Abstract:
A heterocyclic phosphorus mono-, di- or polyester has the constitution of the product prepared by reacting an intermediate of specified type with a di- or polyol or derivative thereof capable of yielding the di- or polyol on hydrolysis, said intermediate of specified type being a heterocyclic phosphorus compound having the constitution of the compound prepared by reacting an olefin polymer or copolymer having at least 50 carbon atoms and containing olefinic unsaturation with a phosphorus trihalide in the presence of a Friedel-Crafts catalyst, preferably consisting of an aluminium halide, to form a reaction product having halogen atoms attached to phosphorus, and thereafter reacting the reaction product with a hydroxy compound, preferably water or methanol, to remove one or both of the halogen atoms attached to the phosphorus atom. Lubricating compositions containing the mono-, di- or polyesters of the invention are also described.
Abstract:
Novel phenols obtained by reacting a compound of the formula I
in which ONE X is a hydroxyl group and the other X is selected from hydrogen atoms and tertiary butyl radicals, EACH OF R1 and R2 is independently selected from hydrogen atoms and tertiary butyl radicals, A is selected from phenyl radicals and phenyl radicals substituted by up to 2 tertiary butyl radicals, with the proviso that at least one of R1 and R2 must be a tertiary butyl radical and with the further proviso that at most 3 tertiary butyl radicals may be present per molecule, with phosphorus trichloride and chlorine atoms which may be left on the phosphorus atom are then reacted with water, alcohols, polyalcohols, or phenols, are described and their use as stabilizers against certain deterioration phenomena, especially adverse effect of light, heat or oxidation with organic materials, especially plastics such as polypropylene.
Abstract:
By contacting an amino carboxylic phosphine sequestering agent with an aqueous solution containing ions of transition metals, said ions react with the amino carboxylic phosphine to form soluble complexes. Since the decomposition of hydrogen peroxide is catalyzed by the presence of trace metal ions, such as Cu , MN , and Fe , the addition of these sequestering agents to peroxide solutions serves to deactivate such metal ions and thus reduce their catalytic effect on peroxide composition. Such agents also serve to control hardness of water and to deactivate objectionable metal ions in textile processing and in metal cleaning and finishing.
Abstract:
Phosphorus compounds containing the skeleton P-(C-P)2 or P-(CP)3 of the formula P(O)a(R1)b( CH2P(O)(R2R3) 3 b and method for making by reacting a compound of the formula P(O)a(R1)b(CH2Cl)3 b with a compound of the formula P(R)5)(R6)OR4 to split off R4Cl. Also uses of the products as threshold agents, sequestering agents, detergent composition additives, peroxy solution stabilizers and chlorine releasing agent stabilization is claimed.
Abstract:
Phosphorus compounds containing the skeleton P-(C-P)2 or P-(CP)3 of the formula P(O)a(R1)b(CH P(O)(R2)R3)3 b and method for making by reacting a compound of the formula P(O)a(R1)b(CH2Cl)3 b with a compound of the formula P(R5)(R6)OR4 to split off R4C1. Also uses of the products as threshold agents, sequestering agents, detergent composition additives, peroxy solution stabilizers and chlorine releasing agent stabilization is claimed.
Abstract:
NOVEL HALOVINYLPHOSPHONOUS DIHALIDES OF THE FORMULA:
CH2=C(-X'')-P(-X)2
WHEREIN X IS A HALOGEN ATOM HAVING AN ATOMIC WEIGHT GREATER THAN ABOUT 30, AND X'' IS A HALOGEN ATOM HAVING AN ATOMIC WEIGHT GREATER THAN ABOUT 15; A NOVEL PROCESS FOR THEIR PREPARATION BY THE REACTION OF A PHOSPHORUS TRIHALIDE AND A VINYL HALIDE AT A TEMPERATURE BETWEEN ABOUT 200*C. AND 800*C. IN A NON-OXIDIZING MEDIUM; POLYMERS INCORPORATING THE HALOVINYLPHOSPHONOUS DIHALIDES AND DERIVATIVES OBTAINED THEREFROM.