公开(公告)号：US07981959B2

公开(公告)日：2011-07-19

申请号：US11908292

申请日：2006-03-13

申请人： Akio Nodera ,  Yusuke Hayata ,  Masanori Sera ,  Takenori Fujimura

发明人： Akio Nodera ,  Yusuke Hayata ,  Masanori Sera ,  Takenori Fujimura

IPC分类号： C08K3/04 ,  C08J3/20

CPC分类号： C08J5/005 ,  B82Y30/00 ,  C08L23/24 ,  C08L69/00 ,  H01B1/24 ,  Y10S977/742 ,  C08L2666/06 ,  C08L2666/02

摘要： The present invention provides a resin composition including 100 parts by mass of a resin component containing 80 to 99 mass % of a thermoplastic resin (A) and 20 to 1 mass % of a side-chain crystalline polymer (B), and 0.1 to 30 parts by mass of carbon nanotube (C). The composition has a stabilized thermoplastic resin/side-chain crystalline polymer phase structure, is free from laminar peeling, and is excellent in conductive (antistatic) property, solvent resistance, flow characteristics, flame retardancy, impact resistance, molding appearance, etc.

摘要翻译： 本发明提供一种树脂组合物，其包含100质量份含有热塑性树脂（A）80〜99质量％和侧链结晶性聚合物（B）20〜1质量％的树脂成分，0.1〜30质量％ 质量份的碳纳米管（C）。 该组合物具有稳定的热塑性树脂/侧链结晶聚合物相结构，没有层状剥离，并且具有优异的导电性（抗静电）性，耐溶剂性，流动特性，阻燃性，耐冲击性，成型外观等。

公开(公告)号：US20090076195A1

公开(公告)日：2009-03-19

申请号：US11908292

申请日：2006-03-13

申请人： Akio Nodera ,  Yusuke Hayata ,  Masanori Sera ,  Takenori Fujimura

发明人： Akio Nodera ,  Yusuke Hayata ,  Masanori Sera ,  Takenori Fujimura

IPC分类号： C08L23/24 ,  C08L69/00 ,  C08L25/10 ,  C08K3/04 ,  C08L71/12

CPC分类号： C08J5/005 ,  B82Y30/00 ,  C08L23/24 ,  C08L69/00 ,  H01B1/24 ,  Y10S977/742 ,  C08L2666/06 ,  C08L2666/02

摘要： The present invention provides a resin composition including 100 parts by mass of a resin component containing to 99 mass % of a thermoplastic resin (A) and 20 to 1 mass % of a side-chain crystalline polymer (B), and 0.1 to 30 parts by mass of carbon nanotube (C). The composition has a stabilized thermoplastic resin/side-chain crystalline polymer phase structure, is free from laminar peeling, and is excellent in conductive (antistatic) property, solvent resistance, flow characteristics, flame retardancy, impact resistance, molding appearance, etc.

摘要翻译： 本发明提供一种树脂组合物，其含有100质量份含有99质量％的热塑性树脂（A）和20〜1质量％的侧链结晶性聚合物（B）的树脂成分，以及0.1〜30份 的碳纳米管（C）。 该组合物具有稳定的热塑性树脂/侧链结晶聚合物相结构，没有层状剥离，并且具有优异的导电性（抗静电）性，耐溶剂性，流动特性，阻燃性，耐冲击性，成型外观等。

公开(公告)号：US07214755B2

公开(公告)日：2007-05-08

申请号：US10505046

申请日：2003-02-19

申请人： Yutaka Minami ,  Masami Kanamaru ,  Masanori Sera ,  Tatsuya Egawa ,  Takenori Fujimura

发明人： Yutaka Minami ,  Masami Kanamaru ,  Masanori Sera ,  Tatsuya Egawa ,  Takenori Fujimura

IPC分类号： C08F110/14 ,  C08F210/14 ,  C08F4/6192

CPC分类号： C08F110/14 ,  C08F10/00 ,  C08F4/65927 ,  C08F2500/17 ,  C08F2500/03 ,  C08F2500/20 ,  C08F2500/18 ,  C08F2500/15

摘要： A crystalline higher α-olefin polymer which is obtained from a C10 or more α-olefin and satisfies either (1) the melting point (Tm) as measured with a differential scanning calorimeter (DSC) is 20 to 100° C. or (2) in an examination of spin-lattice relaxation time (T1) by solid NMR analysis, a single T1 is observed at the temperatures not lower than the melting point; and a process for producing the α-olefin polymer with a specific metallocene catalyst. The crystalline higher α-olefin polymer is excellent in low-temperature characteristics, rigidity, heat resistance, compatibility with lubricating oils, mixability with inorganic fillers, and secondary processability.

摘要翻译： 由差示扫描量热仪（DSC）测得的，由C 10〜10以上的α-烯烃得到的满足（1）熔点（Tm）的结晶高级α-烯烃聚合物为20 至（100）℃，或（2）在通过固体NMR分析检查自旋晶格弛豫时间（T 1 N 2）时，在温度下观察到单个T 1 不低于熔点; 以及用特定的茂金属催化剂生产α-烯烃聚合物的方法。 结晶高级α-烯烃聚合物的低温特性，刚性，耐热性，与润滑油的相容性，与无机填料的混合性以及二次加工性优异。

公开(公告)号：US20060111526A1

公开(公告)日：2006-05-25

申请号：US11324304

申请日：2006-01-04

申请人： Yutaka Minami ,  Takenori Fujimura ,  Masanori Sera ,  Tomoaki Takebe

发明人： Yutaka Minami ,  Takenori Fujimura ,  Masanori Sera ,  Tomoaki Takebe

IPC分类号： C08F4/44

CPC分类号： C08F210/14 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65927 ,  C08F2500/20 ,  C08F2500/03

摘要： An object of the present invention is to provide crystalline high α-olefin copolymers which have excellent compatibility with thermoplastic resins, especially polyolefins, and compatibility with lubricant oils, fuel oils or waxes, excellent miscibility with inorganic fillers and secondary processability, and which have narrow temperature ranges for melting and crystallization, and to provide a process for preparation thereof. The present invention provides a crystalline higher α-olefin copolymer obtained by copolymerizing at least two higher α-olefins having 10 or more carbon atoms or at least one higher α-olefin having 10 or more carbon atoms with at least one other olefin, wherein it satisfies the following (1) to (3): (1): the content of higher α-olefin units is 50 mol % or greater, (2): the melting point (Tm) which is measured, by using a differential scanning calorimeter (DSC), from the melting endothermic curve obtained by maintaining the copolymer at 190° C. for 5 minutes under a nitrogen atmosphere, cooling it to −10° C. at a rate of 5° C./min, maintaining it at −10° C. for 5 minutes, and then elevating its temperature to 190° C. at 10° C./min is in the range of 20 to 100° C., and (3): in the intensity distribution of wide-angle X-ray scattering, a single peak X1 resulting from crystallization of side chains is observed at 15 deg

摘要翻译： 本发明的目的是提供与热塑性树脂特别是聚烯烃具有优异相容性的结晶高α-烯烃共聚物，与润滑油，燃料油或蜡的相容性，与无机填料的混溶性和二次加工性，并且具有窄 熔化和结晶的温度范围，并提供其制备方法。 本发明提供通过使至少两种具有10个或更多个碳原子的高级α-烯烃或至少一个具有10个或更多个碳原子的高级α-烯烃与至少一种其它烯烃共聚得到的结晶高级α-烯烃共聚物，其中 满足以下（1）〜（3）：（1）：高级α-烯烃单元的含量为50摩尔％以上，（2）：使用差示扫描量热计测定的熔点（Tm） （DSC）中，从在氮气气氛下将共聚物在190℃下保持5分钟而获得的熔融吸热曲线，以5℃/ min的速度将其冷却至-10℃， 10℃下5分钟，然后在10℃/分钟将其温度升至190℃/分钟在20至100℃的范围内，和（3）：在广角度的强度分布 在15度<2度<30度观察到X射线散射，由侧链结晶产生的单峰X1。

公开(公告)号：US07714081B2

公开(公告)日：2010-05-11

申请号：US10577496

申请日：2004-10-27

申请人： Masanori Sera ,  Yutaka Minami ,  Takenori Fujimura

发明人： Masanori Sera ,  Yutaka Minami ,  Takenori Fujimura

IPC分类号： C08L23/00 ,  C08L23/02

CPC分类号： C09K5/063

摘要： The present invention relates to a heat storage material composition comprising 20 to 100% by weight of a heat storage material, 80 to 0% by weight of crystalline polyolefin (B) and 50 to 0% by weight of an elastomer (C), and the heat storage material described above contains a side chain-crystalline polymer (A), wherein the heat storage material described above comprises preferably a higher α-olefin polymer (a) containing 50 mole % or more of higher α-olefin having 10 or more carbon atoms and a petroleum wax (b) in which a melting point (Tm) is higher by 10° C. or more than that of the polymer (a). Provided is a heat storage material composition which has less bleeding and stickiness and is excellent in stability at high temperature and which can meet a change in temperature such as a difference in room temperature when applied to a material for floor heating and can avoid a heating state deviated to high temperature or low temperature.

摘要翻译： 本发明涉及一种储热材料组合物，其包含20至100重量％的蓄热材料，80至0重量％的结晶聚烯烃（B）和50至0重量％的弹性体（C），以及 上述储热材料含有侧链状聚合物（A），其中上述储热材料优选包含含有50摩尔％以上的具有10个以上的高级α-烯烃的高级α-烯烃聚合物（a） 碳原子和熔点（Tm）高于聚合物（a）的10℃以上的石油蜡（b）。 本发明提供一种蓄热材料组合物，其具有较少的渗透性和粘性，并且在高温下的稳定性优异，并且当施加到用于地板加热的材料时可以满足诸如室温差的温度变化并且可以避免加热状态 偏向高温或低温。

公开(公告)号：US07109283B2

公开(公告)日：2006-09-19

申请号：US11324304

申请日：2006-01-04

申请人： Yutaka Minami ,  Takenori Fujimura ,  Masanori Sera ,  Tomoaki Takebe

发明人： Yutaka Minami ,  Takenori Fujimura ,  Masanori Sera ,  Tomoaki Takebe

IPC分类号： C08F10/14

CPC分类号： C08F210/14 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65927 ,  C08F2500/20 ,  C08F2500/03

摘要： The present invention provides a crystalline higher α-olefin copolymer obtained by copolymerizing at least two higher α-olefins having 10 or more carbon atoms or at least one higher α-olefin having 10 or more carbon atoms with at least one other olefin, wherein it satisfies certain conditions.

摘要翻译： 本发明提供通过使至少两种具有10个或更多个碳原子的高级α-烯烃或至少一个具有10个或更多个碳原子的高级α-烯烃与至少一种其它烯烃共聚得到的结晶高级α-烯烃共聚物，其中 满足一定条件。

公开(公告)号：US07019091B2

公开(公告)日：2006-03-28

申请号：US10925037

申请日：2004-08-25

申请人： Yutaka Minami ,  Takenori Fujimura ,  Masanori Sera ,  Tomoaki Takebe

发明人： Yutaka Minami ,  Takenori Fujimura ,  Masanori Sera ,  Tomoaki Takebe

IPC分类号： C08F4/642 ,  C08F210/14

CPC分类号： C08F210/14 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65927 ,  C08F2500/20 ,  C08F2500/03

摘要： The present invention provides a crystalline higher α-olefin copolymer obtained by copolymerizing at least two higher α-olefins having 10 or more carbon atoms or at least one higher α-olefin having 10 or more carbon atoms with at least one other olefin, wherein it satisfies certain conditions.

公开(公告)号：US20050119374A1

公开(公告)日：2005-06-02

申请号：US10505046

申请日：2003-02-19

申请人： Yutaka Minami ,  Masami Kanamaru ,  Masanori Sera ,  Tatsuya Egawa ,  Takenori Fujimura

发明人： Yutaka Minami ,  Masami Kanamaru ,  Masanori Sera ,  Tatsuya Egawa ,  Takenori Fujimura

IPC分类号： C08F4/642 ,  C08F10/00 ,  C08F110/14 ,  C08L67/00

CPC分类号： C08F110/14 ,  C08F10/00 ,  C08F4/65927 ,  C08F2500/17 ,  C08F2500/03 ,  C08F2500/20 ,  C08F2500/18 ,  C08F2500/15

摘要： A crystalline higher (x-olefin polymer which is obtained from a C10 or more α-olefin and satisfies either (1) the melting point (Tm) as measured with a differential scanning calorimeter (DSC) is 20 to 100° C. or (2) in an examination of spin-lattice relaxation time (T1) by solid NMR analysis, a single T1 is observed at the temperatures not lower than the melting point; and a process for producing the α-olefin polymer with a specific metallocene catalyst. The crystalline higher α-olefin polymer is excellent in low-temperature characteristics, rigidity, heat resistance, compatibility with lubricating oils, mixability with inorganic fillers, and secondary processability.

摘要翻译： 由差示扫描量热仪（DSC）测得的结晶高（X-α-烯烃聚合物，由C 10以上的α-烯烃得到并满足（1）熔点（Tm） 20至100℃或（2）通过固体NMR分析检查自旋晶格弛豫时间（T 1 N 2）时，在 不低于熔点的温度;以及用特定的茂金属催化剂生产α-烯烃聚合物的方法，结晶高级α-烯烃聚合物的低温特性，刚性，耐热性，与润滑油的相容性，混合性 无机填料，二次加工性能。

公开(公告)号：US20050049373A1

公开(公告)日：2005-03-03

申请号：US10925037

申请日：2004-08-25

申请人： Yutaka Minami ,  Takenori Fujimura ,  Masanori Sera ,  Tomoaki Takebe

发明人： Yutaka Minami ,  Takenori Fujimura ,  Masanori Sera ,  Tomoaki Takebe

IPC分类号： C08F4/645 ,  C08F4/659 ,  C08F4/6592 ,  C08F210/14 ,  C08F4/44

CPC分类号： C08F210/14 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65927 ,  C08F2500/20 ,  C08F2500/03

摘要： An object of the present invention is to provide crystalline high α-olefin copolymers which have excellent compatibility with thermoplastic resins, especially polyolefins, and compatibility with lubricant oils, fuel oils or waxes, excellent miscibility with inorganic fillers and secondary processability, and which have narrow temperature ranges for melting and crystallization, and to provide a process for preparation thereof. The present invention provides a crystalline higher α-olefin copolymer obtained by copolymerizing at least two higher α-olefins having 10 or more carbon atoms or at least one higher α-olefin having 10 or more carbon atoms with at least one other olefin, wherein it satisfies the following (1) to (3): (1): the content of higher α-olefin units is 50 mol % or greater, (2): the melting point (Tm) which is measured, by using a differential scanning calorimeter (DSC), from the melting endothermic curve obtained by maintaining the copolymer at 190° C. for 5 minutes under a nitrogen atmosphere, cooling it to −10° C. at a rate of 5° C./min, maintaining it at −10° C. for 5 minutes, and then elevating its temperature to 190° C. at 10° C./min is in the range of 20 to 100° C., and (3): in the intensity distribution of wide-angle X-ray scattering, a single peak X1 resulting from crystallization of side chains is observed at 15 deg

摘要翻译： 本发明的目的是提供与热塑性树脂特别是聚烯烃具有优异相容性的结晶高α-烯烃共聚物，与润滑油，燃料油或蜡的相容性，与无机填料的混溶性和二次加工性，并且具有窄 熔化和结晶的温度范围，并提供其制备方法。 本发明提供通过使至少两种具有10个或更多个碳原子的高级α-烯烃或至少一个具有10个或更多个碳原子的高级α-烯烃与至少一种其它烯烃共聚得到的结晶高级α-烯烃共聚物，其中 满足以下（1）〜（3）：（1）：高级α-烯烃单元的含量为50摩尔％以上，（2）：使用差示扫描量热计测定的熔点（Tm） （DSC）中，从在氮气气氛下将共聚物在190℃下保持5分钟而获得的熔融吸热曲线，以5℃/ min的速度将其冷却至-10℃， 10℃下5分钟，然后在10℃/分钟将其温度升至190℃/分钟在20至100℃的范围内，和（3）：在广角度的强度分布 在15度<2度<30度观察到X射线散射，由侧链结晶产生的单峰X1。

公开(公告)号：US20070079825A1

公开(公告)日：2007-04-12

申请号：US10577496

申请日：2004-10-27

申请人： Masanori Sera ,  Yutaka Minami ,  Takenori Fujimura

发明人： Masanori Sera ,  Yutaka Minami ,  Takenori Fujimura

IPC分类号： F24J2/34

CPC分类号： C09K5/063

摘要： The present invention relates to a heat storage material composition comprising 20 to 100% by weight of a heat storage material, 80 to 0% by weight of crystalline polyolefin (B) and 50 to 0% by weight of an elastomer (C), and the heat storage material described above contains a side chain-crystalline polymer (A), wherein the heat storage material described above comprises preferably a higher α-olefin polymer (a) containing 50 mole % or more of higher α-olefin having 10 or more carbon atoms and a petroleum wax (b) in which a melting point (Tm) is higher by 10° C. or more than that of the polymer (a). Provided is a heat storage material composition which has less bleeding and stickiness and is excellent in stability at high temperature and which can meet a change in temperature such as a difference in room temperature when applied to a material for floor heating and can avoid a heating state deviated to high temperature or low temperature.

摘要翻译： 本发明涉及一种储热材料组合物，其包含20至100重量％的蓄热材料，80至0重量％的结晶聚烯烃（B）和50至0重量％的弹性体（C），以及 上述储热材料含有侧链结晶聚合物（A），其中上述储热材料优选包含含有50摩尔％以上的具有10个或更多个的高级α-烯烃的高级α-烯烃聚合物（a） 碳原子和熔点（Tm）高于聚合物（a）的10℃以上的石油蜡（b）。 本发明提供一种蓄热材料组合物，其具有较少的渗透性和粘性，并且在高温下的稳定性优异，并且当施加到用于地板加热的材料时可以满足诸如室温差的温度变化并且可以避免加热状态 偏向高温或低温。