公开(公告)号：US20170158575A1

公开(公告)日：2017-06-08

申请号：US14902181

申请日：2014-06-27

Applicant: BASF SE

Inventor： Karl-Heinrich Schneider ,  Claudia Klodwig ,  Gregor Pasda ,  Alexander Wissemeier ,  Daniella Lohe ,  Achim Reddig ,  Christian Miyagawa ,  Wolfram Zerulla ,  Steffen Tschirschwitz ,  Ralf-Thomas Rahn ,  Ansgar Gereon Altenhoff ,  Stephan Hüffer

IPC: C05G3/08 ,  C05G3/00 ,  C09D5/00 ,  C09D179/02 ,  C09K15/22 ,  C09K15/18 ,  C09K15/06 ,  C05C9/00 ,  C09K15/28

CPC classification number: C05G3/08 ,  C05C9/00 ,  C05C9/005 ,  C05C11/00 ,  C05G3/0029 ,  C05G3/0041 ,  C09D5/00 ,  C09D179/02 ,  C09K15/06 ,  C09K15/10 ,  C09K15/18 ,  C09K15/22 ,  C09K15/26 ,  C09K15/28 ,  C09K15/30

Abstract: An composition comprising: (A) a mixture comprising at least one (thio)phosphoric acid triamide according to the general formula (I) R1R2N—P(X)(NH2)2, wherein X is oxygen or sulfur; R1 is a C1 to C20 alkyl, C3 to C20 cycloalkyl, C6 to C20 aryl, or dialkylaminocarbonyl group; R2 is H, or R1 and R2 together with the nitrogen atom linking them define a 5- or 6-membered saturated or unsaturated heterocyclic radical, which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur, and (C) at least one amine selected from the group consisting of (C1) a polymeric polyamine, and (C2) an amine containing not more than one amino group and at least three alkoxy- or hydroxy-substituted C2 to C12 alkyl groups R21, wherein at least one of the groups R21 is different to the other groups R21, and (C3) an amine containing not more than one amino group and at least two alkoxy- or hydroxy-substituted C2 to C12 alkyl groups R22, wherein at least one of the groups R22 bears the alkoxy or hydroxy substituent at a secondary or tertiary carbon atom and wherein at least one of the groups R22 is different to the other group(s) R22, and (C4) an amine containing at least one saturated or unsaturated C8 to C40 alkyl group R23, and (C5) a saturated or unsaturated heterocyclic amine which contains at least one oxygen atom as ring atom and which does not contain a further alkoxy group.

公开(公告)号：US20150148231A1

公开(公告)日：2015-05-28

申请号：US14406398

申请日：2013-02-15

Applicant: BASF SE

Inventor： Barbara Nave ,  Lutz Brahm ,  Daniella Lohe ,  Alexander Wissemeier ,  Wolfram Zerulla ,  Achim Reddig ,  Markus Schmid ,  Gregor Pasda

IPC: C05G3/08 ,  C05G3/02 ,  A01N47/24

CPC classification number: C05G3/08 ,  A01N25/00 ,  A01N47/24 ,  C05G3/02 ,  Y02P60/218 ,  A01N37/50 ,  A01N43/16 ,  A01N43/40 ,  A01N43/54 ,  A01N43/56 ,  A01N43/88

Abstract: The present invention relates to an agrochemical mixture for reducing nitrous oxide and/or ammonia emission from soils, comprising:1) a composition (component A) comprising N-n-butylthiophosphoric triamide (NBTPT) and/or N-n-propylthiophosphoric triamide (NPTPT); and2) at least one strobilurin (component B) selected from the group consisting of pyraclostrobin, azoxystrobin, dimoxystrobin, enestroburin, fluoxastrobin, kresoxim-methyl, metominostrobin, orysastrobin, picoxystrobin, trifloxystrobin, pyrametostrobin, pyraoxystrobin, coumoxystrobin, coumethoxystrobin, fenaminostrobin (=diclofenoxystrobin), flufenoxystrobin, 2-(2-(6-(3-chloro-2-methyl-phenoxy)-5-fluoro-pyrimidin-4-yloxy)-phenyl)-2-methoxyimino-N-methyl-acetamide, 3-methoxy-2-(2-(N-(4-methoxy-phenyl)-cyclopropane-carboximidoylsulfanylmethyl)-phenyl)-acrylic acid methyl ester, methyl (2-chloro-5-[(1-(3-methylbenzyloxyimino)ethyl]benzyl)carbamate and 2-(2-(3-(2,6-dichlorophenyl)-1-methyl-allylideneaminooxymethyl)-phenyl)-2-methoxyimino-N methyl-acetamidein synergistically effective amounts.In addition, the present invention relates to the use of a mixture as defined above for synergistically reducing nitrous oxide emission from soils.Moreover, the present invention relates to the use of a mixture as defined above for synergistically reducing ammonia emission from soils.

Abstract translation: 本发明涉及用于从土壤中还原一氧化二氮和/或氨排放的农用化学混合物，其包括：1）包含N-正丁基硫代磷酸三酰胺（NBTPT）和/或N-正丙基硫代磷酰三胺（NPTPT）的组合物（组分A） 至少一种选自以下的嗜球果伞素（组分B），其由选自嘧菌酯，嘧菌酯，二恶霉素，依维酮磺隆，氟草胺酯，甲氧基甲基，美托品酮，奥沙司他啶，嘧菌酯，肟菌酯，吡拉莫司托，吡唑斯特灵，呋喃霉菌素， （2-（6-（3-氯-2-甲基 - 苯氧基）-5-氟 - 嘧啶-4-基氧基） - 苯基）-2-甲氧基亚氨基-N-甲基 - 乙酰胺，3 - 甲氧基-2-（2-（N-（4-甲氧基 - 苯基） - 环丙烷 - 甲酰亚氨基硫基甲基） - 苯基） - 丙烯酸甲酯，（2-氯-5 - [（1-（3-甲基苄氧基亚氨基）乙基 ]苄基）氨基甲酸酯和2-（2-（3-（2,6-二氯苯基）-1-甲基 - 烯丙基氨基氧基甲基） - 苯基）-2-甲氧基亚氨基-N-甲基 - 乙酰胺，另外，本发明 涉及如上定义的混合物的用途，协同地减少来自土壤的一氧化二氮排放物。此外，本发明涉及使用 的混合物，以协同地减少土壤中的氨排放。

公开(公告)号：US20230250036A1

公开(公告)日：2023-08-10

申请号：US17781143

申请日：2020-12-04

Applicant: BASF SE

Inventor： Manuel Daumann ,  Lars Neubert ,  Gregor Pasda ,  Wolfram Zerulla ,  Jonas Goossens ,  Xavier Scheldeman

IPC: C05G3/90 ,  C05B15/00

CPC classification number: C05G3/90 ,  C05B15/00

Abstract: A method for improving the health of a plant, comprising treating a plant growing on soil or soil substituents and/or treating the locus where the plant is growing or is intended to grow with at least one (thio)phosphoric acid triamide according to the general formula (I) wherein X is oxygen or sulfur, R1 and R2 are—independent from each other—H, substituted or unsubstituted 2-nitrophenyl, C1 to C20 alkyl, C3 to C20 cycloalkyl, C6 to C20 heterocycloaryl, C6 to C20 aryl, or dialkylaminocarbonyl group wherein R1 and R2 together with the nitrogen atom linking them define a 5- or 6-membered saturated or unsaturated heterocyclic radical, which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur, wherein improved plant health is determined by —increased crop biomass or crop yield, —improved plant vigor, —improved plant quality, and/or —improved tolerance or resistance of the plant to abiotic stress factors.

公开(公告)号：US11659837B2

公开(公告)日：2023-05-30

申请号：US16630047

申请日：2018-07-05

Applicant: BASF SE

Inventor： Barbara Nave ,  Gregor Pasda ,  Alexander Wissemeier ,  Maarten Staal ,  Karl-Heinrich Schneider ,  Markus Schmid ,  Wolfram Zerulla ,  Daniella Lohe ,  Sascha Shuxia Zhu ,  Wolfgang Weigelt ,  Manuel Daumann

IPC: A01N43/56 ,  A01N57/28 ,  C05G3/60 ,  C05G3/90

CPC classification number: A01N43/56 ,  A01N57/28 ,  C05G3/60 ,  C05G3/90

Abstract: Described herein are mixtures including as active components at least one specific nitrification inhibitor (compound I) and at least one urease inhibitor (compound II). Also described herein are a method for improving the nitrification-inhibiting effect, or for increasing the health of a plant using mixtures of at least one compound I and at least one compound II and a method of using the mixtures comprising compounds I and compounds II for increasing the health of a plant. Also described herein are agrochemical compositions including these mixtures. Also described herein is plant propagation material including these mixtures or these agrochemical compositions.

公开(公告)号：US11246258B2

公开(公告)日：2022-02-15

申请号：US16655755

申请日：2019-10-17

Applicant: BASF SE

Inventor： Wolfram Zerulla ,  Markus Schmid ,  Gregor Pasda

IPC: A01C21/00 ,  A01C15/00 ,  A01C23/04 ,  C05G3/90 ,  A01C23/00

Abstract: The present invention relates to methods and vehicles for separately applying a solid fertilizer and a liquid fertilizer additive to a working area of a field.

公开(公告)号：US20210155560A1

公开(公告)日：2021-05-27

申请号：US17046012

申请日：2019-04-01

Applicant: BASF SE

Inventor： Markus Schmid ,  Wolfram Zerulla ,  Nadine Tresch ,  Maarten Staal ,  Uwe Thiel ,  Gregor Pasda ,  Karl-Heinrich Schneider

IPC: C05G3/90 ,  C05C9/00 ,  C07F9/22

Abstract: Method for obtaining a fertilizer composition comprising (iii) at least one urea-containing fertilizer (1); and (iv) at least one (thio)phosphoric acid triamide (2) according to general formula (I) wherein X1 is O or S; R1 is C1-C20-alkyl, C3-C20-cycloalkyl, C6-C20-aryl, C6-C20-aryl-C1-C4-alkyl, or C1-C6-(di)alylaminocarbonyl; R2 is H, C1-C20-alkyl, C3-C20-cycloalkyl, C6-C20-aryl, C6-C20-aryl-C1-C4-alkyl, or C1-C6-(di)alkylaminocarbonyl; or R1 and R2 together with the nitrogen atom linking them define a 5- or 6-membered saturated or unsaturated heterocyclic radical, which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of N, O, and S; and R3, R4, R5, and R6 are independently of each other selected from the group consisting of H and C1-C4-alkyl; comprising the steps: a) providing a solid and/or liquid premix (P) wherein the premix (P) comprises at least one urea-containing fertilizer (1) and at least one (thio)phosphoric acid triamide (2) in a weight ratio of 1:6 to 400:1 based on the total weight of all urea-containing fertilizers (1) and of all (thio)phosphoric acid triamides (2), wherein at least 85 wt % of the premix (P) (a1) is not a melt; and (a2) is not obtained via melting of any of the at least one urea-containing fertilizer (1) or melting of any of the at least one (thio)phosphoric acid triamide (2); and (a3) is not obtained via dissolving or mixing the at least one (thio)phosphoric acid tri-amide (2) in/with a solvent (S) having a boiling point of less than 100° C., and b) adding the premix (P) to a melt (Q) comprising urea-containing fertilizer (1) by forming a mixture (M) n comprising the at least one urea-containing fertilizer (1) and the at least one (thio)phosphoric acid triamide (2), wherein the residence time of the thus formed mixture (M) before granulation is adjusted such that the at least one (thio)phosphoric acid tri-amide (2) is not or almost not decomposed in the mixture (M); and c) forming solid fertilizer granules by use of the mixture (M) comprising the at least one urea-containing fertilizer (1) and the at least one (thio)phosphoric acid triamide (2).

公开(公告)号：US20200157018A1

公开(公告)日：2020-05-21

申请号：US16748890

申请日：2020-01-22

Applicant: BASF SE

Inventor： Markus Schmid ,  Wolfram Zerulla ,  Gregor Pasda ,  Alexander Wissemeier ,  Tobias Lang ,  Karl-Heinrich Schneider ,  Zoltan Baan ,  Maarten Staal ,  Ansgar Gereon Altenhoff ,  Kian Molawi ,  Sophia Ebert ,  Olivier Fleischel

IPC: C05G5/30 ,  C07F9/22 ,  C05G3/90

Abstract: A composition comprising: (A) a mixture comprising at least one (thio)phosphoric acid triamide according to the general formula (I) R1R2N—P(X)(NH2)2, wherein X is oxygen or sulfur; R1 is a C1 to C20 alkyl, C3 to C20 cycloalkyl, C6 to C20 aryl, or dialkylaminocarbonyl group; R2 is H, or R1 and R2 together with the nitrogen atom linking them define a 5- or 6-membered saturated or unsaturated heterocyclic radical, which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur, and (L1) at least one amine selected from the group consisting of (L10), (L11), (L12), (L13), (L14), (L15), (L16), (L17), (L18), (L19), (L20), (L21), (L22), (L23), (L24), and (L29).

公开(公告)号：US10577290B2

公开(公告)日：2020-03-03

申请号：US15538963

申请日：2015-12-22

Applicant: BASF SE

Inventor： Markus Schmid ,  Wolfram Zerulla ,  Gregor Pasda ,  Alexander Wissemeier ,  Tobias Lang ,  Karl-Heinrich Schneider ,  Zoltan Baan ,  Maarten Staal ,  Ansgar Gereon Altenhoff ,  Kian Molawi ,  Sophia Ebert ,  Olivier Fleischel

IPC: C05G3/00 ,  C05G3/08 ,  C07F9/22

Abstract: A composition comprising: (A) a mixture comprising at least one (thio)phosphoric acid triamide according to the general formula (I) R1R2N—P(X)(NH2)2, wherein X is oxygen or sulfur; R1 is a C1 to C20 alkyl, C3 to C20 cycloalkyl, C6 to C20 aryl, or dialkylaminocarbonyl group; R2 is H, or R1 and R2 together with the nitrogen atom linking them define a 5- or 6-membered saturated or unsaturated heterocyclic radical, which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur, and (L1) at least one amine selected from the group consisting of (L10), (L11), (L12), (L13), (L14), (L15), (L16), (L17), (L18), (L19), (L20), (L21), (L22), (L23), (L24), and (L29).

公开(公告)号：US20190112241A1

公开(公告)日：2019-04-18

申请号：US16088920

申请日：2017-03-23

Applicant: BASF SE

Inventor： Maarten Staal ,  Johannes G Reuvers ,  Wolfram Zerulla ,  Markus Schmid ,  Uwe Thiel

IPC: C05G3/08 ,  C05C9/00 ,  C05B7/00 ,  C05G3/00

Abstract: A cation source to prevent decomposition of a (thio)phosphoric acid triamide is disclosed. A method for preventing decomposition of a (thio)phosphoric acid triamide by adding a cation source is disclosed. A mixture comprising a cation source and a (thio)phosphoric acid triamide is disclosed. A granule coated with a cation source and comprising a fertilizer is disclosed. A composition obtainable by specific processes and comprising a (thio)phosphoric acid triamide, a fertilizer mixture, and a cation source is disclosed.

公开(公告)号：US10150712B2

公开(公告)日：2018-12-11

申请号：US14902181

申请日：2014-06-27

Applicant: BASF SE

Inventor： Karl-Heinrich Schneider ,  Claudia Klodwig ,  Gregor Pasda ,  Alexander Wissemeier ,  Daniella Lohe ,  Achim Reddig ,  Christian Carlos Miyagawa ,  Wolfram Zerulla ,  Steffen Tschirschwitz ,  Ralf-Thomas Rahn ,  Ansgar Gereon Altenhoff ,  Stephan Hüffer

IPC: C05C9/00 ,  C05G3/00 ,  C05G3/08 ,  C09K15/30 ,  C05C11/00 ,  C09K15/10 ,  C09K15/26 ,  C09D5/00 ,  C09D179/02 ,  C09K15/06 ,  C09K15/18 ,  C09K15/22 ,  C09K15/28

Abstract: An composition comprising: (A) a mixture comprising at least one (thio)phosphoric acid triamide according to the general formula (I) R1R2N—P(X)(NH2)2, wherein X is oxygen or sulfur; R1 is a C1 to C20 alkyl, C3 to C20 cycloalkyl, C6 to C20 aryl, or dialkylaminocarbonyl group; R2 is H, or R1 and R2 together with the nitrogen atom linking them define a 5- or 6-membered saturated or unsaturated heterocyclic radical, which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur, and (C) at least one amine selected from the group consisting of (C1) a polymeric polyamine, and (C2) an amine containing not more than one amino group and at least three alkoxy- or hydroxy-substituted C2 to C12 alkyl groups R21, wherein at least one of the groups R21 is different to the other groups R21, and (C3) an amine containing not more than one amino group and at least two alkoxy- or hydroxy-substituted C2 to C12 alkyl groups R22, wherein at least one of the groups R22 bears the alkoxy or hydroxy substituent at a secondary or tertiary carbon atom and wherein at least one of the groups R22 is different to the other group(s) R22, and (C4) an amine containing at least one saturated or unsaturated C8 to C40 alkyl group R23, and (C5) a saturated or unsaturated heterocyclic amine which contains at least one oxygen atom as ring atom and which does not contain a further alkoxy group.