least one α-olefin having 6 or more carbon atoms or polymerization of at least one α-olefin having 6 or more carbon atoms with at least one other α-olefin with a crosslinking agent and which satisfy the following requirements: (1) the content of units of α-olefins having 6 or more carbon atoms is 50 mol % or more, (2) the molecular weight distribution (Mw/Mn) as determined by gel permeation chromatography (GPC) is 7.0 or more in terms of polystyrene, (3) the content of components having weight-average molecular weights (Mw) of 106 or more is 5% by mass or more as determined by GPC, and (4) the stereoregularity indication M4 is 75 mol % or less; and a process for the production of the polymers.

摘要翻译： 在保持成型性，如注塑成型性，纺丝性，成膜性以及韧性（包括伸长率和断裂性等）的物理性能的同时，粘合性降低，刚性，耐热性，耐光性和耐水性降低的交联烯烃聚合物 强度）和粘性; 及其生产方法。 通过使至少一种具有6个或更多个碳原子的至少一种α-烯烃聚合而产生的α-烯烃聚合物或至少一种具有6个或更多个碳原子的至少一个碳原子的α-烯烃与至少一种其它的α-烯烃反应而获得的交联烯烃聚合物 （1）具有6个或更多个碳原子的α-烯烃的单元含量为50摩尔％以上，（2）分子量分布（Mw / Mn）为 通过凝胶渗透色谱法（GPC）测定的聚苯乙烯换算为7.0以上，（3）通过GPC测定，重均分子量（Mw）为106以上的成分的含量为5质量％以上， （4）立构规整性指示M4为75摩尔％以下; 以及聚合物的制造方法。

公开(公告)号：US20070079825A1

公开(公告)日：2007-04-12

申请号：US10577496

申请日：2004-10-27

申请人： Masanori Sera ,  Yutaka Minami ,  Takenori Fujimura

发明人： Masanori Sera ,  Yutaka Minami ,  Takenori Fujimura

IPC分类号： F24J2/34

CPC分类号： C09K5/063

摘要： The present invention relates to a heat storage material composition comprising 20 to 100% by weight of a heat storage material, 80 to 0% by weight of crystalline polyolefin (B) and 50 to 0% by weight of an elastomer (C), and the heat storage material described above contains a side chain-crystalline polymer (A), wherein the heat storage material described above comprises preferably a higher α-olefin polymer (a) containing 50 mole % or more of higher α-olefin having 10 or more carbon atoms and a petroleum wax (b) in which a melting point (Tm) is higher by 10° C. or more than that of the polymer (a). Provided is a heat storage material composition which has less bleeding and stickiness and is excellent in stability at high temperature and which can meet a change in temperature such as a difference in room temperature when applied to a material for floor heating and can avoid a heating state deviated to high temperature or low temperature.

摘要翻译： 本发明涉及一种储热材料组合物，其包含20至100重量％的蓄热材料，80至0重量％的结晶聚烯烃（B）和50至0重量％的弹性体（C），以及 上述储热材料含有侧链结晶聚合物（A），其中上述储热材料优选包含含有50摩尔％以上的具有10个或更多个的高级α-烯烃的高级α-烯烃聚合物（a） 碳原子和熔点（Tm）高于聚合物（a）的10℃以上的石油蜡（b）。 本发明提供一种蓄热材料组合物，其具有较少的渗透性和粘性，并且在高温下的稳定性优异，并且当施加到用于地板加热的材料时可以满足诸如室温差的温度变化并且可以避免加热状态 偏向高温或低温。

公开(公告)号：US20070073021A1

公开(公告)日：2007-03-29

申请号：US10575109

申请日：2004-09-28

申请人： Ryo Aburatani ,  Masanori Sera ,  Yutaka Minami

发明人： Ryo Aburatani ,  Masanori Sera ,  Yutaka Minami

IPC分类号： C08F20/06

CPC分类号： C08F255/08 ,  C08F8/20 ,  C08F110/14 ,  C08F222/02 ,  C08F220/06

摘要： A higher olefin polymer having a polar group which is produced by subjecting to an incorporation reaction of a polar compound or halogen compound into a higher α-olefin polymer satisfying the requirements of the following (1) and (2), which is obtained by polymerizing one or more higher α-olefins having 10 or more carbon atoms or copolymerizing one or more higher α-olefins having 10 or more carbon atoms with one or more other olefins and a method for producing a higher olefin polymer having a polar group which is obtained by polymerizing one or more higher α-olefins having 10 or more carbon atoms or copolymerizing one or more higher α-olefins having 10 or more carbon atoms with one or more other olefins to form a higher α-olefins polymer satisfying the requirements of the following (1) and (2) and subsequently subjecting to an incorporation reaction of a polar compound or halogen compound into the higher α-olefin polymer. (1) The content of units of a higher α-olefins having 10 or more carbon atoms is 50 mol % or more. (2) A single peak X1 which is ascribed to the side chain crystallization and observed at 15 deg

摘要翻译： 具有极性基团的高级烯烃聚合物，其通过将极性化合物或卤素化合物的引入反应进入满足以下（1）和（2）的要求的高级α-烯烃聚合物中制备，所述高级α-烯烃聚合物通过聚合 一种或多种具有10个或更多个碳原子的高级α-烯烃或使一种或多种具有10个或更多碳原子的高级α-烯烃与一种或多种其它烯烃共聚，以及制备具有极性基团的高级烯烃聚合物的方法 通过聚合一种或多种具有10个或更多个碳原子的高级α-烯烃或将一个或多个具有10个或更多个碳原子的高级α-烯烃与一种或多种其它烯烃共聚以形成满足以下要求的较高级α-烯烃聚合物 （1）和（2），然后将极性化合物或卤素化合物的引入反应进入较高级的α-烯烃聚合物。 （1）碳原子数为10以上的高级α-烯烃的单元含量为50摩尔％以上。 （2）观察到归属于侧链结晶并在广角X射线散射强度分布中在15度<2度<30度观察到的单峰X1。

公开(公告)号：US06486272B1

公开(公告)日：2002-11-26

申请号：US09926788

申请日：2001-12-19

申请人： Tetsuya Inoue ,  Masanori Sera

发明人： Tetsuya Inoue ,  Masanori Sera

IPC分类号： C08F4645

CPC分类号： C08F212/04

摘要： A process for producing a styrenic copolymer having a functional group and a syndiotactic configuration is provided. The process comprises bringing a metal compound into interaction with a vinyl compound having a functional group to mask the functional group and copolymerizing the vinyl compound having the masked functional group with a styrenic compound in the presence of a polymerization catalyst comprising (A) a transition metal compound, (B) at least one compound selected from compounds having oxygen and compounds which can form ionic complex compounds by reaction with the transition metal compound and (C) an organometallic compound. A styrenic copolymer which is a random, block or graft copolymer, preferably a random copolymer, of a vinyl compound having a functional group and a styrenic compound and has the repeating units derived from the styrenic compound having the syndiotactic configuration can be produced efficiently. The above styrenic random copolymer exhibits excellent physical properties such as excellent adhesion with various adhesives and excellent compatibility with various rubbers and is advantageously used for various applications as various types of molded articles.

摘要翻译： 提供了具有官能团和间同立构构型的苯乙烯类共聚物的制造方法。 该方法包括使金属化合物与具有官能团的乙烯基化合物相互作用以掩蔽该官能团并在具有（A）过渡金属的聚合催化剂的存在下将具有掩蔽官能团的乙烯基化合物与苯乙烯类化合物共聚 化合物，（B）至少一种选自具有氧的化合物的化合物和可以与过渡金属化合物反应形成离子络合物的化合物和（C）有机金属化合物。 可以有效地制造作为具有官能团的乙烯基化合物和苯乙烯类化合物的具有间同立构构型的苯乙烯类化合物的重复单元的随机，嵌段或接枝共聚物，优选无规共聚物的苯乙烯系共聚物。 上述苯乙烯类无规共聚物表现出优异的物理性能，例如与各种粘合剂的优异粘附性和与各种橡胶的优异相容性，并且有利地用于各种类型的模制品的各种应用。

公开(公告)号：US06359094B1

公开(公告)日：2002-03-19

申请号：US09926272

申请日：2001-10-04

申请人： Masanori Sera ,  Hajime Shouzaki

发明人： Masanori Sera ,  Hajime Shouzaki

IPC分类号： C08F1202

CPC分类号： C08F12/04 ,  C08F4/65912 ,  C08F12/08 ,  C08F4/6592

摘要： Provided is a styrenic polymer having a syndiotactic structure, of which the ratio P of the angular frequency, &ohgr;3000 (unit: rad/sec), when its storage elastic modulus G′ measured through dynamic viscoelastometry is 3000 (Pa), to the angular frequency thereof, &ohgr;30 (unit: rad/sec), when its storage elastic modulus G′ is 30 (Pa), P=[&ohgr;3000/&ohgr;30] satisfies the following formula (1): P=[&ohgr;3000/&ohgr;30]≧25  (1). The polymer has good melt flowability and improved moldability and melt tension, still having excellent mechanical strength, heat resistance and solvent resistance.

摘要翻译： 本发明提供具有间同立构结构的苯乙烯类聚合物，其通过动态粘弹法测定的储能弹性模量G'为3000（Pa）时的角频率ω3000（单位：弧度/秒）的比率P与角频率 其中，ωga30（单位：弧度/秒）当其储能弹性模量G'为30（Pa）时，P = [ω000/ω30]满足下式（1）：聚合物具有良好的熔体流动性和改善的成型性和熔融性 张力，仍然具有优异的机械强度，耐热性和耐溶剂性。

公开(公告)号：US07981959B2

公开(公告)日：2011-07-19

申请号：US11908292

申请日：2006-03-13

申请人： Akio Nodera ,  Yusuke Hayata ,  Masanori Sera ,  Takenori Fujimura

发明人： Akio Nodera ,  Yusuke Hayata ,  Masanori Sera ,  Takenori Fujimura

IPC分类号： C08K3/04 ,  C08J3/20

CPC分类号： C08J5/005 ,  B82Y30/00 ,  C08L23/24 ,  C08L69/00 ,  H01B1/24 ,  Y10S977/742 ,  C08L2666/06 ,  C08L2666/02

摘要： The present invention provides a resin composition including 100 parts by mass of a resin component containing 80 to 99 mass % of a thermoplastic resin (A) and 20 to 1 mass % of a side-chain crystalline polymer (B), and 0.1 to 30 parts by mass of carbon nanotube (C). The composition has a stabilized thermoplastic resin/side-chain crystalline polymer phase structure, is free from laminar peeling, and is excellent in conductive (antistatic) property, solvent resistance, flow characteristics, flame retardancy, impact resistance, molding appearance, etc.

摘要翻译： 本发明提供一种树脂组合物，其包含100质量份含有热塑性树脂（A）80〜99质量％和侧链结晶性聚合物（B）20〜1质量％的树脂成分，0.1〜30质量％ 质量份的碳纳米管（C）。 该组合物具有稳定的热塑性树脂/侧链结晶聚合物相结构，没有层状剥离，并且具有优异的导电性（抗静电）性，耐溶剂性，流动特性，阻燃性，耐冲击性，成型外观等。