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    Crosslinkable vinyl fluoride copolymer coated film and process for making same
    1.
    发明授权
    Crosslinkable vinyl fluoride copolymer coated film and process for making same 有权
    可交联的氟乙烯共聚物涂膜及其制备方法

    公开(公告)号：US08124221B2

    公开(公告)日：2012-02-28

    申请号：US11962135

    申请日：2007-12-21

    申请人： Ronald Earl Uschold ,  Jian Wang ,  Masahiro Yamamoto

    发明人： Ronald Earl Uschold ,  Jian Wang ,  Masahiro Yamamoto

    IPC分类号： C08F14/20 ,  B32B7/04 ,  B32B27/28 ,  B32B27/34 ,  B32B27/36

    CPC分类号： C08F214/20 ,  C08F214/18 ,  C08F214/202 ,  Y10T428/2495 ,  Y10T428/24967 ,  Y10T428/26 ,  Y10T428/263 ,  Y10T428/264 ,  Y10T428/265 ,  Y10T428/266 ,  Y10T428/269 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31721 ,  Y10T428/31725 ,  Y10T428/3175 ,  Y10T428/31794 ,  Y10T428/31797 ,  Y10T428/31935

    摘要： The invention provides a fluoropolymer coated film comprising: a polymeric substrate film; and a fluoropolymer coating on the polymeric substrate film, the fluoropolymer coating comprising a vinyl fluoride copolymer comprised of about 40 to about 90 mole % of repeat units derived from vinyl fluoride and about 10 to about 60 mole % of repeat units derived from monomer selected from the group consisting of (a) and (b) below and mixtures thereof, with the proviso that about 0.1 mole % to 50 mole % of repeat units in the copolymer are derived from monomer selected from (b): (a) monomer selected from the group consisting of, tetrafluoroethylene, trifluoroethylene, chlorotrifluoroethylene and mixtures thereof; and (b) vinyl monomer containing at least one functional group selected from the group consisting of hydroxyls, thiols, carbonyls, carboxylic acids, carboxylic esters, acid anhydrides, sulfonyls, sulfonic acids, sulfonic esters, phosphoric acids, phosphoric esters, boric acids, boric esters, epoxies, isocyanates, thiocyanates, amines, amides, nitriles and halogen selected from bromide and iodide, wherein the polymeric substrate film comprises functional groups that interact with the functional groups of the vinyl fluoride copolymer to promote bonding of the fluoropolymer coating to the polymeric substrate film.

    摘要翻译： 本发明提供一种含氟聚合物涂覆膜，包括：聚合物基底膜; 和含氟聚合物涂层，所述含氟聚合物涂层包含由约40至约90摩尔％的衍生自氟乙烯的重复单元和约10至约60摩尔％的衍生自选自以下的单体的重复单元组成的氟乙烯共聚物： 由（a）和（b）组成的组和其混合物，共聚物中约0.1摩尔％至50摩尔％的重复单元衍生自选自（b）的单体：（a）选自 由四氟乙烯，三氟乙烯，一氯三氟乙烯及其混合物组成的组; 和（b）含有至少一种选自羟基，硫醇，羰基，羧酸，羧酸酯，酸酐，磺酰基，磺酸，磺酸酯，磷酸，磷酸酯，硼酸等的官能团的乙烯基单体， 硼酸酯，环氧化物，异氰酸酯，硫氰酸酯，胺，酰胺，腈和选自溴化物和碘化物的卤素，其中聚合物基底膜包含与氟乙烯共聚物的官能团相互作用以促进含氟聚合物涂层与 聚合物基底膜。

    Crosslinkable Vinyl Fluoride Copolymer Coated Film and Process for Making Same
    4.
    发明申请
    Crosslinkable Vinyl Fluoride Copolymer Coated Film and Process for Making Same 有权
    可交联乙烯基氟共聚物涂膜及其制造方法

    公开(公告)号：US20080156367A1

    公开(公告)日：2008-07-03

    申请号：US11962135

    申请日：2007-12-21

    申请人： Ronald Earl Uschold ,  Jian Wang ,  Masahiro Yamamoto

    发明人： Ronald Earl Uschold ,  Jian Wang ,  Masahiro Yamamoto

    IPC分类号： H01L31/0216 ,  B05D5/12 ,  B32B27/08

    CPC分类号： C08F214/20 ,  C08F214/18 ,  C08F214/202 ,  Y10T428/2495 ,  Y10T428/24967 ,  Y10T428/26 ,  Y10T428/263 ,  Y10T428/264 ,  Y10T428/265 ,  Y10T428/266 ,  Y10T428/269 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31721 ,  Y10T428/31725 ,  Y10T428/3175 ,  Y10T428/31794 ,  Y10T428/31797 ,  Y10T428/31935

    摘要： The invention provides a fluoropolymer coated film comprising: a polymeric substrate film; and a fluoropolymer coating on the polymeric substrate film, the fluoropolymer coating comprising a vinyl fluoride copolymer comprised of about 40 to about 90 mole % of repeat units derived from vinyl fluoride and about 10 to about 60 mole % of repeat units derived from monomer selected from the group consisting of (a) and (b) below and mixtures thereof, with the proviso that about 0.1 mole % to 50 mole % of repeat units in the copolymer are derived from monomer selected from (b): (a) monomer selected from the group consisting of, tetrafluoroethylene, trifluoroethylene, chlorotrifluoroethylene and mixtures thereof; and (b) vinyl monomer containing at least one functional group selected from the group consisting of hydroxyls, thiols, carbonyls, carboxylic acids, carboxylic esters, acid anhydrides, sulfonyls, sulfonic acids, sulfonic esters, phosphoric acids, phosphoric esters, boric acids, boric esters, epoxies, isocyanates, thiocyanates, amines, amides, nitriles and halogen selected from bromide and iodide, wherein the polymeric substrate film comprises functional groups that interact with the functional groups of the vinyl fluoride copolymer to promote bonding of the fluoropolymer coating to the polymeric substrate film.

    摘要翻译： 本发明提供一种含氟聚合物涂覆膜，包括：聚合物基底膜; 和含氟聚合物涂层，所述含氟聚合物涂层包含由约40至约90摩尔％的衍生自氟乙烯的重复单元和约10至约60摩尔％的衍生自选自以下的单体的重复单元组成的氟乙烯共聚物： 由（a）和（b）组成的组和其混合物，共聚物中约0.1摩尔％至50摩尔％的重复单元衍生自选自（b）的单体：（a）选自 由四氟乙烯，三氟乙烯，一氯三氟乙烯及其混合物组成的组; 和（b）含有至少一种选自羟基，硫醇，羰基，羧酸，羧酸酯，酸酐，磺酰基，磺酸，磺酸酯，磷酸，磷酸酯，硼酸等的官能团的乙烯基单体， 硼酸酯，环氧化物，异氰酸酯，硫氰酸酯，胺，酰胺，腈和选自溴化物和碘化物的卤素，其中聚合物基底膜包含与氟乙烯共聚物的官能团相互作用以促进含氟聚合物涂层与 聚合物基底膜。

    Crosslinkable Vinyl Fluoride Copolymers
    5.
    发明申请
    Crosslinkable Vinyl Fluoride Copolymers 有权
    可交联乙烯基氟共聚物

    公开(公告)号：US20080154004A1

    公开(公告)日：2008-06-26

    申请号：US11962134

    申请日：2007-12-21

    申请人： Ronald Earl Uschold ,  Jian Wang ,  Masahiro Yamamoto

    发明人： Ronald Earl Uschold ,  Jian Wang ,  Masahiro Yamamoto

    IPC分类号： C08F14/20 ,  C09D127/00

    CPC分类号： C08F214/20 ,  C08F214/18 ,  C08F214/202 ,  Y10T428/2495 ,  Y10T428/24967 ,  Y10T428/26 ,  Y10T428/263 ,  Y10T428/264 ,  Y10T428/265 ,  Y10T428/266 ,  Y10T428/269 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31721 ,  Y10T428/31725 ,  Y10T428/3175 ,  Y10T428/31794 ,  Y10T428/31797 ,  Y10T428/31935

    摘要： The present invention provides a vinyl fluoride copolymer comprising: about 40 to about 90 mole % of repeat units derived from vinyl fluoride; and about 10 to about 60 mole % of repeat units derived from monomer selected from the group consisting of (a) and (b) below and mixtures thereof, with the proviso that about 0.1 mole % to 50 mole % of repeat units in the copolymer are derived from monomer selected from (b): (a) monomer selected from the group consisting of, tetrafluoroethylene, trifluoroethylene, chlorotrifluoroethylene and mixtures thereof; and (b) vinyl monomer containing at least one functional group selected from the group consisting of hydroxyls, thiols, carbonyls, carboxylic acids, carboxylic esters, acid anhydrides, sulfonyls, sulfonic acids, sulfonic esters, phosphoric acids, phosphoric esters, boric acids, boric esters, epoxies, isocyanates, thiocyanates, amines, amides, nitriles and halogen selected from bromide and iodide.

    摘要翻译： 本发明提供一种氟乙烯共聚物，其包含：约40至约90摩尔％的衍生自氟乙烯的重复单元; 和约10至约60摩尔％的衍生自下述（a）和（b）的单体的重复单元及其混合物，条件是共聚物中约0.1摩尔％至50摩尔％的重复单元 衍生自选自（b）的单体：（a）选自四氟乙烯，三氟乙烯，三氟氯乙烯及其混合物的单体; 和（b）含有至少一种选自羟基，硫醇，羰基，羧酸，羧酸酯，酸酐，磺酰基，磺酸，磺酸酯，磷酸，磷酸酯，硼酸等的官能团的乙烯基单体， 硼酸酯，环氧化物，异氰酸酯，硫氰酸酯，胺，酰胺，腈和选自溴化物和碘化物的卤素。

    Vinyl fluoride interpolymers of low crystallinity
    7.
    发明授权
    Vinyl fluoride interpolymers of low crystallinity 有权
    低结晶度的氟乙烯互聚物

    公开(公告)号：US06271303B1

    公开(公告)日：2001-08-07

    申请号：US09710965

    申请日：2000-11-13

    申请人： Ronald Earl Uschold

    发明人： Ronald Earl Uschold

    IPC分类号： C08L2714

    CPC分类号： C08F214/20 ,  C08F214/18 ,  C08F214/202 ,  C08F214/26 ,  C08F214/262 ,  Y10T428/31692 ,  Y10T428/31783

    摘要： An interpolymer consisting essentially of units derived from vinyl fluoride and at least two highly fluorinated monomers, at least one of the highly fluorinated monomers introducing into the polymer a side chain of at least one carbon atom. Films from these interpolymers have substantially reduced haze, low surface tension, and can be made to form solutions in common polar organic solvents that are stable at room temperature. The extremely low surface tensions obtained with these interpolymer films provide enhanced stain resistance and improved release properties compared to polyvinyl fluoride or known vinyl fluoride interpolymers.

    摘要翻译： 基本上由衍生自氟乙烯和至少两种高度氟化的单体的单元组成的互聚物，至少一种高度氟化的单体向聚合物中引入至少一个碳原子的侧链。 来自这些互聚物的膜具有显着降低的雾度，低表面张力，并且可以制成在室温下稳定的常用极性有机溶剂中形成溶液。 与聚氟乙烯或已知的氟乙烯互聚物相比，用这些互聚物膜获得的极低的表面张力提供了增强的耐污染性和改善的脱模性能。

    ELECTRODE COMPOSITIONS AND ENERGY STORAGE DEVICES
    9.
    发明申请
    ELECTRODE COMPOSITIONS AND ENERGY STORAGE DEVICES 审中-公开
    电极组合物和能源储存装置

    公开(公告)号：US20150332805A1

    公开(公告)日：2015-11-19

    申请号：US14703014

    申请日：2015-05-04

    申请人： E I DU PONT DE NEMOURS AND COMPANY

    发明人： MICHAEL JOSEPH BROWN ,  Biswajit Choudhury ,  Mookkan Periyasamy ,  Ronald Earl Uschold

    IPC分类号： H01B1/20 ,  H01M2/16 ,  H01M10/0525 ,  H01G9/042 ,  H01M4/62

    CPC分类号： H01B1/20 ,  C08F214/202 ,  C09D127/14 ,  H01G9/042 ,  H01M2/1673 ,  H01M4/623 ,  H01M10/0525

    摘要： In a first aspect, an electrode composition includes an electroactive material and an interpolymer including polymer units derived from about 64 to about 75 mole percent vinyl fluoride and from about 25 to about 36 mole percent of at least two highly fluorinated monomers. A first highly fluorinated monomer provides the interpolymer a side chain of at least one carbon atom.In a second aspect, an energy storage device includes an anode, a cathode, a porous separator between the anode and the cathode and an electrolyte. The anode, the cathode or both the anode and the cathode include a binder material including an interpolymer including polymer units derived from about 64 to about 75 mole percent vinyl fluoride and from about 25 to about 36 mole percent of at least two highly fluorinated monomers. A first highly fluorinated monomer provides the interpolymer a side chain of at least one carbon atom.

    摘要翻译： 在第一方面，电极组合物包括电活性材料和互聚物，其包含衍生自约64至约75摩尔％的氟乙烯和约25至约36摩尔％的至少两种高度氟化的单体的聚合物单元。 第一高度氟化的单体提供互聚物至少一个碳原子的侧链。 在第二方面，一种能量存储装置包括阳极，阴极，在阳极和阴极之间的多孔隔板和电解质。 阳极，阴极或阳极和阴极两者包括粘合剂材料，其包括互聚物，其包括衍生自约64至约75摩尔％的氟乙烯的聚合物单元和约25至约36摩尔％的至少两种高度氟化的单体。 第一高度氟化的单体提供互聚物至少一个碳原子的侧链。

    COPOLYMER, METHOD FOR ITS PRODUCTION, AND WATER/OIL REPELLENT COMPOSITION
    10.
    发明申请
    COPOLYMER, METHOD FOR ITS PRODUCTION, AND WATER/OIL REPELLENT COMPOSITION 审中-公开
    共聚物，其生产方法和水/油组合物

    公开(公告)号：US20110071248A1

    公开(公告)日：2011-03-24

    申请号：US12958906

    申请日：2010-12-02

    申请人： Kazunori Sugiyama ,  Toyomichi Shimada ,  Nobuyuki Otozawa ,  Yuuichi Oomori ,  Minako Shimada

    发明人： Kazunori Sugiyama ,  Toyomichi Shimada ,  Nobuyuki Otozawa ,  Yuuichi Oomori ,  Minako Shimada

    IPC分类号： C08F214/18 ,  C08L27/12 ,  C08F220/24

    CPC分类号： C08F214/18 ,  C08F214/202 ,  C08F214/222 ,  C08F216/1408 ,  C08F220/26 ,  C08F220/36 ,  C08F220/58 ,  C08F222/10 ,  C08F2220/1891 ,  C08F214/08

    摘要： To provide a copolymer which is capable of providing an article surface with a dynamic water repellency and which has extremely excellent washing durability of water repellency and oil repellency, while placing little burden on the environment; a method for its production; and a water/oil repellent composition.A copolymer comprising structural units of the monomer (a) and structural units of the monomer (b), wherein the total of the content of structural units based on the monomer (a) and the content of structural units based on the monomer (b) is at least 85 mass % of all structural units (100 mass %), and the molar ratio ((a)/(b)) of the content of structural units based on the monomer (a) to the content of structural units based on the monomer (b) is from 0.12 to 3; and a water/oil repellent composition containing such a copolymer. Monomer (a): a compound represented by (Z—Y)n—X, wherein Z is a C1-6 polyfluoroalkyl group or the like, Y is a bivalent organic group or a single bond, n is 1 or 2, and when n is 1, and X is a polymerizable unsaturated group. Monomer (b): a halogenated olefin.

    摘要翻译： 为了提供一种共聚物，其能够提供具有动态拒水性的物品表面，并且在环境上施加很小的负担的情况下具有非常优异的防水性和拒油性的洗涤耐久性。 一种生产方法; 和斥水斥油剂组合物。 包含单体（a）的结构单元和单体（b）的结构单元的共聚物，其中基于单体（a）的结构单元的含量和基于单体（b）的结构单元的含量的总和 基于单体（a）的结构单元的含量与基于单体（a）的结构单元的含量相比，所有结构单元（100质量％）的至少85质量％和结构单元的含量（（a）/（b） 单体（b）为0.12〜3; 和含有这种共聚物的斥水斥油剂组合物。 单体（a）：由（Z-Y）n -X表示的化合物，其中Z为C1-6多氟烷基等，Y为二价有机基团或单键，n为1或2，当 n为1，X为可聚合不饱和基团。 单体（b）：卤代烯烃。