公开(公告)号：US4113864A

公开(公告)日：1978-09-12

申请号：US768875

申请日：1977-02-15

申请人： Hiroshi Tsuchiya ,  Kunio Mukai ,  Akio Kimura ,  Hiroshi Taya ,  Keimei Fujimoto ,  Toshiaki Ozaki ,  Sigeo Yamamoto ,  Taizo Ogawa ,  Tadashi Ooishi ,  Yositosi Okuno

发明人： Hiroshi Tsuchiya ,  Kunio Mukai ,  Akio Kimura ,  Hiroshi Taya ,  Keimei Fujimoto ,  Toshiaki Ozaki ,  Sigeo Yamamoto ,  Taizo Ogawa ,  Tadashi Ooishi ,  Yositosi Okuno

IPC分类号： A01N57/10 ,  A01N57/14 ,  C07F9/18 ,  C07F9/553 ,  A01N9/00 ,  A01N9/36

CPC分类号： C07F9/5537 ,  A01N57/10 ,  A01N57/14 ,  C07F9/18

摘要： Phosphorothiolates represented by the formula, ##STR1## wherein R is an alkyl; A is an alkyl, haloalkyl, alkenyl, alkinyl, alkylthioalkyl, phenylthioalkyl, phthalimidoalkyl or phenylalkyl; X is hydrogen, a halogen or an alkyl; and n is an integer of 1 to 5, are obtained by (1) reacting sodium or potassium hydrosulfide with a compound represented by the formula, ##STR2## WHEREIN R, X and n have the same significances as mentioned above, to prepare a thiophosphate represented by the formula, ##STR3## wherein R, X and n have the same significances as mentioned above; and M is an alkali metal, and then (2) reacting said thiophosphate with a halide represented by the formula,Y -- Awherein A has the same significance as mentioned above; and Y is a halogen.The phosphorothiolates have insecticidal and fungicidal activities.

公开(公告)号：US3987113A

公开(公告)日：1976-10-19

申请号：US586755

申请日：1975-06-13

申请人： Mitsuru Sasaki ,  Katsuji Nodera ,  Kunio Mukai

发明人： Mitsuru Sasaki ,  Katsuji Nodera ,  Kunio Mukai

IPC分类号： C07C205/22 ,  C07C79/26

CPC分类号： C07C201/12 ,  C07C303/06

摘要： A process for preparing 5-methyl-2-nitrophenol from di-m-cresyl carbonate in high yield, by a specific combination of sulfonation, nitration, hydrolysis and steam distillation, is provided.

公开(公告)号：US3956429A

公开(公告)日：1976-05-11

申请号：US486510

申请日：1974-07-08

申请人： Mitsuru Sasaki ,  Kunio Mukai ,  Katsutoshi Tanaka

发明人： Mitsuru Sasaki ,  Kunio Mukai ,  Katsutoshi Tanaka

IPC分类号： C07F9/24 ,  A01N9/36 ,  C07D317/06

CPC分类号： C07F9/247

摘要： A phenylenediamine compound of the formula: ##SPC1##Wherein R.sub.1 is a lower alkyl group or a phenyl group which may bear one to five substituents, R.sub.2 is a lower alkyl group, A is an alkyl group, an alkenyl group, an alkynyl group, a haloalkyl group, a phenyl group, a cyanoalkyl group, a lower alkylthioalkyl group, a haloalkenyl group, a lower alkoxyalkyl group, a lower alkoxycarbonylalkyl group, a lower alkylcarbamoylalkyl group or a phenylalkyl group which may bear one to five substituents on the benzene ring and X is an oxygen atom or a sulfur atom, which is useful as a pesticide effective in preventing and controlling simultaneously two or more kinds of plant diseases and can be produced by reacting an amidophosphoric ester of the formula: ##SPC2##Wherein R.sub.1, A and X are each as defined above with an alkoxycarbonyl isothiocyanate of the formula: ##EQU1## wherein R.sub.2 is as defined above.

摘要翻译： 下式的苯二胺化合物：

公开(公告)号：US3949023A

公开(公告)日：1976-04-06

申请号：US422388

申请日：1973-12-06

申请人： Mitsuru Sasaki ,  Isao Ohno ,  Hisami Takeda ,  Takeo Satomi ,  Kunio Mukai

发明人： Mitsuru Sasaki ,  Isao Ohno ,  Hisami Takeda ,  Takeo Satomi ,  Kunio Mukai

IPC分类号： A01N57/12 ,  A01N57/10 ,  A01N57/14 ,  C07F9/165 ,  C07F9/59 ,  A01N9/36 ,  C07D211/08 ,  C07D317/14

CPC分类号： C07F9/1657 ,  A01N57/10

摘要： Oximino-phosphorothiolate derivatives represented by the formula, ##EQU1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are as hereinafter defined, which are useful as a controlling agent for agricultural pests containing the oximino-phosphorothiolate derivatives as active ingredients, as well as processes for preparing the compounds and the composition are disclosed.

摘要翻译： 由下式表示的肟基 - 硫代磷酸酯衍生物，其中R 1，R 2，R 3和R 4如下文所定义，其可用作含有肟基 - 硫代磷酸酯的农业害虫的控制剂 衍生物作为活性成分，以及制备化合物和组合物的方法。