Abstract:
A photoelectric conversion element including a photoconductor layer, wherein the photoconductor layer contains semiconductor fine particles carrying a metal complex dye of Formula (I); a metal complex dye, a dye solution, a dye-adsorbed electrode, a dye-sensitized solar cell, and a method for producing the solar cell: M(LD)(LA)·(CI) Formula (I) wherein M represents a metal ion; LD represents a tridentate ligand of formulas (DL-1) to (DL-4); LA represents a specific tridentate ligand; and CI represents a counter ion: Y1 and Y2 represent an oxygen, sulfur, nitrogen, or phosphorus atom; AD and BD represent a hydrocarbon or hetero ring; L represents a linking group of formulas (L-1) to (L-4); and Ra and Rb represent a substituent, X represents a nitrogen or carbon atom; CD represents hetero ring; T represents —O—, —S—, —NRL2— or —PRL3; RL1 to RL3 represent a hydrogen atom or a substituent; and Alk represents an alkylene group.
Abstract:
A photoelectric conversion element having a laminate structure including, provided on an electrically conductive support, a photoconductor layer having a layer of dye-adsorbed semiconductor fine particles, a charge transfer layer, and a counter electrode, wherein the dye is a metal complex dye represented by the following formula (1): M1L1L2Z1 (1) wherein, in formula (1), M1 represents a metal atom; Z1 represents a monodentate ligand; L1 represents a specific tridentate ligand; and L2 represents a specific bidentate ligand.