-
21.发明授权Nitrogen-containing derivatives of carboxymethylcellulose, their synthesis and their use in cosmetic preparations 失效羧甲基纤维素的含氮衍生物，其合成及其在化妆品制剂中的应用
公开(公告)号：US4988806A
公开(公告)日：1991-01-29
申请号：US365612
申请日：1989-06-13
CPC分类号： A61Q5/00 , A61K8/731 , A61Q5/02 , C08B11/14 , C08B11/20 , D21H17/26 , A61K2800/5426 , Y10S514/88
摘要： Derivatives of carboxymethylcellulose are disclosed in which all or a portion of the carboxymethyl groups are replaced by groups of the general formula ##STR1## in which R.sup.1 is a hydrogen or methyl group,R.sup.2 is a divalent aliphatic hydrocarbon group with 2 to 5 carbon atoms,R.sup.3, R.sup.4 are alkyl groups with 1 to 4 carbon atoms,R.sup.5 is an alkyl group with 1 to 4 carbon atoms or a benzyl group,X is a halogen or sulfate group or a sulfonic acid group,with the proviso that, on the average, at least 0.1 quaternary ammonium groups are contained per anhydroglucose unit of the polymeric molecule.The invention furthermore relates to derivatives of carboxymethylcellulose, in which all or a portion of the carboxymethyl groups are replaced by groups of the general formula ##STR2## in which the substituents R.sup.1, R.sup.2, R.sup.3 and R.sup.4 have the above meaning, with the proviso that, on the average, at least 0.1 tertiary amino groups are contained per anhydroglucose unit of the polymeric molecule, as intermediates for the synthesis of the aforementioned derivatives.The invention furthermore is directed to a method for the synthesis of the derivatives of carboxymethylcellulose and their use in cosmetic preparations, especially for the care of hair.
摘要翻译： 公开了羧甲基纤维素的衍生物，其中全部或部分羧甲基被R 1为氢或甲基的通式为“IMAGE”的基团取代，R 2为具有2至5个碳原子的二价脂族烃基， R3，R4是具有1至4个碳原子的烷基，R5是具有1至4个碳原子的烷基或苄基，X是卤素或硫酸根或磺酸基，条件是平均 ，聚合物分子中每个脱水葡萄糖单元含有至少0.1个季铵基团。 本发明还涉及羧甲基纤维素的衍生物，其中全部或部分羧甲基被由通式“IMAGE”的基团取代，其中取代基R 1，R 2，R 3和R 4具有上述含义，条件是 平均来说，作为合成上述衍生物的中间体，聚合物分子中每个脱水葡萄糖单元含有至少0.1个叔氨基。 此外，本发明涉及一种合成羧甲基纤维素衍生物的方法及其在化妆品制剂中的用途，特别是用于护理头发。
-
公开(公告)号：US4687786A
公开(公告)日：1987-08-18
申请号：US833957
申请日：1986-02-27
CPC分类号： C08J9/0061 , C08G77/46 , C08J2375/04 , C08J2483/00
摘要： Process for the preparation of flexible polyurethane foams using polysiloxane-polyoxyalkylene block copolymers as stabilizers having the general formula: ##STR1## in which A represents A.sup.1 and A.sup.2 polyoxyalkylene blocks, as defined hereinafter, which are linked to silicon over carbon and which have the general formula --R.sup.2 --O--(C.sub.x H.sub.2x O--).sub.y R.sup.3, R.sup.2 being a divalent hydrocarbon radical with 2 to 4 carbon atoms and R.sup.3, x and y are as defined hereinafter,B is a methyl radical, the A or R.sup.1 radical,R.sup.1 is an alkyl radical with 1 to 12 carbon atoms, a substituted alkyl radical with 1 to 12 carbon atoms, an aryl or an alkaryl radical,n has a value of 30 to 200,m has a value of 3 to 20 when B is a methyl radical or corresponds to the R.sup.1 radical, and a value of 1 to 18 when B corresponds to the A radical,o has a value of 0 to 40, n being not less than 5 m, and m and o being not greater than 1/3 n,with the proviso that(a) the A.sup.1 blocks consist of 30 to 60 weight percent of oxyethylene units, the remainder being oxypropylene units, the R.sup.3 radical is a hydrogen radical and the average molecular weight of the A.sup.1 Blocks is from 2,500 to 4,500,(b) the A.sup.2 blocks consist of 30 to 80 weight percent of oxyethylene units, the remainder being oxypropylene units, the R.sup.3 radical is an alkyl radical with 1 to 4 carbon atoms or an acyl radical, and the average molecular weight of the A.sup.2 blocks is from 800 to 2,400, and(c) the molar ratio of the A.sup.1 blocks to the A.sup.2 blocks is 20:80 to 60:40, and there is at least one A.sup.1 and one A.sup.2 block in the average molecule.The stabilizers are distinguished by exceptionally high stabilizing properties and, when used in flexible polyurethane foams, surprisingly form open cells in spite of the fact that they contain OH-terminated polyoxyalkylene blocks.
摘要翻译： 使用聚硅氧烷 - 聚氧化烯嵌段共聚物作为稳定剂制备柔性聚氨酯泡沫体的方法，其具有以下通式：其中A表示与下列定义的A1和A2的聚氧化烯嵌段，其与碳相连，并具有一般性 式-R2-O-（CxH2xO-）yR3，R2是具有2至4个碳原子的二价烃基，R3，x和y如下文所定义，B是甲基，A或R1基团，R1是 具有1至12个碳原子的烷基，具有1至12个碳原子的取代烷基，芳基或烷芳基，n具有30至200的值，当B是甲基时，m具有3至20的值 或对应于R1基团，当B对应于A基团时为1〜18，o为0〜40，n为5m以上，m为0以下，1 / n，条件是（a）A1嵌段由30至60重量％的氧化乙烯单元组成， 茚基为氧化丙烯单元，R3基团为氢原子，A1嵌段的平均分子量为2,500至4,500，（b）A2嵌段由30至80重量％的氧化乙烯单元组成，其余为氧化丙烯单元， R3基是碳原子数为1〜4的烷基或酰基，A2嵌段的平均分子量为800〜2400，（c）A1嵌段与A2嵌段的摩尔比为20 ：80〜60:40，平均分子中至少有一个A1和A2嵌段。 稳定剂的特征在于极高的稳定性，并且当用于柔性聚氨酯泡沫时，令人惊奇地形成开孔，尽管它们含有OH封端的聚氧化烯嵌段。
-
23.发明授权Siloxanes with betaine groups, their synthesis and use in hair care products 失效具有甜菜碱基团的硅氧烷，它们在护发产品中的合成和用途
公开(公告)号：US4609750A
公开(公告)日：1986-09-02
申请号：US744469
申请日：1985-06-13
CPC分类号： A61K8/898 , A61Q5/02 , A61Q5/12 , C08G77/388
摘要： Organopolysiloxanes that have betaine groups and the following general formula ##STR1## in which R.sup.1 can represent the same or different groups in the molecule and may be an alkyl radical with 1 to 18 carbon atoms, an aryl radical or a polyoxyalkylene radical with the proviso that at least 70% of the R.sup.1 radicals are methyl radicals,R.sup.2 may be the same as R.sup.1, with the proviso that at least one R.sup.2 radical represents ##STR2## in which R.sup.3 is a divalent alkylene radical with 2 to 12 carbon atoms,R.sup.4 is a divalent alkylene radical with 2 to 6 carbon atoms,R.sup.5 and R.sup.6 are the same or different and represent an alkyl radical with 1 to 4 carbon atoms or a benzyl radical, andn=1, 2, or 3,x has a value of 0 to 200, andy has a value of 1 to 50, as well as processes for their synthesis and their use in cosmetic preparations, especially in hair care products.
摘要翻译： 具有甜菜碱基团的有机聚硅氧烷和以下通式“IMAGE”，其中R 1可以在分子中表示相同或不同的基团，并且可以是具有1至18个碳原子的烷基，芳基或聚氧化烯基，条件是 至少70％的R 1基团是甲基，R 2可以与R 1相同，条件是至少一个R 2基团表示其中R 3是具有2至12个碳原子的二价亚烷基，R 4是 具有2至6个碳原子的二价亚烷基，R 5和R 6相同或不同，表示具有1至4个碳原子的烷基或苄基，n = 1,2或3，x具有 0至200，y值为1至50，以及它们的合成方法及其在化妆品制剂中的用途，特别是在护发产品中。
-
公开(公告)号：US4588755A
公开(公告)日：1986-05-13
申请号：US703736
申请日：1985-02-21
CPC分类号： C08J9/0061 , C08G18/2027 , C08J2375/04 , C08J2483/00
摘要： In a process of the preparation of flexible polyester urethane foams by reacting polyester polyols having at least two hydroxyl groups in the molecule with at least difunctional polyisocyanates in the presence of water, optionally of physical blowing agents, catalysts, stabilizers and optionally of other conventional additives, the following two components are added for catalysis in the form of a mixture to the reaction formulation in the amounts given (which are based on the polyester polyol):(a) 0.2 to 1.5 weight percent of N,N'-dimethylpiperazine,(b) 0.05 to 0.5 weight percent of a polysiloxane-polyoxyalkylene block copolymer of the general formula ##STR1## in which R.sup.1 is a polyoxyalkylene radical of the general formula--(CH.sub.2).sub.3 O(C.sub.m H.sub.2m O).sub.n R.sup.2 in whichR.sup.2 is an alkyl radical with 1 to 4 carbon atoms;m=2 or 3, the average value of m being 2 to 2.5:n=a whole number corresponding to a molecular weight for the R.sup.1 radical of 250 to 1600;a=is a whole number from 3 to 12; andb=is a whole number from 3 to 12.Flexible polyether urethane foams with a high degree of open-cell character are obtained, whose amine odor is clearly reduced.
摘要翻译： 在制备柔性聚酯聚氨酯泡沫的过程中，通过在水存在下使分子中具有至少两个羟基的聚酯多元醇与任选的物理发泡剂，催化剂，稳定剂和任选的其它常规添加剂 加入下列两种成分，以混合物形式的反应制剂形式的催化作用（以聚酯多元醇为基础）：（a）0.2-1.5％（重量）N，N'-二甲基哌嗪（ b）0.05至0.5重量％的通式为“IMAGE”的聚硅氧烷 - 聚氧化烯嵌段共聚物，其中R 1是通式为 - （CH 2）3 O（C m H 2 m O）n R 2的聚氧化烯基，其中R 2为具有1个 至4个碳原子; m = 2或3，m的平均值为2至2.5：n =对应于R1基团的分子量为250至1600的整数; a =从3到12的整数; b =是3〜12的整数。获得具有高开放性能的柔性聚醚聚氨酯泡沫，其明显降低了胺气味。
-
公开(公告)号：US4529743A
公开(公告)日：1985-07-16
申请号：US660497
申请日：1984-10-12
CPC分类号： C08J9/0061 , C08G77/46 , C08J2375/04 , C08J2483/00
摘要： In a process for producing rigid polyurethane foams, polysiloxane-polyoxyalkylene block copolymers having the formula ##STR1## are used, in which A represents polyoxyalkylene blocks A.sup.1 or A.sup.2 having the formula --R.sup.2 --O--(C.sub.m H.sub.2m O).sub.y R.sup.1, which are linked to silicon by an SiC bond and in which R.sup.1 represents a hydrogen atom or an alkyl radical with 1 to 4 carbon atoms, R.sup.2 represents a bridging group, y is a whole number, and m has a value of 2.0 to 2.6, with the proviso that:a. the A.sup.1 blocks comprise 70 to 100 weight percent oxyethylene units, the remainder being oxypropylene units, and have a molecular weight from about 250 to 1,000,b. the A.sup.2 blocks comprise 35 to 65 weight percent oxyethylene units, the remainder being oxypropylene units, and have a molecular weight from about 600 to 1,500,c. the molar ratio of the A.sup.1 block to the A.sup.2 blocks is 85:15 to 15:85 and there is at least one block of A.sup.1 and block of A.sup.2 in the average molecule;B is a methyl radical or an A.sup.1 or A.sup.2 polyoxyalkylene block;a has a value of 15 to 150, andb has a value of 5 to 20, when B is a methyl radical, and a value of 3 to 18, when B represents A.sup.1 or A.sup.2.
摘要翻译： 在制造刚性聚氨酯泡沫体的方法中，使用具有式（I）的聚硅氧烷 - 聚氧化烯嵌段共聚物，其中A表示具有式-R 2 -O-（C m H 2 m O）y R 1的聚氧化烯嵌段A 1或A 2，其与 硅，其中R1表示氢原子或具有1至4个碳原子的烷基，R2表示桥连基团，y表示整数，m表示2.0至2.6的值，条件是 ： 一个。 所述A1嵌段包含70至100重量％的氧化乙烯单元，其余为氧化丙烯单元，分子量为约250至1,000，b。 A2嵌段包含35至65重量％的氧化乙烯单元，其余为氧化丙烯单元，分子量为约600至1500，c。 A1嵌段与A2嵌段的摩尔比为85:15〜15:85，在平均分子中存在至少一个A1嵌段和A2嵌段; B是甲基或A1或A2聚氧化烯嵌段; a的值为15〜150，当B为甲基时，b为5〜20，B为A1或A2时为3〜18。
-
26.发明授权Process for easily degrading waste consisting of the reaction products of organic compounds containing isocyanate groups with alcohols and/or water 失效容易降解含有异氰酸酯基团的有机化合物与醇和/或水的反应产物的废物的方法
公开(公告)号：US4267078A
公开(公告)日：1981-05-12
申请号：US55075
申请日：1979-07-05
申请人： Werner Lidy , Gerd Rossmy , Hans-Joachim Kollmeier
发明人： Werner Lidy , Gerd Rossmy , Hans-Joachim Kollmeier
CPC分类号： C08J11/22 , C08J2375/04 , Y02W30/706
摘要： A method for easily degrading wastes consisting of the reaction products of organic materials containing isocyanate groups and specifically foamed polyurethane wastes by comminuting the waste and reacting it with alkylene oxide at 120.degree. C. to 200.degree. C. and removing the unreacted alkylene oxide. The products obtained are homogeneous liquids which can be added to polyols for reaction with isocyanates to form foamed polyurethanes.
摘要翻译： 通过粉碎废物并使其与环氧烷在120℃至200℃下反应并除去未反应的环氧烷烃，容易地降解由含有异氰酸酯基团的有机材料的反应产物，特别是发泡聚氨酯废物组成的废物的方法。 获得的产物是均匀的液体，其可以加入到多异氰酸酯中以与异氰酸酯反应以形成发泡聚氨酯。
-
-
-
-
-
搜索结果
26 条记录 (耗时 0.019 秒)
