公开(公告)号：US20170305832A1

公开(公告)日：2017-10-26

申请号：US15521353

申请日：2014-10-22

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Selvanathan Arumugam ,  John Ell ,  Bo Lu ,  Brandon Rowe ,  Jiguang Zhang

IPC: C07C67/26 ,  C07C69/587 ,  C07C67/58

CPC classification number: C07C67/26 ,  C07C67/58 ,  C07C69/587

Abstract: The present invention is a process for preparing a sorbate ester comprising the steps of: a) contacting together in a reaction vessel a first organic solvent, sorbic acid, a catalytic amount of TiC14, an anti-oxidant, and an alkylene oxide under conditions sufficient to form a mixture of the sorbate ester and residual water-soluble impurities; then b) separating the sorbate ester from the residual water-soluble impurities by washing. Sorbate esters can be prepared in an efficient and cost-effective manner by the process of the present invention.

公开(公告)号：US20170305831A1

公开(公告)日：2017-10-26

申请号：US15521319

申请日：2014-10-22

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Selvanathan Arumugam ,  John Ell ,  Bo Lu ,  Brandon Rowe ,  Kenneth E. Stockman ,  Jiguang Zhang

IPC: C07C67/26 ,  C07C69/587

CPC classification number: C07C67/26 ,  C07C69/587

Abstract: The present invention is a process for preparing a hydroxyalkyl sorbate comprising the steps of of: a) contacting together in a reaction vessel a solvent, sorbic acid, a transition metal halide catalyst, an anti-oxidant, and an alkylene oxide under conditions sufficient to form the hydroxyalkyl sorbate; b) removing the solvent in vacuo, wherein the anti-oxidant is characterized by the following formula or a carboxylic acid salt thereof: wherein Y, x, and R1 are defined herein. The process of the present invention provides a convenient way of preparing hydroxyalkyl sorbates in high yield and purity without complicated workup steps.

公开(公告)号：US20170037266A1

公开(公告)日：2017-02-09

申请号：US15303752

申请日：2014-04-16

Applicant: Rohm and Haas Company ,  Dow Global Technologies LLC

Inventor： Steven Arturo ,  Selvanathan Arumugam ,  Kebede Beshah ,  David Conner ,  John Ell ,  Ralph C. Even ,  Fujun Lu ,  Bo Lu ,  Brandon Rowe ,  Justin Sparks ,  Jianping Xu ,  Jiguang Zhang

IPC: C09D7/12 ,  C09D133/00

CPC classification number: C09D133/00 ,  C08K5/101 ,  C08K5/103 ,  C08K5/20 ,  C09D7/63

Abstract: The present invention is a composition comprising a stable aqueous dispersion of polymer particles and a sorbate ester, which is a liquid at 20° C. and has a molecular weight in the range of 125 to 500 g/mol. The composition of the present invention provides a way to enhance film formation of coatings prepared using relatively high Tg latexes without the aid of high volatile organic content (VOC) coalescents.

Abstract translation: 本发明是一种组合物，其包含稳定的聚合物颗粒水分散体和山梨酸酯，其在20℃是液体，分子量为125至500g / mol。 本发明的组合物提供了一种在没有高挥发性有机成分（VOC）聚结剂的帮助的情况下增强使用相对高Tg胶乳制备的涂料的成膜方法。