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公开(公告)号：US4524029A
公开(公告)日：1985-06-18
申请号：US534911
申请日：1983-09-22
CPC分类号： C11C1/005
摘要： This invention comprises a process for separating a saturated fatty acid from a feed mixture comprising saturated and unsaturated fatty acids, which process comprises contacting the mixture at separation conditions with a molecular sieve comprising a crystalline silica, thereby selectively retaining the saturated fatty acid. The saturated fatty acid is recovered from the molecular sieve by displacement at displacement conditions with a displacement fluid comprising a diluent soluble in the feed mixture and having a polarity index of at least 3.5. Amorphous silica is a preferred binder for the molecular sieve.
摘要翻译： 本发明包括从包含饱和和不饱和脂肪酸的进料混合物中分离饱和脂肪酸的方法，该方法包括在分离条件下将混合物与包含结晶二氧化硅的分子筛接触，由此选择性地保留饱和脂肪酸。 饱和脂肪酸通过在包含可溶于进料混合物中并具有至少3.5的极性指数的稀释剂的置换流体的置换条件下从分子筛中回收。 无定形二氧化硅是用于分子筛的优选粘合剂。
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公开(公告)号：US4353838A
公开(公告)日：1982-10-12
申请号：US234518
申请日：1981-02-13
CPC分类号： C09F5/10
摘要： A process for separating a monoethanoid fatty acid from a mixture comprising a monoethanoid fatty acid and a diethanoid fatty acid which process comprises contacting the mixture at adsorption conditions with an adsorbent comprising a hydrophobic insoluble cross-linked polystyrene polymer, thereby selectively adsorbing the monoethanoid fatty acid. Preferably the monoethanoid fatty acid will be recovered from the adsorbent by desorption with a desorbent material.
摘要翻译： 从含有单乙醇酸脂肪酸和二乙醇酸脂肪酸的混合物中分离单乙醇酸脂肪酸的方法，该方法包括使吸附条件下的混合物与包含疏水不溶性交联聚苯乙烯聚合物的吸附剂接触，从而选择性吸附单乙醇酸脂肪酸 。 优选地，单乙醇酸脂肪酸将通过用解吸剂材料的解吸从吸附剂中回收。
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公开(公告)号：US4295994A
公开(公告)日：1981-10-20
申请号：US139492
申请日：1980-04-11
申请人： Santi Kulprathipanja
发明人： Santi Kulprathipanja
CPC分类号： C13K13/007 , B01J20/183
摘要： An improved adsorbent comprising a crystalline aluminosilicate, method of manufacture of the adsorbent and improved process for separating a component from a feed mixture comprising an aqueous solution of a mixture of different components, such as a mixture of saccharides. In the process the mixture is contacted with the adsorbent, which selectively adsorbs a component from the feed mixture. The adsorbed component is then recovered by contacting the adsorbent with a desorbent material such as water to effect the desorption of the adsorbed component from the adsorbent. There is an undesirable tendency for the silicon constituent of the crystalline aluminosilicate to dissolve in the aqueous system. The improvement to the adsorbent and process comprises the incorporation of a binder material in the adsorbent comprising cellulose acetate butyrate which substantially reduces the undesirable dissolution. The adsorbent is manufactured by mixing together powder of the crystalline aluminosilicate, powders of the binder, and a liquid organic solvent, extruding the mixture into an extrudate and drying the extrudate.
摘要翻译： 一种改进的吸附剂，包括结晶硅铝酸盐，制造吸附剂的方法和用于从包含不同组分的混合物的水溶液如糖的混合物的进料混合物中分离组分的改进方法。 在该过程中，混合物与吸附剂接触，吸附剂从进料混合物中选择性吸附组分。 然后通过使吸附剂与解吸材料如水接触来回收吸附的组分，以实现吸附组分从吸附剂的解吸附。 结晶硅铝酸盐的硅成分溶解在水性体系中是不希望的。 对吸附剂和方法的改进包括在包含乙酸丁酸纤维素的吸附剂中引入粘合剂材料，其基本上减少了不期望的溶解。 吸附剂通过将结晶硅铝酸盐的粉末，粘合剂的粉末和液体有机溶剂混合在一起来制造，将混合物挤出成挤出物并干燥挤出物。
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公开(公告)号：US08404917B2
公开(公告)日：2013-03-26
申请号：US12392399
申请日：2009-02-25
CPC分类号： C10G25/03 , B01J20/18 , B01J20/186 , B01J2220/42 , C10G2300/104 , C10G2300/1044
摘要： A mixed matrix adsorbent is found for use in the removal of light alkanes from a gasoline stream. The mixed matrix comprises two adsorbents with one adsorbent having an LTA type structure and the other adsorbent having an MFI structure.
摘要翻译： 发现混合基质吸附剂用于从汽油流中除去轻质烷烃。 混合基质包含两个吸附剂，其中一个吸附剂具有LTA型结构，另一个吸附剂具有MFI结构。
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25.发明授权公开(公告)号：US07795483B2
公开(公告)日：2010-09-14
申请号：US10658703
申请日：2003-09-09
申请人： Santi Kulprathipanja , Richard E. Marinangeli , Stephen W. Sohn , Thomas R. Fritsch , R. Joe Lawson
发明人： Santi Kulprathipanja , Richard E. Marinangeli , Stephen W. Sohn , Thomas R. Fritsch , R. Joe Lawson
CPC分类号： C07C7/13
摘要： The present invention is a process for producing phenyl-alkanes by paraffin adsorptive separation followed by paraffin dehydrogenation and then by alkylation of a phenyl compound by a lightly branched olefin. The adsorptive separation step employs a silicalite adsorbent and, as the desorbent, a C5-C8 linear paraffin, a C5-C8 cycloparaffin, a branched paraffin such as isooctane, or mixtures thereof. The effluent of the alkylation zone comprises paraffins that are recycled to the adsorptive separation step or to the dehydrogenation step. This invention is also a process that that sulfonates phenyl-alkanes having lightly branched aliphatic alkyl groups that to produce modified alkylbenzene sulfonates. In addition, this invention is the compositions produced by these processes, which can be used as detergents having improved cleaning effectiveness in hard and/or cold water while also having biodegradability comparable to that of linear alkylbenzene sulfonates, as lubricants, and as lubricant additives. This invention is moreover the use of compositions produced by these processes as lubricants and lubricant additives.
摘要翻译： 本发明是通过链烷烃吸附分离然后进行链烷烃脱氢然后通过轻支化烯烃烷基化苯基化合物来生产苯基烷烃的方法。 吸附分离步骤使用硅沸石吸附剂，并且作为解吸剂，使用C5-C8直链石蜡，C5-C8环烷烃，支链链烷烃如异辛烷，或其混合物。 烷基化区的流出物包括再循环到吸附分离步骤或脱氢步骤的链烷烃。 本发明也是一种方法，即磺酸化具有轻支化脂族烷基的苯基烷烃，以生产改性烷基苯磺酸盐。 此外，本发明是通过这些方法制备的组合物，其可以用作在硬水和/或冷水中具有改善的清洁效果的洗涤剂，同时具有与线性烷基苯磺酸盐，润滑剂和润滑剂添加剂相当的生物降解性。 此外，本发明还将这些方法生产的组合物用作润滑剂和润滑剂添加剂。
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公开(公告)号：US07638060B2
公开(公告)日：2009-12-29
申请号：US11782731
申请日：2007-07-25
IPC分类号： C02F3/00
摘要： An adsorbent for removal of impurities from silicone based solvents is presented. The adsorbent is regenerable for repeated use in cleaning silicone based solvents.
摘要翻译： 提出了一种用于从有机硅类溶剂中除去杂质的吸附剂。 吸附剂可再生，以重复使用以清洁硅酮类溶剂。
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公开(公告)号：US07344585B1
公开(公告)日：2008-03-18
申请号：US11216823
申请日：2005-08-31
IPC分类号： B01D53/22
CPC分类号： B01D53/228 , B01D67/0079 , B01D69/10 , B01D69/141 , B01D69/148 , B01D71/028 , B01D71/16 , B01D71/70 , B01D2257/504 , B01D2257/7022 , B01D2323/20 , Y02C10/10
摘要： An improved mixed matrix membrane for the separation of gases comprises a nitrogen containing compound such as an amine, silicone rubber and activated carbon on a porous support. The membrane may also comprise a carbonate such as potassium carbonate and a plasticizer such as polyethylene glycol. Membranes of this design may be used in processing natural gas or other gases. The gases which may be separated by the membrane include mixtures of methane and carbon dioxide, mixtures of oxygen and nitrogen, and mixtures of carbon dioxide and nitrogen.
摘要翻译： 用于分离气体的改进的混合基质膜包括在多孔载体上的含氮化合物如胺，硅橡胶和活性炭。 膜还可以包含碳酸盐如碳酸钾和增塑剂如聚乙二醇。 该设计的膜可用于加工天然气或其他气体。 可以由膜分离的气体包括甲烷和二氧化碳的混合物，氧和氮的混合物，以及二氧化碳和氮气的混合物。
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公开(公告)号：US20080051619A1
公开(公告)日：2008-02-28
申请号：US11467383
申请日：2006-08-25
IPC分类号： C07C7/12
摘要： This invention is drawn to a process for recovering detergent-range olefins from a feed stream by adsorption. The adsorbent and desorbent are selected to enable olefins with a range of carbon numbers to be recovered simultaneously in light of differing adsorbent retention characteristics.
摘要翻译： 本发明涉及通过吸附从进料流中回收洗涤剂范围的烯烃的方法。 根据不同的吸附剂保留特性，选择吸附剂和解吸剂以使能够同时回收碳数范围的烯烃。
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29.发明授权Separation of citric acid from gluconic acid in fermentation broth using a weakly or strongly basic anionic exchange resin adsorbent 有权使用弱碱性或强碱性阴离子交换树脂吸附剂在发酵液中分离柠檬酸与葡萄糖酸公开(公告)号：US07241918B1
公开(公告)日：2007-07-10
申请号：US10392095
申请日：2003-03-18
申请人： Santi Kulprathipanja
发明人： Santi Kulprathipanja
IPC分类号： C07C51/42 , C07C59/265
CPC分类号： C07C51/47 , C07C59/265
摘要： Citric acid is separated from a fermentation broth containing gluconic acid by using an adsorbent comprising a water-insoluble, macroreticular or gel, strongly or weakly basic anionic exchange resin possessing quaternary or tertiary amine functional groups, said a anionic exchange resin having a cross-linked acrylic or styrene resin matrix and a desorbent comprising water or dilute sulfuric acid. The pH of the feed is maintained below the first ionization constant (pKa1) of citric acid to maintain selectivity.
摘要翻译： 通过使用包含具有季铵或叔胺官能团的不溶于水，大网络或凝胶，强或弱碱性阴离子交换树脂的吸附剂，将柠檬酸与含有葡萄糖酸的发酵液分离，所述阴离子交换树脂具有交联 丙烯酸或苯乙烯树脂基质和包含水或稀硫酸的解吸剂。 饲料的pH值保持在柠檬酸的第一电离常数（pKa 1 H 1/2）以下以保持选择性。
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30.发明授权公开(公告)号：US06617481B1
公开(公告)日：2003-09-09
申请号：US09650886
申请日：2000-08-29
申请人： Santi Kulprathipanja , Richard E. Marinangeli , Stephen W. Sohn , Thomas R. Fritsch , R. Joe Lawson
发明人： Santi Kulprathipanja , Richard E. Marinangeli , Stephen W. Sohn , Thomas R. Fritsch , R. Joe Lawson
IPC分类号： C07C266
CPC分类号： C07C7/13
摘要： The present invention is a process for producing phenyl-alkanes by paraffin adsorptive separation followed by paraffin dehydrogenation and then by alkylation of a phenyl compound by a lightly branched olefin. The adsorptive separation step employs a silicalite adsorbent and, as the desorbent, a C5-C8 linear paraffin, a C5-C8 cycloparaffin, a branched paraffin such as isooctane, or mixtures thereof. The effluent of the alkylation zone comprises paraffins that are recycled to the adsorptive separation step or to the dehydrogenation step. This invention is also a process that sulfonates phenyl-alkanes having lightly branched aliphatic alkyl groups that to produce modified alkylbenzene sulfonates. In addition, this invention is the compositions produced by these processes, which can be used as detergents having improved cleaning effectiveness in hard and/or cold water while also having biodegradability comparable to that of linear alkylbenzene sulfonates, as lubricants, and as lubricant additives. This invention is moreover the use of compositions produced by these processes as lubricants and lubricant additives.
摘要翻译： 本发明是通过链烷烃吸附分离然后进行链烷烃脱氢然后通过轻支化烯烃烷基化苯基化合物来生产苯基烷烃的方法。 吸附分离步骤使用硅沸石吸附剂，并且作为解吸剂，使用C5-C8直链石蜡，C5-C8环烷烃，支链链烷烃如异辛烷，或其混合物。 烷基化区的流出物包括再循环到吸附分离步骤或脱氢步骤的链烷烃。 本发明也是一种使具有轻支化脂族烷基的苯基烷烃磺化以生产改性烷基苯磺酸盐的方法。 此外，本发明是通过这些方法制备的组合物，其可以用作在硬水和/或冷水中具有改善的清洁效果的洗涤剂，同时具有与线性烷基苯磺酸盐，润滑剂和润滑剂添加剂相当的生物降解性。 此外，本发明还将这些方法生产的组合物用作润滑剂和润滑剂添加剂。
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