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    Process and composition for generation of acid
    11.
    发明授权
    Process and composition for generation of acid 失效
    生成酸的方法和组成

    公开(公告)号：US6110638A

    公开(公告)日：2000-08-29

    申请号：US757195

    申请日：1996-11-27

    申请人： Roger A. Boggs ,  Jurgen M. Grasshoff ,  Eric S. Kolb ,  John L. Marshall ,  Richard A. Minns ,  Socorro M. Ramos ,  Stephen G. Stroud ,  Stephen J. Telfer ,  Haixin Yang

    发明人： Roger A. Boggs ,  Jurgen M. Grasshoff ,  Eric S. Kolb ,  John L. Marshall ,  Richard A. Minns ,  Socorro M. Ramos ,  Stephen G. Stroud ,  Stephen J. Telfer ,  Haixin Yang

    IPC分类号： B41M5/30 ,  G03C1/73 ,  G03F7/004 ,  C03C1/492 ,  C03C1/494 ,  C03C1/76

    CPC分类号： B41M5/30 ,  G03C1/73 ,  G03F7/0045 ,  Y10S430/115

    摘要： A process for generation of acid uses a medium comprising a first acid-generating component capable of generating a first acid, and a secondary acid generator, this secondary acid generator being capable of thermal decomposition to form a secondary acid, the thermal decomposition of the secondary acid generator being catalyzed by the first acid. At least part of the medium is exposed to so as to cause formation of the first acid from the first acid-generating component; and the medium is then heated to cause, in the exposed part of the medium, acid-catalyzed thermal decomposition of the secondary acid generator and formation of the secondary acid. The secondary acid generator has a first site bearing a first leaving group and a second site bearing a second leaving group, the first leaving group being capable of protonation by the first acid, with expulsion of the first leaving group, followed by loss of a proton from the secondary acid generator to form an unstable intermediate, which then fragments with loss of the second leaving group, accompanied by either (a) loss of a second proton; or (b) addition of a proton-containing nucleophile, followed by loss of a proton, the second leaving group, in combination with a proton, forming the secondary acid. Preferred variants of the process are of the types described in U.S. Pat. Nos. 5,286,612; 5,334,489; 5,395,736; 5,441,850 and 5,453,345.

    摘要翻译： 酸的制造方法使用包含能够产生第一酸的第一产酸成分的培养基和二次酸发生剂，该二次酸发生剂能够热分解形成二次酸，二次酸的热分解 酸发生剂由第一种酸催化。 介质的至少一部分被暴露以便从第一产酸组分形成第一种酸; 然后将介质加热以在介质的暴露部分中引起二次酸发生器的酸催化热分解和二次酸的形成。 二次酸产生器具有带有第一离去基团的第一位点和带有第二离去基团的第二位点，第一离去基团能够被第一酸质子化，同时排出第一离去基团，然后丢失质子 从次级酸产生器形成不稳定的中间体，然后随着第二离去基团的损失而断裂，伴随着（a）第二质子的损失; 或者（b）加入含质子的亲核试剂，然后与质子组合丢失质子，第二离去基团与质子结合，形成二次酸。 该方法的优选变体是在美国专利No. 第5,286,612号; 5,334,489; 5,395,736; 5,441,850和5,453,345。

    Squarylium compounds, and processes and intermediates for the synthesis of these compounds
    17.
    发明授权
    Squarylium compounds, and processes and intermediates for the synthesis of these compounds 失效
    方酸化合物，以及用于合成这些化合物的方法和中间体

    公开(公告)号：US06482950B1

    公开(公告)日：2002-11-19

    申请号：US08479077

    申请日：1995-06-06

    申请人： Paulina P. Garcia ,  John W. Lee ,  John L. Marshall ,  Donald A. McGowan ,  Anthony J. Puttick ,  Thomas K. Spencer ,  Stephen G. Stroud ,  Stephen J. Telfer ,  Michael J. Zuraw

    发明人： Paulina P. Garcia ,  John W. Lee ,  John L. Marshall ,  Donald A. McGowan ,  Anthony J. Puttick ,  Thomas K. Spencer ,  Stephen G. Stroud ,  Stephen J. Telfer ,  Michael J. Zuraw

    IPC分类号： C07D47100

    CPC分类号： G11B7/247 ,  C07D309/34 ,  C07D335/02 ,  C07D335/06 ,  C07D345/00 ,  C09B23/0025 ,  C09B23/0066 ,  C09B57/007 ,  G03G5/0611 ,  G11B7/246

    摘要： Squarylium compounds of the formula: wherein Q1 and Q2 are each independently a pyrylium, thiopyrylium, selenopyrylium, benzpyrylium, benzthiopyrylium or benzselenopyrylium nucleus, and R1 and R2 are each independently an aliphatic or cycloaliphatic group, can be prepared by reacting a squaric acid derivative of the formula: with a compound of the formula Q2CH2R2 in the presence of a base. The derivatives of Formula II may be prepared by condensing a 2,3,4,4-tetrahalocyclobut-2-en-1-one with a compound of the formula Q1CH2R1 in the presence of a base to produce a compound of the formula: wherein Q1 and R1 are as defined above, and X represents chlorine or bromine, and hydrolyzing the compound of Formula III. Alternatively, the derivatives of Formula II may be prepared by reacting a diester, monoacid chloride monoester or diacid chloride of squaric acid with a compound of the formula Q1CH2R1 in the presence of a base, followed by hydrolysis of the resultant monoacid chloride or monoester derivative of the compound of Formula II to the parent compound.

    摘要翻译： 下式的方酸化合物：其中Q1和Q2各自独立地是吡喃鎓，硫代吡喃鎓，硒代吡喃鎓，苯并吡喃鎓，苯并硫代吡喃鎓或苯并硒吡喃鎓核，R1和R2各自独立地是脂族或脂环族基团，可以通过将 式中：在碱的存在下使用式Q2CH2R2的化合物。 式II的衍生物可以通过在碱的存在下将2,3,4,4-四卤代环丁-2-烯-1-酮与式Q1CH2R1的化合物缩合来制备下式的化合物：其中 Q1和R1如上定义，X​​表示氯或溴，并水解式III化合物。 或者，式II的衍生物可以通过在碱的存在下使方酸的二酯，单酰氯单酯或二酸氯化物与式Q1CH2R1的化合物反应制备，然后水解所得的单酰氯或单酯衍生物 式II化合物与母体化合物。

    Process and composition for generation of acid
    18.
    发明授权
    Process and composition for generation of acid 失效

    公开(公告)号：US06242154B1

    公开(公告)日：2001-06-05

    申请号：US09210101

    申请日：1998-12-11

    申请人： Jurgen M. Grasshoff ,  John L. Marshall ,  Richard A. Minns ,  Socorro M. Ramos ,  Stephen G. Stroud ,  Stephen J. Telfer ,  Haixin Yang ,  Roger A. Boggs ,  Eric S. Kolb

    发明人： Jurgen M. Grasshoff ,  John L. Marshall ,  Richard A. Minns ,  Socorro M. Ramos ,  Stephen G. Stroud ,  Stephen J. Telfer ,  Haixin Yang ,  Roger A. Boggs ,  Eric S. Kolb

    IPC分类号： G03C1492

    CPC分类号： G03C1/73 ,  B41M5/30 ,  G03F7/0045

    摘要： A process for generation of acid uses a medium comprising a first acid-generating component capable of generating a first acid, and a secondary acid generator, this secondary acid generator being capable of thermal decomposition to form a secondary acid, the thermal decomposition of the secondary acid generator being catalyzed by the first acid. At least part of the medium is exposed to so as to cause formation of the first acid from the first acid-generating component; and the medium is then heated to cause, in the exposed part of the medium, acid-catalyzed thermal decomposition of the secondary acid generator and formation of the secondary acid. The secondary acid generator has a first site bearing a first leaving group and a second site bearing a second leaving group, the first leaving group being capable of protonation by the first acid, with expulsion of the first leaving group to form a cation which electrophilically adds to an unsaturated reagent bearing a proton at the site of addition and a proton-containing nucleophilic grouping at an adjacent site, following which said proton on the reagent is lost and the second leaving group is displaced by said nucleophilic grouping, the second leaving group, in combination with a proton, forming the secondary acid. Preferred variants of the process are of the types described in U.S. Pat. Nos. 5,286,612; 5,334,489; 5,395,736; 5,441,850 and 5,453,345.

    Process and composition for generation of acid
    19.
    发明授权
    Process and composition for generation of acid 有权
    生成酸的方法和组成

    公开(公告)号：US06307085B1

    公开(公告)日：2001-10-23

    申请号：US09627939

    申请日：2000-07-28

    申请人： Jurgen M. Grasshoff ,  John L. Marshall ,  Richard A. Minns ,  Socorro M. Ramos ,  Stephen G. Stroud ,  Stephen J. Telfer ,  Haixin Yang ,  Roger A. Boggs ,  Eric S. Kolb

    发明人： Jurgen M. Grasshoff ,  John L. Marshall ,  Richard A. Minns ,  Socorro M. Ramos ,  Stephen G. Stroud ,  Stephen J. Telfer ,  Haixin Yang ,  Roger A. Boggs ,  Eric S. Kolb

    IPC分类号： C07F902

    CPC分类号： G03C1/73 ,  B41M5/30 ,  G03F7/0045

    摘要： A process for generation of acid uses a medium comprising a first acid-generating component capable of generating a first acid, and a secondary acid generator, this secondary acid generator being capable of thermal decomposition to form a secondary acid, the thermal decomposition of the secondary acid generator being catalyzed by the first acid. At least part of the medium is exposed to so as to cause formation of the first acid from the first acid-generating component; and the medium is then heated to cause, in the exposed part of the medium, acid-catalyzed thermal decomposition of the secondary acid generator and formation of the secondary acid. The secondary acid generator has a first site bearing a first leaving group and a second site bearing a second leaving group, the first leaving group being capable of protonation by the first acid, with expulsion of the first leaving group to form a cation which electrophilically adds to an unsaturated reagent bearing a proton at the site of addition and a proton-containing nucleophilic grouping at an adjacent site, following which said proton on the reagent is lost and the second leaving group is displaced by said nucleophilic grouping, the second leaving group, in combination with a proton, forming the secondary acid. Preferred variants of the process are of the types described in U.S. Pat. Nos. 5,286,612; 5,334,489; 5,395,736; 5,441,850 and 5,453,345.

    摘要翻译： 酸的制造方法使用包含能够产生第一酸的第一产酸成分的培养基和二次酸发生剂，该二次酸发生剂能够热分解形成二次酸，二次酸的热分解 酸发生剂由第一种酸催化。 介质的至少一部分被暴露以便从第一产酸组分形成第一种酸; 然后将介质加热以在介质的暴露部分中引起二次酸发生器的酸催化热分解和二次酸的形成。 二次酸发生器具有带有第一离去基团的第一位点和带有第二离去基团的第二位点，第一离去基团能够被第一酸质子化，同时排出第一离去基团以形成亲电子加成的阳离子 涉及在相邻位置处带有质子的不饱和试剂和在相邻位置处含质子的亲核基团，随后试剂上的所述质子损失，第二离去基团被所述亲核基团置换，第二离去基团， 与质子结合形成二次酸。 该方法的优选变体是在美国专利No. 第5,286,612号; 5,334,489; 5,395,736; 5,441,850和5,453,345。

    Process and composition for generation of acid
    20.
    发明授权
    Process and composition for generation of acid 失效
    生成酸的方法和组成

    公开(公告)号：US5914213A

    公开(公告)日：1999-06-22

    申请号：US944284

    申请日：1997-10-06

    申请人： Jurgen M. Grasshoff ,  John L. Marshall ,  Richard A. Minns ,  Socorro M. Ramos ,  Stephen G. Stroud ,  Stephen J. Telfer ,  Haixin Yang ,  Roger A. Boggs ,  Eric S. Kolb

    发明人： Jurgen M. Grasshoff ,  John L. Marshall ,  Richard A. Minns ,  Socorro M. Ramos ,  Stephen G. Stroud ,  Stephen J. Telfer ,  Haixin Yang ,  Roger A. Boggs ,  Eric S. Kolb

    IPC分类号： B41M5/30 ,  G03C1/73 ,  G03F7/004 ,  G03C1/492 ,  G03C1/494 ,  G03C1/76

    CPC分类号： G03C1/73 ,  B41M5/30 ,  G03F7/0045

    摘要： A process for generation of acid uses a medium comprising a first acid-generating component capable of generating a first acid, and a secondary acid generator, this secondary acid generator being capable of thermal decomposition to form a secondary acid, the thermal decomposition of the secondary acid generator being catalyzed by the first acid. At least part of the medium is exposed to so as to cause formation of the first acid from the first acid-generating component; and the medium is then heated to cause, in the exposed part of the medium, acid-catalyzed thermal decomposition of the secondary acid generator and formation of the secondary acid. The secondary acid generator has a first site bearing a first leaving group and a second site bearing a second leaving group, the first leaving group being capable of protonation by the first acid, with expulsion of the first leaving group to form a cation which electrophilically adds to an unsaturated reagent bearing a proton at the site of addition and a proton-containing nucleophilic grouping at an adjacent site, following which said proton on the reagent is lost and the second leaving group is displaced by said nucleophilic grouping, the second leaving group, in combination with a proton, forming the secondary acid. Preferred variants of the process are of the types described in U.S. Pat. Nos. 5,286,612; 5,334,489; 5,395,736; 5,441,850 and 5,453,345.

    摘要翻译： 酸的制造方法使用包含能够产生第一酸的第一产酸成分的培养基和二次酸发生剂，该二次酸发生剂能够热分解形成二次酸，二次酸的热分解 酸发生剂由第一种酸催化。 介质的至少一部分被暴露以便从第一产酸组分形成第一种酸; 然后将介质加热以在介质的暴露部分中引起二次酸发生器的酸催化热分解和二次酸的形成。 二次酸发生器具有带有第一离去基团的第一位点和带有第二离去基团的第二位点，第一离去基团能够被第一酸质子化，同时排出第一离去基团以形成亲电子加成的阳离子 涉及在相邻位置处带有质子的不饱和试剂和在相邻位置处含质子的亲核基团，随后试剂上的所述质子损失，第二离去基团被所述亲核基团置换，第二离去基团， 与质子结合形成二次酸。 该方法的优选变体是在美国专利No. 第5,286,612号; 5,334,489; 5,395,736 5,441,850和5,453,345。