公开(公告)号：US20100105543A1

公开(公告)日：2010-04-29

申请号：US12530280

申请日：2007-10-31

申请人： Chun-Byung Yang ,  Joon-Ryeo Park

发明人： Chun-Byung Yang ,  Joon-Ryeo Park

IPC分类号： C08F4/654

CPC分类号： C08F10/06 ,  C08F110/06 ,  C08F4/651 ,  C08F4/6543 ,  C08F2500/12

摘要： A preparation method of a solid titanium catalyst for olefin polymerization characteristically comprises the steps of: (1) obtaining a magnesium compound solution by dissolving a magnesium halide compound in an oxygen-containing solvent that is a mixed solvent of a cyclic ether and at least one of alcohols; (2) preparing a carrier by primarily reacting the obtained magnesium compound solution with a titanium halide compound at −10-30° C., then raising a temperature or aging so as to obtain particles, and secondly reacting the particles with a titanium halide compound; (3) preparing a catalyst by reacting the carrier with a titanium halide compound and an electron donor of phthalic acid dialkylester having a C9-13 alkyl group; and (4) washing the prepared catalyst with a hydrocarbon solvent at 40-200° C.

摘要翻译： 一种用于烯烃聚合的固体钛催化剂的制备方法，其特征在于包括以下步骤：（1）通过将卤化镁化合物溶解在作为环醚和至少一种的醚的混合溶剂的含氧溶剂中来获得镁化合物溶液 的醇类 （2）通过在-10-30℃下使得到的镁化合物溶液与卤化钛化合物主要反应制备载体，然后升高温度或老化以获得颗粒，并且其次使该颗粒与卤化钛化合物 ; （3）通过使载体与卤化钛化合物和具有C 9-13烷基的邻苯二甲酸二烷基酯的电子给体反应制备催化剂; 和（4）用烃溶剂在40-200℃下洗涤制备的催化剂

公开(公告)号：US20090215611A1

公开(公告)日：2009-08-27

申请号：US12274069

申请日：2008-11-19

申请人： Chun-Byung Yang ,  Jong-Sik Kim ,  Jin-Kyu Ahn ,  Joon-Ryeo Park

发明人： Chun-Byung Yang ,  Jong-Sik Kim ,  Jin-Kyu Ahn ,  Joon-Ryeo Park

IPC分类号： C08F4/50

CPC分类号： C08F10/00 ,  C08F110/02 ,  C08F4/651 ,  C08F4/6565 ,  C08F2500/18 ,  C08F2500/24

摘要： Provided is a preparation method of a catalyst for ethylene (co)polymerization, comprising the following steps: (1) preparing a magnesium compound solution by contact-reacting a halogenated magnesium compound with a mixed solvent of cyclic ether and at least one alcohol; (2) reacting the resulted magnesium compound solution from the above step (1) with a silicon compound having at least one alkoxy group; (3) preparing a support by adding a titanium compound to the resulted product from the step (2); and (4) reacting thus obtained support with a titanium compound and optionally a monoester compound, resulting in a catalyst. Catalysts prepared according to the present invention have a regulated particle shape, and their particle size can be easily adjusted. Therefore, with such catalyst, it is possible to produce polymers having high bulk density at high production yield.

摘要翻译： 提供了一种乙烯（共）聚合催化剂的制备方法，包括以下步骤：（1）通过使卤代镁化合物与环醚和至少一种醇的混合溶剂接触反应来制备镁化合物溶液; （2）使所得到的上述步骤（1）的镁化合物溶液与具有至少一个烷氧基的硅化合物反应; （3）通过向步骤（2）得到的产物中加入钛化合物制备载体; 和（4）使由此获得的载体与钛化合物和任选的单酯化合物反应，得到催化剂。 根据本发明制备的催化剂具有调节的颗粒形状，并且其粒度可以容易地调节。 因此，通过这样的催化剂，能够以高的产率制造高堆积密度的聚合物。

公开(公告)号：US6034025A

公开(公告)日：2000-03-07

申请号：US989292

申请日：1997-12-11

申请人： Chun-Byung Yang ,  Mie-Ock Kim

发明人： Chun-Byung Yang ,  Mie-Ock Kim

IPC分类号： C08F4/02 ,  C08F4/64 ,  C08F4/645 ,  C08F4/654 ,  C08F10/00 ,  C08F110/06 ,  B01J31/00 ,  B01J37/00 ,  C08F4/60

CPC分类号： C08F110/06

摘要： A method for producing a catalyst for the polymerization or copolymerization of olefins is described. The method includes producing a magnesium compound solution by reacting a magnesium halide compound in the mixture of a cyclic ether and two alcohols with an organosilane compound. The magnesium compound solution may be reacted with a titanium halide compound such that precipitated solid components are formed. These precipitated solid components may be reacted with a titanium compound and an electron donor to produce the polymerization catalyst.

摘要翻译： 描述了用于制备用于烯烃聚合或共聚的催化剂的方法。 该方法包括通过使环醚和两种醇的混合物中的卤化镁化合物与有机硅烷化合物反应制备镁化合物溶液。 镁化合物溶液可以与卤化钛化合物反应，形成沉淀的固体组分。 这些沉淀的固体组分可以与钛化合物和电子给体反应以产生聚合催化剂。