Trifluoroacetate salts of esteramines as paint additives
    22.
    发明授权
    Trifluoroacetate salts of esteramines as paint additives 失效
    酯胺的三氟乙酸盐作为涂料添加剂

    公开(公告)号:US3413322A

    公开(公告)日:1968-11-26

    申请号:US69230967

    申请日:1967-12-21

    Applicant: DU PONT

    Inventor: VASTA JOSEPH A

    CPC classification number: C09D7/63 C08K5/17 C09D7/47 Y10S516/01

    Abstract: Paint compositions contain compounds, or salts of compounds, of formulae wherein R1 is C1- 12 alkyl, C4- 7 cycloalkyl, or aryl, alkaryl or aralkyl groups (up to C18), one of R2 and R3 is C4- 18 tertiary alkyl and the other is the same or an alkyl, aryl, alkaryl, aralkyl or cycloalkyl group (up to C18). In Example 4, a baking enamel contains a styrene/acrylic acid copolymer (made using (Me3C)2O2 and PhCH2NMe3OH) esterified with the glycidyl ester of a carboxylic acid containing a C8- 10 tertiary alkyl group; petroleum naphtha, butanol and xylene; TiO2; melamine -CH2O resin in BuOH and the CF3CO2H salt of a mixture of compounds of the above formulae in which R1 is lauryl and R2, R3 are each C8- 10 tertiary alkyl.ALSO:In Examples 1 and 2, compounds of formulae are prepared, where R1 is lauryl or cyclohexyl, and R2 and R3 are each C8- 10 tertiary alkyl, by reacting the corresponding glycidyl ester with laurylamine or cyclohexylamine. In Example 3, the CF3CO2H salt of the above compound (R1 = lauryl) is also made.

    Abstract translation: 油漆组合物含有化学式或化合物的盐,式(FORM:1106987 / C3 / 1)其中R1是C1-12烷基,C4-7环烷基或芳基,烷芳基或芳烷基(最高至C18),R2 并且R 3是C 4-18叔烷基,而另一个是相同的或烷基,芳基,烷芳基,芳烷基或环烷基(直至C18)。 在实施例4中,烘焙搪瓷含有与含有C8-10叔烷基的羧酸的缩水甘油酯酯化的苯乙烯/丙烯酸共聚物(使用(Me 3 C)2 O 2和PhCH 2 NMe 3 OH制得) 石脑油,丁醇和二甲苯; TiO2; 其中R 1为月桂基,R 2,R 3为C 8-10叔烷基的上式化合物的混合物中的三聚氰胺-CH 2 O树脂和上式化合物的CF 3 CO 2 H盐。实施例1和2中,式 1106987 / C2 / 1>,其中R1是月桂基或环己基,R2和R3各自为C8-10叔烷基,通过相应的缩水甘油酯与月桂胺或环己胺反应。 在实施例3中,也制备上述化合物的CF 3 CO 2 H盐(R1 =月桂基)。

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