Abstract:
Preparing forming coating liquid for an acid gas separation facilitated transport membrane which includes a hydrophilic compound, an acid gas carrier, and water, coating the forming coating liquid, using a layered film layered in the order of a hydrophilic porous film, a hydrophobic porous film, and an auxiliary support film as a porous support, on a surface of the hydrophilic porous film of the layered film with a liquid film thickness of 0.3 mm to 1.0 mm and drying the coated liquid to form a first acid gas separation facilitated transport membrane, and further coating the forming coating liquid for the acid gas separation facilitated transport membrane on the surface of the hydrophilic porous film with the previously formed acid gas separation facilitated transport membrane and drying the coated liquid to form a next acid gas separation facilitated transport membrane.
Abstract:
A solution is to produce an acid gas separation composite membrane provided with an acid gas separation facilitated membrane on a porous support, including; arranging of a coating liquid for acid gas separation formed through dispersing or dissolving into water a polyvinyl acetal compound formed through crosslinking, by an acetal bond, block copolymers formed through bonding of a polymer block formed of polyvinyl alcohol and a polymer block formed of polyacrylate through a linking group, an acid gas carrier and at least one kind of anion other than hydroxide ion, carboxyl ion, carbonate ion and bicarbonate ion, and coating of the coating liquid for acid gas separation onto a hydrophobic surface of the porous support having hydrophobicity at least on one surface to form the acid gas separation facilitated transport membrane thereon.
Abstract:
A carbon dioxide separation member is disclosed, which includes: a hydrophobic porous membrane that has heat resistance to a temperature of 100° C. or higher; and a polymer compound layer that is formed on a surface of the porous membrane, the polymer compound layer including moisture, and at least one carbon dioxide carrier selected from the group consisting of alkali metal carbonates, alkali metal bicarbonates, and alkali metal hydroxides, and having a cross-linked structure that is formed with a specific single crosslinkable group and includes a specific hydrolysis-resistant bond, wherein the carbon dioxide separation member selectively allows a carbon dioxide gas in a mixture of the carbon dioxide gas and a hydrogen gas to permeate therethrough under temperature conditions of from 100° C. to 250° C.