Vinyl fluoride interpolymers of low crystallinity

    公开(公告)号:US06242547B1

    公开(公告)日:2001-06-05

    申请号:US09058831

    申请日:1998-04-13

    IPC分类号: C08F21418

    摘要: An interpolymer consisting essentially of units derived from vinyl fluoride and at least two highly fluorinated monomers, at least one of the highly fluorinated monomers introducing into the polymer a side chain of at least one carbon atom. Films from these interpolymers have substantially reduced haze, low surface tension, and can be made to form solutions in common polar organic solvents that are stable at room temperature. The extremely low surface tensions obtained with these interpolymer films provide enhanced stain resistance and improved release properties compared to polyvinyl fluoride or known vinyl fluoride interpolymers.

    Crosslinkable vinyl fluoride copolymers
    15.
    发明授权
    Crosslinkable vinyl fluoride copolymers 有权
    可交联的氟乙烯共聚物

    公开(公告)号:US07842765B2

    公开(公告)日:2010-11-30

    申请号:US11962134

    申请日:2007-12-21

    IPC分类号: C08F14/20

    摘要: The present invention provides a vinyl fluoride copolymer comprising: about 40 to about 90 mole % of repeat units derived from vinyl fluoride; and about 10 to about 60 mole % of repeat units derived from monomer selected from the group consisting of (a) and (b) below and mixtures thereof, with the proviso that about 0.1 mole % to 50 mole % of repeat units in the copolymer are derived from monomer selected from (b): (a) monomer selected from the group consisting of, tetrafluoroethylene, trifluoroethylene, chlorotrifluoroethylene and mixtures thereof; and (b) vinyl monomer containing at least one functional group selected from the group consisting of hydroxyls, thiols, carbonyls, carboxylic acids, carboxylic esters, acid anhydrides, sulfonyls, sulfonic acids, sulfonic esters, phosphoric acids, phosphoric esters, boric acids, boric esters, epoxies, isocyanates, thiocyanates, amines, amides, nitriles and halogen selected from bromide and iodide.

    摘要翻译: 本发明提供一种氟乙烯共聚物,其包含:约40至约90摩尔%的衍生自氟乙烯的重复单元; 和约10至约60摩尔%的衍生自下述(a)和(b)的单体的重复单元及其混合物,条件是共聚物中约0.1摩尔%至50摩尔%的重复单元 衍生自选自(b)的单体:(a)选自四氟乙烯,三氟乙烯,三氟氯乙烯及其混合物的单体; 和(b)含有至少一种选自羟基,硫醇,羰基,羧酸,羧酸酯,酸酐,磺酰基,磺酸,磺酸酯,磷酸,磷酸酯,硼酸等的官能团的乙烯基单体, 硼酸酯,环氧化物,异氰酸酯,硫氰酸酯,胺,酰胺,腈和选自溴化物和碘化物的卤素。