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    Process for the preparation of vinylaromatic polymers with a high degree of syndiotaxy
    12.
    发明授权
    Process for the preparation of vinylaromatic polymers with a high degree of syndiotaxy 失效
    制备具有高度间同立构的乙烯基芳族聚合物的方法

    公开(公告)号：US06174973B1

    公开(公告)日：2001-01-16

    申请号：US09415912

    申请日：1999-10-12

    申请人： Riccardo Po' ,  Luigi Abbondanza

    发明人： Riccardo Po' ,  Luigi Abbondanza

    IPC分类号： C08F1204

    CPC分类号： B01J31/26 ,  B01J31/143 ,  B01J31/2295 ,  B01J2531/46 ,  C08F4/65912 ,  C08F12/08 ,  C08F4/6592

    摘要： Process for the preparation of crystalline vinylaromatic polymers with a high degree of syndiotaxy which comprises polymerizing vinylaromatic monomers in the presence of a catalytic system essentially consisting of: a) a complex of titanium having the general formula: CpTiX1X2X3  (I) wherein Cp represents a cyclopentadienyl ligand whereas X1, X2, X3, the same or different, are selected from a halogen such as chlorine, or from alkyl groups, alkoxides, carboxylates, di(alkyl)amides; b) a polyalkylaluminoxane wherein the alkyl group contains from 1 to 8 carbon atoms; c) aluminum trifluoride.

    摘要翻译： 用于制备具有高度间同立构的结晶乙烯基芳族聚合物的方法，其包括在催化体系存在下聚合乙烯基芳族单体，所述催化体系基本上由以下组成：a）具有以下通式的钛络合物：其中Cp表示环戊二烯基配体，而X1， X2，X3相同或不同，选自卤素如氯或烷基，醇盐，羧酸盐，二（烷基）酰胺; b）其中烷基含有1至8个碳原子的聚烷基铝氧烷; c ）三氟化铝。

    COPOLYMERS FOR SOLAR CELLS BASED ON ACRIDONIC UNITS
    14.
    发明申请
    COPOLYMERS FOR SOLAR CELLS BASED ON ACRIDONIC UNITS 有权
    基于ACRIDONIC单位的太阳能电池共聚物

    公开(公告)号：US20130001474A1

    公开(公告)日：2013-01-03

    申请号：US13516857

    申请日：2010-12-15

    申请人： Maria Caldararo ,  Andrea Pellegrino ,  Giuliana Schimperna ,  Riccardo Po'

    发明人： Maria Caldararo ,  Andrea Pellegrino ,  Giuliana Schimperna ,  Riccardo Po'

    IPC分类号： C08G75/32 ,  C08G73/08 ,  H01B1/12

    CPC分类号： C07D409/14 ,  C08G61/122 ,  C08G61/123 ,  C08G61/126 ,  C08G2261/3241 ,  C08G2261/3246 ,  C08G2261/411 ,  C08G2261/91 ,  H01L51/0036 ,  H01L51/0043 ,  H01L51/4253 ,  Y02E10/549

    摘要： The present invention relates to copolymers for solar cells based on acridonic units comprising: a monomeric unit (A) having general formula (I) wherein X is S or Se, Y is 0, S or NR′ and R′, R′, the same or different, are C4-C24 alkyl groups, aryl groups optionally substituted with other functional groups, acyl groups or thioacyl groups; at least one monomer unit (B) having general formula (II) wherein Z is 0, S, Se or N—R″, wherein R″ is a C4-C24 alkyl group, an aryl group op-tionally substituted with other functional groups, an acyl group or thioacyl group, said monomeric unit (B) being connected to any position available of a hetero-aromatic side ring of the unit (A) through one of the two positions indicated by the dashed lines in general formula (II). Photovoltaic devices comprising said alternating π-conjugated polymers are also described.

    摘要翻译： 本发明涉及基于吖啶单体的太阳能电池用共聚物，包括：具有通式（I）的单体单元（A），其中X为S或Se，Y为0，S或NR'，R'，R'， 相同或不同的是C 4 -C 24烷基，任选被其它官能团取代的芳基，酰基或硫代酰基; 至少一种具有通式（II）的单体单元（B），其中Z为0，S，Se或N-R“，其中R”为C 4 -C 24烷基，被其它官能团取代的芳基 ，酰基或硫代酰基，所述单体单元（B）通过通式（II）中的虚线所示的两个位置之一连接到单元（A）的杂芳族侧环的任何位置上， 。 还描述了包含所述交替共轭聚合物的光伏器件。

    Process for the preparation of stable nitroxyl radicals
    17.
    发明授权
    Process for the preparation of stable nitroxyl radicals 有权
    制备稳定硝酰自由基的方法

    公开(公告)号：US07982052B2

    公开(公告)日：2011-07-19

    申请号：US12161283

    申请日：2007-02-09

    申请人： Maria Caldararo ,  Riccardo Po' ,  Marco Ricci

    发明人： Maria Caldararo ,  Riccardo Po' ,  Marco Ricci

    IPC分类号： C07D209/44

    CPC分类号： C07D209/46

    摘要： Process for the preparation of stable nitroxyl radicals (I) starting from N-benzylphthalimide in two steps. In the first step, the intermediate N-benzyl-1,1,3,3-tetra-alkylisoindoline is prepared by treatment with a Grignard reagent, prepared in methyl-tert-butyl ether, of N-benzylphthalimide, obtained in the same reaction environment starting from phthalic anhydride and benzylamine. In the second step, the N-benzyl-1,1,3,3-tetra-alkylisoindoline is transformed into the nitroxyl radical by hydrogenolysis and subsequent oxidation with hydrogen peroxide in the presence of a catalyst selected from acids and salts of polymolybdic or polytungstic acids.

    摘要翻译： 从N-苄基邻苯二甲酰亚胺开始制备稳定的硝酰基（I）的方法分两步进行。 在第一步中，中间体N-苄基-1,1,3,3-四烷基异吲哚啉通过用在相同反应中获得的N-苄基邻苯二甲酰亚胺的甲基叔丁基醚中制备的格氏试剂进行处理 环境从邻苯二甲酸酐和苄胺开始。 在第二步中，N-苄基-1,1,3,3-四烷基异吲哚啉通过氢解反应转化为硝酰基，随后在选自酸和多钼或多元酸的盐的催化剂存在下用过氧化氢氧化 酸。

    Process for the preparation of acrylonitrile copolymers with at least one (di) olefin
    18.
    发明授权
    Process for the preparation of acrylonitrile copolymers with at least one (di) olefin 失效
    用至少一种（二）烯烃制备丙烯腈共聚物的方法

    公开(公告)号：US5889129A

    公开(公告)日：1999-03-30

    申请号：US104240

    申请日：1998-06-25

    申请人： Riccardo Po' ,  Luisa Fiocca

    发明人： Riccardo Po' ,  Luisa Fiocca

    IPC分类号： C08F4/643 ,  C08F4/659 ,  C08F210/00 ,  C08F220/44 ,  C08F236/04 ,  C08F236/12

    CPC分类号： C08F210/00 ,  C08F220/44 ,  C08F236/04 ,  C08F110/06 ,  C08F4/65912 ,  Y10S526/943

    摘要： Process for the preparation of acrylonitrile copolymers with at least one (di)olefin which comprises reacting the monomers in the presence of a catalytic system essentially consisting of:i) a complex of zirconium having the general formula:ZrA.sub.a B.sub.b (I)wherein A represents a cyclopentadienyl, indenyl or fluorenyl group, B represents a hydrogen atom, a halogen or a C.sub.1 -C.sub.8 (iso)alkyl, alkoxyl or carboxyl radical;ii) an aluminumalkyl halide having the general formula:AlR.sub.n X.sub.m (II)wherein R represents a C.sub.1 -C.sub.4 (iso)alkyl group, X is a halogen.

    摘要翻译： 用至少一种（二）烯烃制备丙烯腈共聚物的方法，其包括在催化体系存在下使单体反应，所述催化体系基本上由以下组成：i）具有以下通式的锆的配合物：ZrAaBb（I）其中A表示 环戊二烯基，茚基或芴基，B表示氢原子，卤素或C1-C8（iso）烷基，烷氧基或羧基; ii）具有以下通式的铝烷基卤化物：AlRnXm（II）其中R表示C1-C4（iso）烷基，X是卤素。

    Process for the preparation of crystalline vinylaromatic polymers with a predominant syndiotactic structure
    19.
    发明授权
    Process for the preparation of crystalline vinylaromatic polymers with a predominant syndiotactic structure 失效
    制备具有主要间同立构结构的结晶乙烯基芳族聚合物的方法

    公开(公告)号：US5721327A

    公开(公告)日：1998-02-24

    申请号：US805247

    申请日：1997-02-24

    申请人： Roberto Santi ,  Giuseppe Cometti ,  Riccardo Po' ,  Nicoletta Cardi

    发明人： Roberto Santi ,  Giuseppe Cometti ,  Riccardo Po' ,  Nicoletta Cardi

    IPC分类号： C08F4/643 ,  C08F12/04 ,  C07F7/00

    CPC分类号： C08F12/04 ,  Y10S526/943

    摘要： Process for the preparation of crystalline vinylaromatic polymers with a predominant syndiotactic structure which involves polymerizing vinylaromatic monomers in the presence of a catalytic system comprising: a titanium complex having general formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4, the same or different, represent a hydrogen atom or a C.sub.1 -C.sub.20 alkyl radical or a C.sub.6 -C.sub.20 arylalkyl or aryl radical, on the condition that at least one of these is different from hydrogen.

    摘要翻译： 制备具有主要间同立构结构的结晶乙烯基芳族聚合物的方法，其包括在催化体系存在下聚合乙烯基芳族单体，包括：具有通式（I）的钛络合物：其中R1，R2，R3和 R 4相同或不同，表示氢原子或C 1 -C 20烷基或C 6 -C 20芳基烷基或芳基，条件是它们中的至少一个不同于氢。