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    Method for the production of monohydroxy-functionalized dialkylphosphinic acids, esters, and salts using ethylene oxide, and use thereof
    3.
    发明授权
    Method for the production of monohydroxy-functionalized dialkylphosphinic acids, esters, and salts using ethylene oxide, and use thereof 有权
    使用环氧乙烷生产单羟基官能化二烷基次膦酸，酯和盐的方法及其用途

    公开(公告)号：US08987490B2

    公开(公告)日：2015-03-24

    申请号：US13140140

    申请日：2009-10-06

    Applicant: Michael Hill ,  Werner Krause ,  Martin Sicken

    Inventor： Michael Hill ,  Werner Krause ,  Martin Sicken

    IPC: C07F9/32 ,  C07F9/30 ,  C09K21/12 ,  C07F9/48 ,  C08K5/53 ,  C08K5/5313

    CPC classification number: C09K21/12 ,  C07F9/30 ,  C07F9/301 ,  C07F9/3211 ,  C07F9/48 ,  C08K5/53 ,  C08K5/5313

    Abstract: A method for producing monohydroxy-functionalized dialkylphosphinic acids, esters, and salts, characterized in that a) a phosphinic acid source (I) is reacted with olefins (IV) in the presence of a catalyst A to obtain an alkylphosphonous acid, the salt or ester (II) thereof, b) the obtained alkylphosphonous acid, the salt or ester (II) thereof is reacted with alkylene oxides of formula (V) in the presence of a catalyst B to obtain a monofunctionalized dialkylphosphinic acid derivative (III), catalyst A represents transition metals and/or transition metal compounds and/or catalyst systems composed of a transition metal and/or a transition metal compound and at least one ligand, and catalyst B is a Lewis acid.

    Abstract translation: 一种制备单羟基官能化二烷基次膦酸，酯和盐的方法，其特征在于a）在催化剂A存在下，使次膦酸源（I）与烯烃（Ⅳ）反应得到烷基亚磷酸，其盐或 其酯（II），b）在催化剂B存在下，将得到的烷基亚磷酸，其盐或酯（II）与式（Ⅴ）的烯化氧反应得到单官能二烷基次膦酸衍生物（III），催化剂 A表示由过渡金属和/或过渡金属化合物和至少一种配体组成的过渡金属和/或过渡金属化合物和/或催化剂体系，催化剂B是路易斯酸。

    Phosphinic acid aluminum salts
    5.
    发明授权
    Phosphinic acid aluminum salts 有权
    次膦酸铝盐

    公开(公告)号：US06211402B1

    公开(公告)日：2001-04-03

    申请号：US09214473

    申请日：1999-02-16

    Applicant: Hans-Jerg Kleiner

    Inventor： Hans-Jerg Kleiner

    IPC: C07F930

    CPC classification number: C08K5/5313 ,  C07F9/30 ,  C07F17/02

    Abstract: Aluminum salts of phosphinic acid or diphosphinic acids having alkyl and/or aryl substitutes, obtainable by heating an ester of the corresponding phosphinic acids or diphosphinic acids with aluminum hydroxide at a temperature of more than 150° C. under pressure in the presence of water, are distinguished by a particular crystal structure and are suitable as flameproofing agents for plastics.

    Abstract translation: 具有烷基和/或芳基取代基的次膦酸或二次膦酸的铝盐可通过在氢气存在下在压力下加热相应次膦酸或二次膦酸的酯与氢氧化铝在大于150℃的温度下获得， 被特定的晶体结构所区分，并且适用于塑料的防火剂。

    Method for producing aluminum phosphinates
    6.
    发明授权
    Method for producing aluminum phosphinates 有权
    铝次膦酸铝的制造方法

    公开(公告)号：US6096914A

    公开(公告)日：2000-08-01

    申请号：US269434

    申请日：1999-03-26

    Applicant: Thomas Seitz

    Inventor： Thomas Seitz

    IPC: C07F19/00 ,  C07F9/30

    CPC classification number: C07F9/30

    Abstract: This invention relates to a method for producing aluminum phosphinates of the formula [R.sub.1 R.sub.2 P(O)O.sup.- ].sub.3 Al.sup.3 +, where R.sub.1 and R.sub.2 are the same or different and represent a C.sub.1-8 alkyl group or a phenyl group. The process involves reaction of the corresponding alkali metal phosphinate with aluminum sulfate. The aluminum phosphinate salts are useful as a flame retardant for plastics.

    Abstract translation: PCT No.PCT / EP97 / 05228 Sec。 371日期1999年3月26日 102（e）1999年3月26日PCT PCT 1997年9月24日PCT公布。 公开号WO98 / 13371 日期：1998年4月2日本发明涉及式[R1R2P（O）O-] 3Al3 +的铝次膦酸盐的制造方法，其中R1和R2相同或不同，表示C1-8烷基或苯基 。 该方法涉及相应的碱金属次膦酸盐与硫酸铝的反应。 铝磷酸盐可用作塑料阻燃剂。

    Process for alkylating elemental phosphorus
    7.
    发明授权
    Process for alkylating elemental phosphorus 有权
    烷基化元素磷的方法

    公开(公告)号：US6011172A

    公开(公告)日：2000-01-04

    申请号：US198543

    申请日：1998-11-24

    Applicant: Norbert Weferling ,  Othmar Stelzer ,  Gunter Kolbe

    Inventor： Norbert Weferling ,  Othmar Stelzer ,  Gunter Kolbe

    IPC: A01N57/20 ,  C07F9/30 ,  C07F9/48 ,  C09K21/12 ,  C07F9/22

    CPC classification number: C07F9/30 ,  C07F9/48

    Abstract: The invention relates to a process for preparing alkali metal salts and/or alkaline earth metal salts of alkylphosphonous acids and dialkylphosphinic acids from elemental yellow phosphorus and alkyl halides, which comprises carrying out the reaction in the presence of aqueous alkali metal hydroxide or alkaline earth metal hydroxide or mixtures thereof. The invention likewise relates to the use of the compounds prepared by the process according to the invention for preparing flame retardants, extraction media and plant protection agents.

    Abstract translation: 本发明涉及从元素黄磷和烷基卤制备烷基亚磷酸和二烷基次膦酸的碱金属盐和/或碱土金属盐的方法，其包括在碱金属氢氧化物或碱土金属水溶液存在下进行反应 氢氧化物或其混合物。 本发明同样涉及通过根据本发明的方法制备的化合物用于制备阻燃剂，提取介质和植物保护剂的用途。

    Process for preparing dialkylphosphinate salts
    8.
    发明授权
    Process for preparing dialkylphosphinate salts 有权
    制备二烷基次膦酸盐的方法

    公开(公告)号：US5973194A

    公开(公告)日：1999-10-26

    申请号：US198542

    申请日：1998-11-24

    Applicant: Norbert Weferling ,  Hans-Peter Schmitz ,  Gunter Kolbe

    Inventor： Norbert Weferling ,  Hans-Peter Schmitz ,  Gunter Kolbe

    IPC: C01B25/163 ,  C07B61/00 ,  C07F9/30

    CPC classification number: C07F9/30

    Abstract: The invention relates to a process for preparing dialkylphosphinate salts, which comprisesa) reacting elemental yellow phosphorus with alkyl halides in the presence of alkali metal hydroxide or alkaline earth metal hydroxide to form a mixture which comprises as main constituents the salts of alkylphosphonous, phosphorous and hypophosphorous acids,b) adjusting the mixture to a pH below 7 and then reacting the mixture with olefins in the presence of a free-radical initiator andc) reacting the dialkylphosphinic acids obtained according to b) and/or alkali metal salts thereof with metal compounds of Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K to give the metal dialkylphosphinate salts.The invention likewise relates to the use of the metal dialkylphosphinate salts prepared by the process according to the invention to prepare flame retardants.

    Abstract translation: 本发明涉及一种制备二烷基次膦酸盐的方法，该方法包括：a）在碱金属氢氧化物或碱土金属氢氧化物存在下使元素黄磷与烷基卤化物反应形成一种混合物，该混合物包含烷基亚磷酸，磷和 次磷酸，b）将混合物调节至低于7的pH，然后在自由基引发剂存在下使该混合物与烯烃反应，和c）将根据b）获得的二烷基次膦酸与/或其碱金属盐与金属反应 Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na和/或K的化合物，得到二烷基次膦酸金属盐。 本发明同样涉及通过本发明方法制备的二烷基次膦酸金属盐制备阻燃剂的用途。

    Preparation of phosphonic and/or phosphinic acids
    10.
    发明授权
    Preparation of phosphonic and/or phosphinic acids 失效
    膦酸和/或次膦酸的制备

    公开(公告)号：US4069245A

    公开(公告)日：1978-01-17

    申请号：US609093

    申请日：1975-08-29

    Applicant: Walter Dursch ,  Hans-Jerg Kleiner ,  Horst-Dieter Thamm

    Inventor： Walter Dursch ,  Hans-Jerg Kleiner ,  Horst-Dieter Thamm

    IPC: C07F9/30 ,  C07F9/38 ,  C07C27/00

    CPC classification number: C07F9/30 ,  C07F9/38

    Abstract: Preparation of phosphonic and/or phosphinic acids by hydrolytic cleavage of phosphonic and/or phosphinic acid alkyl esters in the presence of the phosphonic and/or phosphinic acid by carrying out the hydrolysis at a temperature of from 160.degree. to 250.degree. C with the use of at least a stoichiometric amount of water, and by distilling off the alkanol formed, optionally together with water.

    Abstract translation: 在膦酸和/或次膦酸的存在下，通过在160-250℃的温度下进行水解，通过使用膦酸和/或次膦酸烷基酯的水解裂解来制备膦酸和/或次膦酸 至少化学计算量的水，并且通过蒸馏除去所形成的链烷醇，任选地与水一起蒸馏。

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