Abstract:
Continuous reductive dehydroxymethylation process for the preparation of alkanes from primary aliphatic alcohols, having 3 to 25 carbon atoms, in the presence of hydrogen and a catalyst in a reactor at a pressure of ≥2 bar, characterized in that the dehydroxymethylation takes place in the vapor phase.
Abstract:
A process for the preparation of amino alcohols includes condensing a compound of Formula (II), a stereoisomer, a tautomer, or a salt thereof with a compound of Formula (IIIa) or Formula (IIIb), a stereoisomer, a tautomer, or a salt thereof to form a condensation product; hydroxylating or acyloxylating the condensation product in the presence of an oxidant to obtain a hydroxylation or acyloxylation product; and subjecting the hydroxylation or acyloxylation product to one or more subsequent reactions comprising a hydrolysis reaction, alcohol deprotection, an amino lysis reaction, or a combination of two or more thereof to obtain an amino alcohol of Formula (I).
Abstract:
The invention relates to a process for the production of 1,6-difunctionalized hexane derivatives from 1,3-diunsaturated hydrocarbons, preferably butadiene, wherein a hydroformylation with carbon monoxide and hydrogen is performed in the presence of an at least dihydric alkanol and during the hydroformylation the temperature is increased. The reaction yields the acetals of the 1,6-hexanedial derivatives which are isolated and further reacted to obtain the desired 1,6-difunctionalized hexane derivatives, in particular 1,6-hexanediamine, 1,6-hexanediol and adipic acid.
Abstract:
Poly(oxyalkylene)oxy- and/or poly(oxyalkylene)aminoalkyltrialkoxysilanes are of the general formula (I) where —X— is —O— or —N(R4)2-a—; —Y— is —CH2—; —Z— is —O—(CH2)d—C(R5)2-c—; a is 1 if —X—═—O—, and is 1 or 2 if —X—═—N(R4)2-a—; b is 0 or 1; c is 0, 1 or 2; d is 0 or 1; m is independently from an integer from 1 to 6; p is a number from 7 to 200; R1 is independently methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl, tert-butyl, or phenyl; R2 is H or methyl; R3, R4, and R5 are independently H or linear or branched C1-C6-alkyl; R6 is independently H, methyl or ethyl; and R7 is H, linear or branched C1-C6-alkyl, linear or branched C1-C10-alkanoyl, or C6-C10-aryloyl; as dispersants for aqueous suspensions composed of aggregates and hydraulic binders, and to aqueous suspensions. Also provided: a process for preparing the alkyltrialkoxysilanes.
Abstract:
A process for producing a compound of the formula (I) involves at least reacting a compound of the formula (II) with hydrogen and water in the presence of at least one homogeneous transition metal catalyst TMC 1.
Abstract:
A process for producing a compound of the formula (T) involves at least reacting a compound of the formula (U) with hydrogen and water in the presence of at least one homogeneous transition metal catalyst TMC 1.
Abstract:
The present invention relates to a two-stage hydroformylation process for producing pound of the formula (I) and to a process for producing a compound of the formula (V) comprising the two-stage hydroformylation process for producing a compound of the formula (I) followed by hydrogenation of the compound of the formula (I).