公开(公告)号：US6096372A

公开(公告)日：2000-08-01

申请号：US10839

申请日：1998-01-22

申请人： Satoru Nomura ,  Yasumichi Hotta ,  Namitsugu Fujii ,  Hiromi Sano

发明人： Satoru Nomura ,  Yasumichi Hotta ,  Namitsugu Fujii ,  Hiromi Sano

IPC分类号： G01N27/409 ,  G01N27/407 ,  B05D5/12

CPC分类号： G01N27/4075

摘要： In a method for forming an inside electrode within a cup-type electrolyte member of an O.sub.2 sensor element, firstly, a nozzle having a paste discharge hole is prepared. The nozzle is inserted into an inside space of the electrolyte member. Then, the paste discharge hole of the nozzle is relatively rotated with respect to the electrolyte member along an inside surface of the electrolyte member while discharging paste therefrom onto the inside surface. Accordingly, the inside electrode formation portion is formed. After forming the inside electrode formation portion, the electrolyte member is baked. As a result, the inside electrode can be disposed on a required portion of the electrolyte member with a uniform thickness.

摘要翻译： 在O 2传感器元件的杯型电解质构件的内部电极的形成方法中，首先，准备具有糊剂排出孔的喷嘴。 喷嘴插入电解质构件的内部空间。 然后，喷嘴的糊剂排出孔相对于电解质构件沿着电解质构件的内表面相对旋转，同时将膏从其排出到内表面。 因此，形成内部电极形成部。 在形成内部电极形成部分之后，电解质部件被烘烤。 结果，内部电极可以以均匀的厚度设置在电解质构件的所需部分上。

公开(公告)号：US5766672A

公开(公告)日：1998-06-16

申请号：US704927

申请日：1996-08-28

申请人： Yasumichi Hotta ,  Hiromi Sano ,  Namitsugu Fujii ,  Naoto Miwa

发明人： Yasumichi Hotta ,  Hiromi Sano ,  Namitsugu Fujii ,  Naoto Miwa

IPC分类号： G01N27/409 ,  G01N27/407 ,  B05D5/12

CPC分类号： G01N27/4075

摘要： An oxygen concentration detector element 2 includes a cup-shaped solid electrolyte 20 with an inside chamber 25 opened at one end and closed at the other end. An external electrode 21 is formed on an outer surface of solid electrolyte 20 by dipping solid electrolyte 20 in first chemical plating liquid 81, while an internal electrode 22 is formed on an inner surface of solid electrolyte 20 by introducing second chemical plating liquid 82 into inside chamber 25. First, in an injecting step, an injection needle 11 is inserted into inside chamber 25 and second chemical plating liquid 82 is introduced into inside chamber 25 via injection needle 11, and then injection needle 11 is pulled out of inside chamber 25. Next, in a plating step, internal electrode 22 is formed on the inner surface of inside chamber 25 using second chemical plating liquid 82. Then, in a discharging step, residual second chemical plating liquid 82 is discharged from inside chamber 25.

摘要翻译： 氧浓度检测元件2包括杯状固体电解质20，其内侧室25在一端开口并在另一端封闭。 通过在第一化学镀液81中浸渍固体电解质20而在固体电解质20的外表面上形成外部电极21，而在固体电解质20的内表面上形成内部电极22，通过将第二化学镀液82引入到内部电极 首先，在注射步骤中，将注入针11插入内部腔25中，并且将第二化学镀液82经由注射针11引入到内部腔25内，然后将注射针11从内部腔25中拉出。 接着，在电镀工序中，使用第二化学镀液82在内部室25的内表面上形成内部电极22.然后，在排出工序中，残留的第二化学镀液82从内部室25排出。

公开(公告)号：US5766434A

公开(公告)日：1998-06-16

申请号：US797652

申请日：1997-01-31

申请人： Namitsugu Fujii ,  Hiromi Sano ,  Yasumichi Hotta ,  Naoto Miwa ,  Motoaki Satou

发明人： Namitsugu Fujii ,  Hiromi Sano ,  Yasumichi Hotta ,  Naoto Miwa ,  Motoaki Satou

IPC分类号： G01N27/407 ,  G01N27/26

CPC分类号： G01N27/4075 ,  G01N27/4077

摘要： An oxygen concentration detecting device comprises a solid electrolyte body, inner and outer electrodes formed on the opposite sides of the solid electrolyte body, and a protective layer formed on the outer electrode and comprised of coarse particles and fine particles mutually bonded through an inorganic binder while substantially keeping the original forms of the both types of particles. A ratio of an average particle size, RB, of the coarse particles to an average particle size, RA, of the fine particles of 30:1 or above, and a content, WA, of the fine particles in the protective layer based on the total content, W, of the content, WA, of the fine particles and the content, WB, of the coarse particles on the weight basis is in the range of 15 to 80 %. A method for fabricating the detecting device having such a protective layer as set out above is also described.

摘要翻译： 氧浓度检测装置包括固体电解质体，形成在固体电解质体的相对侧的内部和外部电极，以及形成在外部电极上的保护层，其由通过无机粘合剂相互粘合的粗粒子和微粒组成， 基本保持两种类型颗粒的原始形式。 基于上述保护层中的微粒的粗粒子的平均粒径RB与微粒的平均粒径RA（30:1以上）和含量WA的比例 粗颗粒的含量W W，微粒的含量W和重量的含量WB在15〜80％的范围内。 还描述了制造具有上述保护层的检测装置的方法。

公开(公告)号：US5707503A

公开(公告)日：1998-01-13

申请号：US549209

申请日：1995-10-27

申请人： Yasumichi Hotta ,  Hiromi Sano ,  Toshitaka Saito ,  Masatoshi Suzuki ,  Naoto Miwa

发明人： Yasumichi Hotta ,  Hiromi Sano ,  Toshitaka Saito ,  Masatoshi Suzuki ,  Naoto Miwa

IPC分类号： G01N27/409 ,  G01N27/407 ,  G01N27/26

CPC分类号： G01N27/4075

摘要： According to the present invention, an oxygen sensor element includes a solid electrolyte having a side surface at one side thereof, the side surface being contactable with a gas to be measured, a skeletal electrode provided on the side surface and having a plurality of pore portions, each of the pore portions passing through the skeletal electrode up to the solid electrolyte, and a reactive electrode made of a porous film and provided in each of the pore portions, a thickness of the porous film being smaller than that of said skeletal electrode. An area percentage (SH/SZ) which is a ratio of a total area (SH) of the reactive electrode to a total area (SZ) of the skeletal electrode and the reactive electrode is in a range from 10 to 50%, an average area (SA) of the pore portions is 100 .mu.m.sup.2 or less, a film thickness of the skeletal electrode is in a range from 1.5 to 4 .mu.m, and the film thickness of the reactive electrode is in a range from 0.6 to 1.5 .mu.m. The oxygen sensor element is superior in the heat resistance characteristics and the response characteristics.

摘要翻译： 根据本发明，氧传感器元件包括固体电解质，其一侧具有侧表面，侧表面可与待测气体接触，骨架电极设置在侧表面上并具有多个孔部分 每个孔部分通过骨架电极直到固体电解质，以及由多孔膜制成的反应性电极，并设置在每个孔部分中，多孔膜的厚度小于所述骨架电极的厚度。 作为骨架电极和反应性电极的反应电极的总面积（SH）与总面积（SZ）的比的面积百分比（SH / SZ）在10〜50％的范围内，平均 孔部的面积（SA）为100μm以下，骨架电极的膜厚在1.5〜4μm的范围内，反应电极的膜厚在0.6〜1.5μm的范围内 m。 氧传感器元件的耐热特性和响应特性优异。

公开(公告)号：US4626337A

公开(公告)日：1986-12-02

申请号：US729854

申请日：1985-05-02

申请人： Yasumichi Hotta ,  Takao Akatsuka ,  Masao Kawaguchi ,  Jiro Nakano ,  Takao Ishibashi

发明人： Yasumichi Hotta ,  Takao Akatsuka ,  Masao Kawaguchi ,  Jiro Nakano ,  Takao Ishibashi

IPC分类号： G01N27/41 ,  G01N27/407 ,  G01N27/409 ,  G01N27/46

CPC分类号： G01N27/4075 ,  G01N27/407 ,  G01N27/4078

摘要： The oxygen sensor has a solid electrolytic element made of an oxygen ion-conducting metal oxide. This element is formed in a cup shape, closed at one end and opened at its other end. The outer peripheral surface of the element is exposed to exhaust gas, and the inner peripheral surface of the element is exposed to the atmosphere. A first electrode is fixed to the outer peripheral surface of the element, and a second electrode is fixed to the inner peripheral surface of the element. An electrically insulating layer is formed on the outer peripheral surface of the element except where the first electrode is disposed. A metal lead of thin film, connected to the first electrode, is formed on the insulating layer. Further, a retaining lead connected to the first electrode is formed on the metal lead. This retaining lead is formed by densely sintering a conductive material and a binding material.

摘要翻译： 氧传感器具有由氧离子传导金属氧化物制成的固体电解质元件。 该元件形成为杯形，在一端封闭并在其另一端开口。 元件的外周面暴露于废气中，元件的内周面暴露在大气中。 第一电极固定在元件的外周面上，第二电极固定在元件的内周面上。 除了设置第一电极之外，在元件的外周表面上形成电绝缘层。 连接到第一电极的薄膜的金属引线形成在绝缘层上。 此外，在金属引线上形成连接到第一电极的保持引线。 该保持引线通过密集地烧结导电材料和粘合材料而形成。