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公开(公告)号:US11876169B2
公开(公告)日:2024-01-16
申请号:US17519565
申请日:2021-11-04
Applicant: SHENZHEN CAPCHEM TECHNOLOGY CO., LTD.
Inventor: Qiao Shi , Muchong Lin , Shiguang Hu , Jiaojiao Yun
IPC: H01M10/0525 , H01M4/131 , H01M10/0567 , H01M10/0569 , H01M4/02 , H01M10/0568
CPC classification number: H01M10/0525 , H01M4/131 , H01M10/0567 , H01M10/0569 , H01M10/0568 , H01M2004/028 , H01M2300/0025 , H01M2300/0028 , H01M2300/0037
Abstract: The application provides a non-aqueous electrolyte for lithium ion battery. The non-aqueous electrolyte for lithium ion battery comprises a compound A represented by formula I and a compound B represented by formula II,
In formula I, R1, R2 and R3 are independently selected from C1-C5 alkyl or haloalkyl, C2-C5 unsaturated hydrocarbon group or unsaturated halohydrocarbon group, and at least one of R1, R2 and R3 is the unsaturated hydrocarbon group or unsaturated halohydrocarbon group; In formula II, R4, R5, R6, R7, R8 and R9 are each independently selected from one of hydrogen atom, fluorine atom and C1-C5 group. The non-aqueous electrolyte for lithium ion battery provided by the application enables the battery to have excellent cycle performance and high-temperature storage performance through the synergistic effect of the compound A and the compound B.-
公开(公告)号:US20230411689A1
公开(公告)日:2023-12-21
申请号:US18034377
申请日:2021-10-28
Applicant: SHENZHEN CAPCHEM TECHNOLOGY CO., LTD.
Inventor: Chaowei Cao , Chi Wang , Qun Chen , Shiguang Hu
IPC: H01M10/0567 , H01M10/0525
CPC classification number: H01M10/0567 , H01M10/0525 , H01M2300/0025
Abstract: The present application belongs to the technical field of new energy, in particular to a non-aqueous electrolyte for a lithium ion battery and a lithium ion battery. The non-aqueous electrolyte for a lithium ion battery comprises a non-aqueous organic solvent, a lithium salt, and a spiro compound represented by Structural Formula 1. The compound represented by Structural Formula 1 has the characteristic of sulfonate additives to improve high-temperature storage performance of battery, and also has the characteristic of sulfate additives to improve high-temperature cycle performance of battery. A passivation film is deposited on the surface of positive electrode, and functional group X is further crosslinked to make the coated passivation film more compact and stable, which can effectively improve the electrochemical performance of the electrode, the storage performance and self-discharge performance of the battery.
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公开(公告)号:US20230231126A1
公开(公告)日:2023-07-20
申请号:US17772130
申请日:2022-04-06
Applicant: SHENZHEN CAPCHEM TECHNOLOGY CO., LTD.
Inventor: Yunxian Qian , Shiguang Hu , Yonghong Deng , Hongmei Li , Xiaoxia Xiang
IPC: H01M4/525 , H01M4/36 , H01M10/0525 , H01M4/62
CPC classification number: H01M4/525 , H01M4/366 , H01M10/0525 , H01M4/625
Abstract: Provided is a lithium ion battery, comprising a positive electrode containing a positive electrode material layer, a negative electrode and a non-aqueous electrolyte, the layer comprises a positive electrode active material, the material comprises LixNiyCozM1-y-zO2, M is at least one element selected from Mn and Al, the material is doped or coated with an element E, which is selected from one or more of Ba, Zn, Ti, Mg, Zr, W, Y, Si, Sn, B, Co, and P, a potential range of the positive electrode active material with respect to lithium metal is ≥4.25V;
the non-aqueous electrolyte comprises a solvent, an electrolyte salt and an additive, the additive comprises a compound represented by structural formula 1:
the lithium ion battery meets the following requirements:
0.1≤(H/T)×M/1000≤10; and
80≤H≤150,0.005≤T≤0.8,0.05≤M≤3.
The lithium ion battery provided by the application has a lower battery impedance and excellent high-temperature cycle performance.-
公开(公告)号:US11362370B2
公开(公告)日:2022-06-14
申请号:US16316621
申请日:2016-12-30
Applicant: SHENZHEN CAPCHEM TECHNOLOGY CO., LTD.
Inventor: Qiao Shi , Muchong Lin , Shiguang Hu , Xionggui Lin , Jiaojiao Yun , Chang'an Zeng
IPC: H01M10/0567 , H01M10/0525 , H01M10/0569 , C07D317/10 , C07D327/10 , C07F9/06 , C07F9/113 , H01M10/056
Abstract: A non-aqueous electrolyte for a lithium-ion battery and a lithium-ion battery. The non-aqueous electrolyte comprises unsaturated phosphate compounds and unsaturated cyclic carboxylic acid anhydride compounds. The unsaturated phosphate compounds have the structure illustrated in structural formula 4; structural formula 4: R13, R11, and R12 are independently selected from hydrocarbon groups having 1-5 carbon atoms respectively, and at least one of R13, R11, and R12 is an unsaturated hydrocarbon group containing double bonds or triple bonds; the unsaturated cyclic carboxylic acid anhydride compounds have the structure illustrated in structural formula 5; structural formula 5: R14 is independently selected from vinylidene having 2-4 carbon atoms or fluoro-substituted vinylidene. By means of the synergistic effect of two compounds, the non-aqueous electrolyte has excellent high-temperature cycling performance and storage performance, and also has lower impedance and good low-temperature performance.
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公开(公告)号:US11362369B2
公开(公告)日:2022-06-14
申请号:US16205258
申请日:2018-11-30
Applicant: SHENZHEN CAPCHEM TECHNOLOGY CO., LTD.
Inventor: Qiao Shi , Shiguang Hu , Qun Chen , Li Wang , Zhou He , Jiaojiao Yun
IPC: H01M10/0567 , H01M10/0525 , H01M10/0569 , H01M4/505 , H01M4/02 , H01M4/525
Abstract: A lithium-ion battery non-aqueous electrolyte and a lithium-ion battery. The non-aqueous electrolyte comprises at least one selected from the compounds represented by structural formula I and II; in formula I, R1 and R2 are independently selected from alkenyl having 2-5 carbon atoms and alkynyl having 2-5 carbon atoms; in formula II, R3 is selected from alkenyl having 2-5 carbon atoms and alkynyl having 2-5 carbon atoms. The compound represented by formula I or II is added in the electrolyte; the compound contains unsaturated bond(s) and hexafluorisopropyl; the unsaturated bond(s) form passivation film on cathode and anode surfaces to inhibit decomposition of the electrolyte on the cathode & anode surface and damage of the cathode material structure; moreover, the polymerization degree of unsaturated bond(s) can be inhibited to some extent due to steric hindrance relationship of fluoroisopropyl functional groups, so as to improve high-temperature performance of the lithium-ion battery while guaranteeing low-temperature performance.
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公开(公告)号:US11302963B2
公开(公告)日:2022-04-12
申请号:US16490897
申请日:2017-06-21
Applicant: SHENZHEN CAPCHEM TECHNOLOGY CO., LTD.
Inventor: Qiao Shi , Chang'an Zeng , Muchong Lin
IPC: H01M10/0567 , H01M10/0525 , H01M10/42 , H01M10/0568
Abstract: In order to solve the problem of poor cycle performance (especially high temperature cycle performance) of the existing lithium ion battery electrolyte containing anhydride or anhydride derivatives, the disclosure provides a non-aqueous electrolyte for lithium ion battery. The non-aqueous electrolyte for lithium ion battery comprises a compound A represented by formula I and a compound B represented by formula II, In the structural formula I, R0 is C2-C4 alkylene or alkenylene, or C2-C4 fluoroalkylene or fluoroalkenylene; In formula II, R1, R2, R3, R4, R5 and R6 are each independently selected from one of hydrogen atom, fluorine atom and C1-C5 group. The non-aqueous electrolyte for lithium ion battery provided by the invention is obtained by combining the compound A and compound B, so that the lithium ion battery containing the non-aqueous electrolyte has better cycle performance and high-temperature storage performance.
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公开(公告)号:US20210050623A1
公开(公告)日:2021-02-18
申请号:US16978765
申请日:2018-06-27
Applicant: SHENZHEN CAPCHEM TECHNOLOGY CO., LTD.
Inventor: Qiao Shi , Qiujun Wang , Zhongbo Liu
IPC: H01M10/0565 , H01M10/0525 , H01M4/525 , H01M4/505 , H01M4/38 , H01M4/583
Abstract: Provided is a polymer electrolyte for lithium ion battery and a polymer battery, comprising polyether polymer and lithium salt, wherein the molar ratio of lithium ions in the lithium salt to oxygen atoms in ether bonds of the polyether polymer is more than 1/4; the polyether polymer comprises polymer of Formula 1: A-Rn; A is a hydrocarbyl group or an oxygen-containing hydrocarbyl group, n is an integer, and n≥1; R is O—Ram1O—Rbn1Rx; Ra and Rb are selected from alkylene, and Rx is selected from organic functional groups and halogen; m1 is a natural number greater than 0, n1 is a natural number, and when n1 is 0, n≥3. Preferably, the ratio of the total number of carbon atoms in all repeating units of the polyether polymer to the total number of repeating units is over 4; More preferably, the polyether polymer has a branched structure.
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公开(公告)号:US10084205B2
公开(公告)日:2018-09-25
申请号:US15037699
申请日:2014-10-22
Applicant: SHENZHEN CAPCHEM TECHNOLOGY CO., LTD.
Inventor: Qiao Shi , Muchong Lin , Dixiong Zhou
IPC: H01M10/056 , H01M10/0567 , H01M10/0525 , H01M4/505 , H01M4/525 , H01M4/02
CPC classification number: H01M10/0567 , H01M4/505 , H01M4/525 , H01M10/0525 , H01M2004/028 , H01M2300/0034 , H01M2300/0042
Abstract: The present invention relates to electrolyte of a high-voltage lithium-ion battery, comprising a non-aqueous organic solvent, lithium salt and an electrolyte additive; the electrolyte additive comprises the following ingredients based on the total weight of the electrolyte: 1%-10% of fluoroethylene carbonate, 1%-5% of dinitrile compound and 0.1%-2% of 2-methyl maleic anhydride; further, the electrolyte can be further added with additives such as 0.2%-2% of lithium bisoxalatoborate and 1,3-propane sultone. The present invention also relates to a high-voltage lithium-ion battery using the electrolyte, with the charging cut-off voltage being greater than 4.2V and smaller than or equal to 4.5V. The electrolyte of the high-voltage lithium-ion battery provided by the present invention can protect the positive electrode and also form good SEI at the negative electrode, and the high-voltage lithium-ion battery has good cycle performance and storage performance.
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公开(公告)号:US20180269528A1
公开(公告)日:2018-09-20
申请号:US15760799
申请日:2015-09-23
Applicant: SHENZHEN CAPCHEM TECHNOLOGY CO., LTD
Inventor: Zhenghua Zhang , Xueshan Hu
IPC: H01M10/0567 , H01M10/0525 , H01M10/0568 , H01M10/0569 , H01M4/36 , H01M4/485 , H01M4/587 , H01M4/525 , H01M4/505 , H01M4/62 , H01M4/131 , H01M10/42
CPC classification number: H01M10/0567 , H01M4/131 , H01M4/366 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/587 , H01M4/628 , H01M10/0525 , H01M10/0568 , H01M10/0569 , H01M10/4235 , H01M2004/027 , H01M2300/0037
Abstract: A lithium ion battery comprising at least one cathode, at least one anode comprising LTO having an optional surface coating, and an electrolyte composition, where the electrolyte composition comprises an organic solvent, one or more lithium salts, one or more SEI forming additives selected from the group consisting of a) alkali metal salts of borates, b) organoboron compounds, c) imides, d) sulfates and e) sulfites; and one or more moisture removing additives selected from the group consisting of f) anhydrides g) nitriles, h) tertiary amines, and i) amides.
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公开(公告)号:US20180076483A1
公开(公告)日:2018-03-15
申请号:US15557780
申请日:2015-10-09
Applicant: SHENZHEN CAPCHEM TECHNOLOGY CO., LTD
Inventor: Qiao SHI , Muchong LIN , Guchun CHEN , Shiguang HU
IPC: H01M10/0567 , H01M10/0525 , H01M10/0568 , H01M10/0569 , H01M4/48 , H01M10/46
CPC classification number: H01M10/0567 , H01M4/48 , H01M4/505 , H01M4/525 , H01M10/0525 , H01M10/0568 , H01M10/0569 , H01M10/46 , H01M2004/028 , H01M2300/0037
Abstract: A non-aqueous electrolyte of a lithium-ion battery and a lithium-ion battery. The electrolyte comprises a non-aqueous organic solvent, a lithium salt and an additive. The additive comprises substances containing the following compounds (A) and (B): (A), where R1, R2, R3 are independently selected from hydrocarbon groups having 1 to 4 carbon atoms respectively, and at least one of R1, R2, R3 is an unsaturated hydrocarbon group containing a triple bond; (B) lithium bis(fluorosulfonyl)imide. The nonaqueous electrolyte of the lithium-ion battery enables the lithium-ion battery to have a lower impedance and better low-temperature and high-temperature performances.
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