Catalytic process for continuously generating polyols
    11.
    发明授权
    Catalytic process for continuously generating polyols 有权
    用于连续生成多元醇的催化方法

    公开(公告)号:US08222464B2

    公开(公告)日:2012-07-17

    申请号:US13193200

    申请日:2011-07-28

    IPC分类号: C07C29/00 C07C31/18

    CPC分类号: C07C29/132 C07C31/20

    摘要: A catalytic process for generating at least one polyol from a feedstock comprising cellulose is performed in a continuous manner. The process involves, contacting, continuously, hydrogen, water, and a feedstock comprising cellulose, with a catalyst to generate an effluent stream comprising at least one polyol, water, hydrogen, and at least one co-product. The water, hydrogen, and at least one co-product are separated from the effluent stream and recycled to the reaction zone. The polyol is recovered from the effluent stream.

    摘要翻译: 以包含纤维素的原料生成至少一种多元醇的催化方法是以连续方式进行的。 该方法包括使含有纤维素的氢,水和原料与催化剂连续地接触,以产生包含至少一种多元醇,水,氢和至少一种共同产物的流出物流。 将水,氢和至少一种副产物与流出物流分离并再循环至反应区。 从流出物流中回收多元醇。

    PROCESS FOR GENERATION OF POLYOLS FROM SACCHARIDES
    14.
    发明申请
    PROCESS FOR GENERATION OF POLYOLS FROM SACCHARIDES 有权
    从SACCHARIDES生产聚合物的方法

    公开(公告)号:US20110313208A1

    公开(公告)日:2011-12-22

    申请号:US13192970

    申请日:2011-07-28

    IPC分类号: C07C29/00

    摘要: A process for generating at least one polyol from a feedstock comprising saccharide is performed in a continuous or batch manner. The process involves, contacting, hydrogen, water, and a feedstock comprising saccharide, with a catalyst system to generate an effluent stream comprising at least one polyol and recovering the polyol from the effluent stream. The catalyst system comprises at least one unsupported component and at least one supported component.

    摘要翻译: 以包含糖的原料生成至少一种多元醇的方法以连续或间歇的方式进行。 该方法包括使氢,水和包含糖的原料与催化剂体系接触以产生包含至少一种多元醇的流出物流并从流出物流中回收多元醇。 催化剂体系包含至少一种未负载的组分和至少一种负载的组分。

    Process for generation of polyols from saccharide containing feedstock
    17.
    发明授权
    Process for generation of polyols from saccharide containing feedstock 有权
    从含糖原料生成多元醇的方法

    公开(公告)号:US08222463B2

    公开(公告)日:2012-07-17

    申请号:US13193072

    申请日:2011-07-28

    IPC分类号: C07C29/00 C07C31/18

    CPC分类号: C07C29/132 C07C31/20

    摘要: A process for generating at least one polyol from a feedstock comprising saccharide is performed in a continuous or batch manner. The process involves, contacting hydrogen, water, and a feedstock comprising saccharide, with a catalyst system to generate an effluent stream comprising at least one polyol and recovering the polyol from the effluent stream. The catalyst system comprises at least one metal component with an oxidation state greater than or equal to 2+.

    摘要翻译: 以包含糖的原料产生至少一种多元醇的方法以连续或间歇方式进行。 该方法涉及使氢,水和包含糖的原料与催化剂体系接触以产生包含至少一种多元醇的流出物流并从流出物流中回收多元醇。 催化剂体系包含至少一种氧化态大于或等于2+的金属组分。

    Process for generation of polyols from saccharides
    18.
    发明授权
    Process for generation of polyols from saccharides 有权
    由糖生成多元醇的方法

    公开(公告)号:US08222462B2

    公开(公告)日:2012-07-17

    申请号:US13192970

    申请日:2011-07-28

    IPC分类号: C07C29/00 C07C31/18

    摘要: A process for generating at least one polyol from a feedstock comprising saccharide is performed in a continuous or batch manner. The process involves, contacting, hydrogen, water, and a feedstock comprising saccharide, with a catalyst system to generate an effluent stream comprising at least one polyol and recovering the polyol from the effluent stream. The catalyst system comprises at least one unsupported component and at least one supported component.

    摘要翻译: 以包含糖的原料生成至少一种多元醇的方法以连续或间歇的方式进行。 该方法包括使氢,水和包含糖的原料与催化剂体系接触以产生包含至少一种多元醇的流出物流并从流出物流中回收多元醇。 催化剂体系包含至少一种未负载的组分和至少一种负载的组分。

    Process for producing terephthalic acid
    19.
    发明授权
    Process for producing terephthalic acid 有权
    对苯二甲酸生产方法

    公开(公告)号:US08884055B2

    公开(公告)日:2014-11-11

    申请号:US13155553

    申请日:2011-06-08

    IPC分类号: C07C51/16 C07C51/265

    摘要: A solid terephthalic acid composition and a process for producing terephthalic acid from para-xylene. The process comprises forming a mixture comprising the para-xylene, a solvent, a bromine source, and a catalyst; and oxidizing the para-xylene by contacting the mixture with an oxidizing agent at oxidizing conditions to produce a solid oxidation product comprising terephthalic acid, para-toluic acid, 4-carboxybenzaldehyde. The solvent comprises a carboxylic acid having from 1 to 7 carbon atoms and an dialkyl imidazolium ionic liquid; and the catalyst comprises at least one of cobalt, titanium, manganese, chromium, copper, nickel, vanadium, iron, molybdenum, tin, cerium, and zirconium. The solid terephthalic acid composition comprises, less than about 4,000 ppm-wt 4-carboxybenzaldehyde content, and more than about 2,000 ppm-wt a para-toluic acid.

    摘要翻译: 固体对苯二甲酸组合物和由对二甲苯生产对苯二甲酸的方法。 该方法包括形成包含对二甲苯,溶剂,溴源和催化剂的混合物; 并通过在氧化条件下将氧化剂与氧化剂接触来氧化对二甲苯以产生包含对苯二甲酸,对甲苯甲酸,4-羧基苯甲醛的固体氧化产物。 溶剂包括具有1至7个碳原子的羧酸和二烷基咪唑鎓离子液体; 催化剂包括钴,钛,锰,铬,铜,镍,钒,铁,钼,锡,铈和锆中的至少一种。 固体对苯二甲酸组合物包含小于约4,000ppm重量的4-羧基苯甲醛含量和大于约2,000ppm重量的对甲苯甲酸。

    PROCESS FOR OXIDIZING ALKYL AROMATIC COMPOUNDS
    20.
    发明申请
    PROCESS FOR OXIDIZING ALKYL AROMATIC COMPOUNDS 有权
    用于氧化烷基芳族化合物的方法

    公开(公告)号:US20120004449A1

    公开(公告)日:2012-01-05

    申请号:US13155519

    申请日:2011-06-08

    摘要: A process and a mixture for oxidizing an alkyl-aromatic compound comprises forming a mixture comprising the alkyl-aromatic compound, a solvent, a bromine source, and a catalyst; and contacting the mixture with an oxidizing agent at oxidizing conditions to produce an oxidation product comprising at least one of an aromatic aldehyde, an aromatic alcohol, an aromatic ketone, and an aromatic carboxylic acid. The solvent comprises a carboxylic acid having from 1 to 7 carbon atoms and an ionic liquid selected from the group consisting of an imidazolium ionic liquid, a pyridinium ionic liquid, a phosphonium ionic liquid, a tetra alkyl ammonium ionic liquid, and combinations thereof. The catalyst comprises at least one of cobalt, titanium, manganese, chromium, copper, nickel, vanadium, iron, molybdenum, tin, cerium, and zirconium.

    摘要翻译: 用于氧化烷基 - 芳族化合物的方法和混合物包括形成包含烷基 - 芳族化合物,溶剂,溴源和催化剂的混合物; 以及在氧化条件下使所述混合物与氧化剂接触以产生包含芳族醛,芳族醇,芳族酮和芳族羧酸中的至少一种的氧化产物。 溶剂包括具有1至7个碳原子的羧酸和选自咪唑鎓离子液体,吡啶鎓离子液体,鏻离子液体,四烷基铵离子液体及其组合的离子液体。 催化剂包括钴,钛,锰,铬,铜,镍,钒,铁,钼,锡,铈和锆中的至少一种。