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    Process and composition for generation of acid
    1.
    发明授权
    Process and composition for generation of acid 失效

    公开(公告)号：US06242154B1

    公开(公告)日：2001-06-05

    申请号：US09210101

    申请日：1998-12-11

    申请人： Jurgen M. Grasshoff ,  John L. Marshall ,  Richard A. Minns ,  Socorro M. Ramos ,  Stephen G. Stroud ,  Stephen J. Telfer ,  Haixin Yang ,  Roger A. Boggs ,  Eric S. Kolb

    发明人： Jurgen M. Grasshoff ,  John L. Marshall ,  Richard A. Minns ,  Socorro M. Ramos ,  Stephen G. Stroud ,  Stephen J. Telfer ,  Haixin Yang ,  Roger A. Boggs ,  Eric S. Kolb

    IPC分类号： G03C1492

    CPC分类号： G03C1/73 ,  B41M5/30 ,  G03F7/0045

    摘要： A process for generation of acid uses a medium comprising a first acid-generating component capable of generating a first acid, and a secondary acid generator, this secondary acid generator being capable of thermal decomposition to form a secondary acid, the thermal decomposition of the secondary acid generator being catalyzed by the first acid. At least part of the medium is exposed to so as to cause formation of the first acid from the first acid-generating component; and the medium is then heated to cause, in the exposed part of the medium, acid-catalyzed thermal decomposition of the secondary acid generator and formation of the secondary acid. The secondary acid generator has a first site bearing a first leaving group and a second site bearing a second leaving group, the first leaving group being capable of protonation by the first acid, with expulsion of the first leaving group to form a cation which electrophilically adds to an unsaturated reagent bearing a proton at the site of addition and a proton-containing nucleophilic grouping at an adjacent site, following which said proton on the reagent is lost and the second leaving group is displaced by said nucleophilic grouping, the second leaving group, in combination with a proton, forming the secondary acid. Preferred variants of the process are of the types described in U.S. Pat. Nos. 5,286,612; 5,334,489; 5,395,736; 5,441,850 and 5,453,345.

    Process and composition for generation of acid
    2.
    发明授权
    Process and composition for generation of acid 失效
    生成酸的方法和组成

    公开(公告)号：US6110638A

    公开(公告)日：2000-08-29

    申请号：US757195

    申请日：1996-11-27

    申请人： Roger A. Boggs ,  Jurgen M. Grasshoff ,  Eric S. Kolb ,  John L. Marshall ,  Richard A. Minns ,  Socorro M. Ramos ,  Stephen G. Stroud ,  Stephen J. Telfer ,  Haixin Yang

    发明人： Roger A. Boggs ,  Jurgen M. Grasshoff ,  Eric S. Kolb ,  John L. Marshall ,  Richard A. Minns ,  Socorro M. Ramos ,  Stephen G. Stroud ,  Stephen J. Telfer ,  Haixin Yang

    IPC分类号： B41M5/30 ,  G03C1/73 ,  G03F7/004 ,  C03C1/492 ,  C03C1/494 ,  C03C1/76

    CPC分类号： B41M5/30 ,  G03C1/73 ,  G03F7/0045 ,  Y10S430/115

    摘要： A process for generation of acid uses a medium comprising a first acid-generating component capable of generating a first acid, and a secondary acid generator, this secondary acid generator being capable of thermal decomposition to form a secondary acid, the thermal decomposition of the secondary acid generator being catalyzed by the first acid. At least part of the medium is exposed to so as to cause formation of the first acid from the first acid-generating component; and the medium is then heated to cause, in the exposed part of the medium, acid-catalyzed thermal decomposition of the secondary acid generator and formation of the secondary acid. The secondary acid generator has a first site bearing a first leaving group and a second site bearing a second leaving group, the first leaving group being capable of protonation by the first acid, with expulsion of the first leaving group, followed by loss of a proton from the secondary acid generator to form an unstable intermediate, which then fragments with loss of the second leaving group, accompanied by either (a) loss of a second proton; or (b) addition of a proton-containing nucleophile, followed by loss of a proton, the second leaving group, in combination with a proton, forming the secondary acid. Preferred variants of the process are of the types described in U.S. Pat. Nos. 5,286,612; 5,334,489; 5,395,736; 5,441,850 and 5,453,345.

    摘要翻译： 酸的制造方法使用包含能够产生第一酸的第一产酸成分的培养基和二次酸发生剂，该二次酸发生剂能够热分解形成二次酸，二次酸的热分解 酸发生剂由第一种酸催化。 介质的至少一部分被暴露以便从第一产酸组分形成第一种酸; 然后将介质加热以在介质的暴露部分中引起二次酸发生器的酸催化热分解和二次酸的形成。 二次酸产生器具有带有第一离去基团的第一位点和带有第二离去基团的第二位点，第一离去基团能够被第一酸质子化，同时排出第一离去基团，然后丢失质子 从次级酸产生器形成不稳定的中间体，然后随着第二离去基团的损失而断裂，伴随着（a）第二质子的损失; 或者（b）加入含质子的亲核试剂，然后与质子组合丢失质子，第二离去基团与质子结合，形成二次酸。 该方法的优选变体是在美国专利No. 第5,286,612号; 5,334,489; 5,395,736; 5,441,850和5,453,345。

    Process and composition for generation of acid
    3.
    发明授权
    Process and composition for generation of acid 有权
    生成酸的方法和组成

    公开(公告)号：US06307085B1

    公开(公告)日：2001-10-23

    申请号：US09627939

    申请日：2000-07-28

    申请人： Jurgen M. Grasshoff ,  John L. Marshall ,  Richard A. Minns ,  Socorro M. Ramos ,  Stephen G. Stroud ,  Stephen J. Telfer ,  Haixin Yang ,  Roger A. Boggs ,  Eric S. Kolb

    发明人： Jurgen M. Grasshoff ,  John L. Marshall ,  Richard A. Minns ,  Socorro M. Ramos ,  Stephen G. Stroud ,  Stephen J. Telfer ,  Haixin Yang ,  Roger A. Boggs ,  Eric S. Kolb

    IPC分类号： C07F902

    CPC分类号： G03C1/73 ,  B41M5/30 ,  G03F7/0045

    摘要： A process for generation of acid uses a medium comprising a first acid-generating component capable of generating a first acid, and a secondary acid generator, this secondary acid generator being capable of thermal decomposition to form a secondary acid, the thermal decomposition of the secondary acid generator being catalyzed by the first acid. At least part of the medium is exposed to so as to cause formation of the first acid from the first acid-generating component; and the medium is then heated to cause, in the exposed part of the medium, acid-catalyzed thermal decomposition of the secondary acid generator and formation of the secondary acid. The secondary acid generator has a first site bearing a first leaving group and a second site bearing a second leaving group, the first leaving group being capable of protonation by the first acid, with expulsion of the first leaving group to form a cation which electrophilically adds to an unsaturated reagent bearing a proton at the site of addition and a proton-containing nucleophilic grouping at an adjacent site, following which said proton on the reagent is lost and the second leaving group is displaced by said nucleophilic grouping, the second leaving group, in combination with a proton, forming the secondary acid. Preferred variants of the process are of the types described in U.S. Pat. Nos. 5,286,612; 5,334,489; 5,395,736; 5,441,850 and 5,453,345.

    摘要翻译： 酸的制造方法使用包含能够产生第一酸的第一产酸成分的培养基和二次酸发生剂，该二次酸发生剂能够热分解形成二次酸，二次酸的热分解 酸发生剂由第一种酸催化。 介质的至少一部分被暴露以便从第一产酸组分形成第一种酸; 然后将介质加热以在介质的暴露部分中引起二次酸发生器的酸催化热分解和二次酸的形成。 二次酸发生器具有带有第一离去基团的第一位点和带有第二离去基团的第二位点，第一离去基团能够被第一酸质子化，同时排出第一离去基团以形成亲电子加成的阳离子 涉及在相邻位置处带有质子的不饱和试剂和在相邻位置处含质子的亲核基团，随后试剂上的所述质子损失，第二离去基团被所述亲核基团置换，第二离去基团， 与质子结合形成二次酸。 该方法的优选变体是在美国专利No. 第5,286,612号; 5,334,489; 5,395,736; 5,441,850和5,453,345。

    Process and composition for generation of acid
    4.
    发明授权
    Process and composition for generation of acid 失效
    生成酸的方法和组成

    公开(公告)号：US5914213A

    公开(公告)日：1999-06-22

    申请号：US944284

    申请日：1997-10-06

    申请人： Jurgen M. Grasshoff ,  John L. Marshall ,  Richard A. Minns ,  Socorro M. Ramos ,  Stephen G. Stroud ,  Stephen J. Telfer ,  Haixin Yang ,  Roger A. Boggs ,  Eric S. Kolb

    发明人： Jurgen M. Grasshoff ,  John L. Marshall ,  Richard A. Minns ,  Socorro M. Ramos ,  Stephen G. Stroud ,  Stephen J. Telfer ,  Haixin Yang ,  Roger A. Boggs ,  Eric S. Kolb

    IPC分类号： B41M5/30 ,  G03C1/73 ,  G03F7/004 ,  G03C1/492 ,  G03C1/494 ,  G03C1/76

    CPC分类号： G03C1/73 ,  B41M5/30 ,  G03F7/0045

    摘要： A process for generation of acid uses a medium comprising a first acid-generating component capable of generating a first acid, and a secondary acid generator, this secondary acid generator being capable of thermal decomposition to form a secondary acid, the thermal decomposition of the secondary acid generator being catalyzed by the first acid. At least part of the medium is exposed to so as to cause formation of the first acid from the first acid-generating component; and the medium is then heated to cause, in the exposed part of the medium, acid-catalyzed thermal decomposition of the secondary acid generator and formation of the secondary acid. The secondary acid generator has a first site bearing a first leaving group and a second site bearing a second leaving group, the first leaving group being capable of protonation by the first acid, with expulsion of the first leaving group to form a cation which electrophilically adds to an unsaturated reagent bearing a proton at the site of addition and a proton-containing nucleophilic grouping at an adjacent site, following which said proton on the reagent is lost and the second leaving group is displaced by said nucleophilic grouping, the second leaving group, in combination with a proton, forming the secondary acid. Preferred variants of the process are of the types described in U.S. Pat. Nos. 5,286,612; 5,334,489; 5,395,736; 5,441,850 and 5,453,345.

    摘要翻译： 酸的制造方法使用包含能够产生第一酸的第一产酸成分的培养基和二次酸发生剂，该二次酸发生剂能够热分解形成二次酸，二次酸的热分解 酸发生剂由第一种酸催化。 介质的至少一部分被暴露以便从第一产酸组分形成第一种酸; 然后将介质加热以在介质的暴露部分中引起二次酸发生器的酸催化热分解和二次酸的形成。 二次酸发生器具有带有第一离去基团的第一位点和带有第二离去基团的第二位点，第一离去基团能够被第一酸质子化，同时排出第一离去基团以形成亲电子加成的阳离子 涉及在相邻位置处带有质子的不饱和试剂和在相邻位置处含质子的亲核基团，随后试剂上的所述质子损失，第二离去基团被所述亲核基团置换，第二离去基团， 与质子结合形成二次酸。 该方法的优选变体是在美国专利No. 第5,286,612号; 5,334,489; 5,395,736 5,441,850和5,453,345。

    Imaging medium
    5.
    发明授权
    Imaging medium 失效
    成像介质

    公开(公告)号：US5453345A

    公开(公告)日：1995-09-26

    申请号：US141852

    申请日：1993-10-22

    申请人： Jurgen M. Grasshoff ,  John L. Marshall ,  Richard A. Minns ,  Anthony J. Puttick ,  Lloyd D. Taylor ,  Stephen J. Telfer

    发明人： Jurgen M. Grasshoff ,  John L. Marshall ,  Richard A. Minns ,  Anthony J. Puttick ,  Lloyd D. Taylor ,  Stephen J. Telfer

    IPC分类号： B41M5/30 ,  B41M5/333 ,  C07C49/593 ,  G03C1/675 ,  G03C1/73 ,  G03F7/004 ,  G03C1/492 ,  G03C1/494 ,  G03C1/76

    CPC分类号： C07C49/593 ,  B41M5/30 ,  G03C1/73 ,  G03F7/0045 ,  Y10S430/145 ,  Y10S430/146

    摘要： Acid can be generated by exposing a mixture of a superacid precursor and a dye to actinic radiation of a first wavelength which does not, in the absence of the dye, cause decomposition of the superacid precursor to form the corresponding superacid, thereby causing absorption of the actinic radiation and decomposition of part of the superacid precursor, with formation of a protonated product derived from the dye, then irradiating the mixture with actinic radiation of a second wavelength, thereby causing decomposition of part of the remaining superacid precursor, with formation of unbuffered superacid. Preferably, following these irradiations, the imaging medium is heated while the superacid is admixed with a secondary acid generator capable of being thermally decomposed to form a second acid, the thermal decomposition of the secondary acid generator being catalyzed by the presence of the superacid. The acid generation process may be used for imaging by bringing the superacid or second acid into contact with an acid-sensitive material which changes color on contact with acid, or the superacid may be used to trigger polymerization, depolymerization or other reactions.

    摘要翻译： 可以通过将超强酸前体和染料的混合物暴露于第一波长的光化辐射而产生酸，在第一波长的光化辐射下，在不存在染料的情况下，超级酸性前体不会分解形成相应的超强酸，从而引起吸收 光化辐射和部分超酸前体的分解，形成衍生自染料的质子化产物，然后用第二波长的光化辐射照射混合物，从而导致部分剩余的超酸前体分解，形成无缓冲的超酸 。 优选地，在这些照射之后，加热成像介质，同时将超强酸与能够热分解形成第二酸的次级酸发生剂混合，二次酸产生剂的热分解由超强酸的存在催化。 酸生成方法可以通过使超酸或第二酸与酸接触改变颜色的酸敏感材料接触而使用，或者超酸可用于引发聚合，解聚或其它反应。

    Process for generation of unbuffered super-acid and for imaging
    6.
    发明授权
    Process for generation of unbuffered super-acid and for imaging 失效
    产生无缓冲超酸和成像的方法

    公开(公告)号：US5578424A

    公开(公告)日：1996-11-26

    申请号：US376037

    申请日：1995-01-20

    申请人： Jurgen M. Grasshoff ,  John L. Marshall ,  Richard A. Minns ,  Anthony J. Puttick ,  Lloyd D. Taylor ,  Stephen J. Telfer

    发明人： Jurgen M. Grasshoff ,  John L. Marshall ,  Richard A. Minns ,  Anthony J. Puttick ,  Lloyd D. Taylor ,  Stephen J. Telfer

    IPC分类号： B41M5/30 ,  B41M5/333 ,  C07C49/593 ,  G03C1/675 ,  G03C1/73 ,  G03F7/004 ,  G03C1/725 ,  G03C1/735 ,  G03C5/00

    CPC分类号： C07C49/593 ,  B41M5/30 ,  G03C1/73 ,  G03F7/0045 ,  Y10S430/145 ,  Y10S430/146

    摘要： Acid can be generated by exposing a mixture of a superacid precursor and a dye to actinic radiation of a first wavelength which does not, in the absence of the dye, cause decomposition of the superacid precursor to form the corresponding superacid, thereby causing absorption of the actinic radiation and decomposition of part of the superacid precursor, with formation of a protonated product derived from the dye, then irradiating the mixture with actinic radiation of a second wavelength, thereby causing decomposition of part of the remaining superacid precursor, with formation of unbuffered superacid. Preferably, following these irradiations, the imaging medium is heated while the superacid is admixed with a secondary acid generator capable of being thermally decomposed to form a second acid, the thermal decomposition of the secondary acid generator being catalyzed by the presence of the superacid. The acid generation process may be used for imaging by bringing the superacid or second acid into contact with an acid-sensitive material which changes color on contact with acid, or the superacid may be used to trigger polymerization, depolymerization or other reactions.

    摘要翻译： 可以通过将超强酸前体和染料的混合物暴露于第一波长的光化辐射而产生酸，在第一波长的光化辐射下，在不存在染料的情况下，超级酸性前体不会分解形成相应的超强酸，从而引起吸收 光化辐射和部分超酸前体的分解，形成衍生自染料的质子化产物，然后用第二波长的光化辐射照射混合物，从而导致部分剩余的超酸前体分解，形成无缓冲的超酸 。 优选地，在这些照射之后，加热成像介质，同时将超强酸与能够热分解形成第二酸的次级酸发生剂混合，二次酸产生剂的热分解由超强酸的存在催化。 酸生成方法可以通过使超酸或第二酸与酸接触改变颜色的酸敏感材料接触而使用，或者超酸可用于引发聚合，解聚或其它反应。

    Sensitizer dyes for photoacid generating systems
    10.
    发明申请
    Sensitizer dyes for photoacid generating systems 失效
    用于光致酸产生系统的敏化剂染料

    公开(公告)号：US20090042105A1

    公开(公告)日：2009-02-12

    申请号：US12070913

    申请日：2008-02-21

    申请人： David A. Waldman ,  Eric S. Kolb ,  Kirk D. Hutchinson ,  Richard A. Minns

    发明人： David A. Waldman ,  Eric S. Kolb ,  Kirk D. Hutchinson ,  Richard A. Minns

    IPC分类号： G03F7/004 ,  G03C1/73 ,  C07C15/38 ,  C07F7/08 ,  C07C33/28

    CPC分类号： G03F7/0045 ,  C09B3/78 ,  C09B3/82 ,  G03F7/038 ,  G03F7/0755 ,  G11B7/24044 ,  G11B7/244 ,  G11B7/246 ,  G11B7/249

    摘要： Photosensitizing dyes are often used in conjunction with a photoacid generator in holographic recording media. Conventional photosensitizing dyes typically are limited by having an appreciable absorption of light when used in a sufficient concentration, such that the intensity of light decreases significantly with penetration into a recording medium. The present invention discloses a number of new 5-alkynyl substituted napthacene photosensitizing dyes that have low extinction coefficients coupled with good sensitizing properties, such that the problems associated with the photosensitizing dyes absorbing light are significantly reduced.

    摘要翻译： 光敏染料通常与全息记录介质中的光致酸发生器结合使用。 常规的光敏染料通常在以足够的浓度使用时具有明显的光吸收来限制，使得光的强度随着渗入记录介质而显着降低。 本发明公开了许多具有低消光系数和良好的敏化性能的新的5-炔基取代的萘并茂光敏染料，使得与吸收光的光敏染料相关的问题显着降低。