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    Disentangled ultra high molecular weight polyethylene graft co-polymers and a process for preparation thereof
    4.
    发明授权
    Disentangled ultra high molecular weight polyethylene graft co-polymers and a process for preparation thereof 有权
    分离的超高分子量聚乙烯接枝共聚物及其制备方法

    公开(公告)号：US09574040B2

    公开(公告)日：2017-02-21

    申请号：US14427263

    申请日：2013-09-10

    Applicant: RELIANCE INDUSTRIES LIMITED

    Inventor： Satya Srinivasa Rao Gandham ,  Ajit Behari Mathur ,  Uma Sankar Satpathy ,  Krishna Renganath Sarma ,  Raksh Vir Jasra

    IPC: C08F255/02 ,  C08F255/10 ,  C08F255/08

    CPC classification number: C08F255/10 ,  C08F255/02 ,  C08F255/08 ,  C08F10/02 ,  C08F2/36

    Abstract: In accordance with the present disclosure, there is provided a solid state graft copolymerization process for the preparation of disentangled ultrahigh molecular weight polyethylene graft copolymers in which disentangled ultrahigh molecular weight polyethylene is admixed with at least one functional monomer and a free radical initiator to obtain a mixture; and the mixture thus obtained is subjected to solid state polymerization to obtain a graft copolymer of disentangled ultrahigh molecular weight polyethylene. The graft copolymers of disentangled ultrahigh molecular weight polyethylene shows better crystallization temperature that ranges between 117° C. to 121° C. and improved decomposition temperature (T100) that ranges between 460° C. to 480° C.

    Abstract translation: 根据本公开内容，提供了一种用于制备解缠结的超高分子量聚乙烯接枝共聚物的固态接枝共聚方法，其中将解开的超高分子量聚乙烯与至少一种官能单体和自由基引发剂混合以获得 混合物; 将由此获得的混合物进行固态聚合，得到解开的超高分子量聚乙烯的接枝共聚物。 分离的超高分子量聚乙烯的接枝共聚物显示出在117℃至121℃之间更好的结晶温度和在460℃至480℃之间改进的分解温度（T100）。

    Resin composition, and wire and cable using the same
    6.
    发明授权
    Resin composition, and wire and cable using the same 有权
    树脂组成，使用电线电缆

    公开(公告)号：US09127110B2

    公开(公告)日：2015-09-08

    申请号：US13474692

    申请日：2012-05-17

    Applicant: Keisuke Sugita ,  Ryutaro Kikuchi

    Inventor： Keisuke Sugita ,  Ryutaro Kikuchi

    IPC: C08F255/02 ,  C08C19/25 ,  C08F255/08 ,  C08J3/24 ,  C08K5/5415 ,  C08C19/28 ,  C09D123/08 ,  C08L51/06 ,  H01B3/44 ,  C08K5/5425

    CPC classification number: C08F255/02 ,  C08C19/25 ,  C08C19/28 ,  C08F255/08 ,  C08J3/24 ,  C08K5/5415 ,  C08K5/5425 ,  C08L51/06 ,  C08L2312/08 ,  C09D123/0815 ,  H01B3/441 ,  C08F230/08

    Abstract: A resin composition includes a silane-crosslinked polyethylene as a main component provided by crosslinking a polyethylene in the presence of a silanol condensation catalyst and water, the polyethylene being graft-copolymerized with a silane compound by a free radical generating agent. The polyethylene has a density of 0.87 to 0.91 g/cm3. The silane compound is included not less than 2 parts by mass relative to 100 parts by mass of the polyethylene. The resin composition includes silicon detected by a fluorescence X-ray at a rate of not less than 0.3 mass % and has a gel fraction of not less than 70%. A mass ratio of the silane compound to the free radical generating agent is not less than 35 and not more than 150.

    Abstract translation: 树脂组合物包括硅烷交联聚乙烯作为主要组分，其通过在硅烷醇缩合催化剂和水的存在下交联聚乙烯，所述聚乙烯通过自由基生成剂与硅烷化合物接枝共聚。 聚乙烯的密度为0.87〜0.91g / cm 3。 相对于100质量份的聚乙烯，硅烷化合物的含量不得少于2质量份。 树脂组合物包含通过荧光X射线以不小于0.3质量％的速率检测并具有不小于70％的凝胶分数的硅。 硅烷化合物与自由基发生剂的质量比不小于35且不大于150。

    ADHESIVE COMPOSITION AND IMAGE DISPLAY DEVICE USING SAME
    7.
    发明申请
    ADHESIVE COMPOSITION AND IMAGE DISPLAY DEVICE USING SAME 有权
    胶粘组合物和图像显示装置使用相同

    公开(公告)号：US20140370316A1

    公开(公告)日：2014-12-18

    申请号：US14344382

    申请日：2012-09-27

    Applicant: Mitsui Chemicals, Inc.

    Inventor： Yasushi Mizuta ,  Toshikazu Gomi

    IPC: C09J133/08 ,  C09J5/00 ,  G02F1/1333

    CPC classification number: C09J133/08 ,  C08F220/18 ,  C08F222/1006 ,  C08F255/08 ,  C08F257/02 ,  C08K5/0025 ,  C09J4/06 ,  C09J5/00 ,  C09J11/06 ,  C09J11/08 ,  C09J151/003 ,  C09J2433/00 ,  G02F1/1333 ,  G02F2202/28 ,  Y10T428/31935 ,  C08F2220/1883

    Abstract: The present invention provides an adhesive composition which has a cured product exhibiting high transparency and a high refractive index, and which has high adhesive strength and experiences little reduction in the adhesive strength, even when exposed to high temperatures. In order to achieve the above the adhesive composition includes: (1) a hydrocarbon polymer having a total light transmittance of visible light, as measured according to JIS K7361-1, of at least 80%; (2) at least one kind of (meth)acrylic monomer selected from a mono(meth)acrylic monomer having one (meth)acrylic group in a molecule and a di(meth)acrylic monomer having two (meth)acrylic groups in a molecule; and (3) a photoinitiator; wherein 30-190 parts by weight of component (2) are included relative to 100 parts by weight of component (1).

    Abstract translation: 本发明提供一种具有高透明度，高折射率的固化物的粘合剂组合物，即使暴露在高温下，也具有高的粘合强度和几乎不降低粘合强度的粘合剂组合物。 为了实现上述目的，粘合剂组合物包括：（1）根据JIS K7361-1测量的具有总可见光透射率的烃聚合物为至少80％; （2）至少一种选自分子中具有一个（甲基）丙烯酸基的单（甲基）丙烯酸单体和分子中具有两个（甲基）丙烯酸基的二（甲基）丙烯酸单体）的（甲基）丙烯酸单体 ; 和（3）光引发剂; 相对于100重量份组分（1），包含30-190重量份的组分（2）。

    Modified polyolefins
    8.
    发明授权
    Modified polyolefins 有权
    改性聚烯烃

    公开(公告)号：US08569417B2

    公开(公告)日：2013-10-29

    申请号：US13001668

    申请日：2009-07-02

    Applicant: Michael Backer ,  Francois De Buyl ,  Valerie Smits ,  Damien Deheunynck

    Inventor： Michael Backer ,  Francois De Buyl ,  Valerie Smits ,  Damien Deheunynck

    IPC: C08F255/00 ,  C08F255/02 ,  C08F8/12 ,  C08F8/42

    CPC classification number: C08F255/00 ,  C08F255/02 ,  C08F255/08 ,  C08L51/06 ,  C08L2666/02 ,  C09D151/06 ,  C09J151/06

    Abstract: The invention relates to a process for grafting hydrolysable silane groups to a polyolefin in which ethylene units, if present, form less than 50% by weight of the total polyolefin. The polyolefin is reacted with an unsaturated silane, having at least one hydrolysable group bonded to Si, or a hydrolysate thereof, in the presence of means capable of generating free radical sites in the polyolefin. The unsaturated silane has the formula R″—CH═CH—Z (I) or R″—C≡C—Z (II) in which Z represents an electron-withdrawing moiety substituted by a —SiRaR′(3-a) group wherein R represents a hydrolysable group; R′ represents a hydrocarbyl group having 1 to 6 carbon atoms; a has a value in the range 1 to 3 inclusive; and R″ represents hydrogen or a group having an electron withdrawing or any other activation effect with respect to the —CH═CH— or —C≡C— bond. The use of an unsaturated silane of the formula R″—CH═CH—Z (I) or R″—C≡C—Z (II) in carrying out the grafting reaction on the polyolefin may give enhanced grafting yield compared to grafting with an olefinically unsaturated silane such as vinyltrimethoxysilane not containing an electron withdrawing moiety Z. The invention permits to provide a silane-modified polyolefin having a high grafting efficiency while limiting/preventing polymer degradation by chain scission. The silane-modified polyolefin can be further reacted with a polar surface, a filler or a polar polymer or reacted on itself to crosslink the polyolefin and obtain enhanced physical properties of the composites made thereof.

    Abstract translation: 本发明涉及一种将可水解硅烷基接枝到聚烯烃上的方法，其中乙烯单元（如果存在的话）占总聚烯烃的小于50重量％。 在能够在聚烯烃中产生自由基位点的手段的存在下，聚烯烃与不饱和硅烷反应，所述不饱和硅烷具有与Si结合的至少一个可水解基团或其水解产物。 不饱和硅烷具有式R“-CH = CH-Z（I）或R”C = CZ（II），其中Z表示被-SiRaR'（3-a）基团取代的吸电子部分 其中R表示可水解基团; R'表示碳原子数1〜6的烃基。 a的值在1到3的范围内; R“表示氢或相对于-CH = CH-或-C = C-键具有吸电子或任何其它活化作用的基团。 在聚烯烃上进行接枝反应时，使用式R'-CH = CH-Z（I）或R“C = CZ（II）的不饱和硅烷可以提高接枝率， 烯属不饱和硅烷如不含吸电子部分Z的乙烯基三甲氧基硅烷。本发明允许提供具有高接枝效率的硅烷改性聚烯烃，同时通过链断裂限制/防止聚合物降解。 硅烷改性的聚烯烃可以进一步与极性表面，填料或极性聚合物反应，或者自身反应以使聚烯烃交联并获得由其制成的复合材料的增强的物理性能。

    RESIN COMPOSITION, AND WIRE AND CABLE USING THE SAME
    9.
    发明申请
    RESIN COMPOSITION, AND WIRE AND CABLE USING THE SAME 有权
    树脂组合物，使用它的电线和电缆

    公开(公告)号：US20120292077A1

    公开(公告)日：2012-11-22

    申请号：US13474692

    申请日：2012-05-17

    Applicant: Keisuke SUGITA ,  Ryutaro KIKUCHI

    Inventor： Keisuke SUGITA ,  Ryutaro KIKUCHI

    IPC: C08F255/02 ,  H01B3/44

    CPC classification number: C08F255/02 ,  C08C19/25 ,  C08C19/28 ,  C08F255/08 ,  C08J3/24 ,  C08K5/5415 ,  C08K5/5425 ,  C08L51/06 ,  C08L2312/08 ,  C09D123/0815 ,  H01B3/441 ,  C08F230/08

    Abstract: A resin composition includes a silane-crosslinked polyethylene as a main component provided by crosslinking a polyethylene in the presence of a silanol condensation catalyst and water, the polyethylene being graft-copolymerized with a silane compound by a free radical generating agent. The polyethylene has a density of 0.87 to 0.91 g/cm3. The silane compound is included not less than 2 parts by mass relative to 100 parts by mass of the polyethylene. The resin composition includes silicon detected by a fluorescence X-ray at a rate of not less than 0.3 mass % and has a gel fraction of not less than 70%. A mass ratio of the silane compound to the free radical generating agent is not less than 35 and not more than 150.

    Abstract translation: 树脂组合物包括硅烷交联聚乙烯作为主要组分，其通过在硅烷醇缩合催化剂和水的存在下交联聚乙烯，所述聚乙烯通过自由基生成剂与硅烷化合物接枝共聚。 聚乙烯的密度为0.87〜0.91g / cm 3。 相对于100质量份的聚乙烯，硅烷化合物的含量不得少于2质量份。 树脂组合物包含通过荧光X射线以不小于0.3质量％的速率检测并具有不小于70％的凝胶分数的硅。 硅烷化合物与自由基发生剂的质量比不小于35且不大于150。

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