WELLBORE SERVICING FLUID COMPRISING A CELLULOSE ETHER
    3.
    发明申请
    WELLBORE SERVICING FLUID COMPRISING A CELLULOSE ETHER 有权
    井筒维护包含纤维素醚的流体

    公开(公告)号:US20130130949A1

    公开(公告)日:2013-05-23

    申请号:US13811575

    申请日:2011-08-10

    IPC分类号: C08B11/193

    摘要: A cellulose ether having (i) one or more substituents selected from the group consisting of methyl, hydroxyethyl and hydroxypropyl, (ii) one or more hydrophobic substituents, and (iii) one or more cationic, tertiary amino, or anionic substituents, and having a retained dynamic viscosity, % η80/25, of at least 30 percent, wherein % η80/25=[dynamic solution viscosity at 80° C./dynamic solution viscosity at 25° C.]×100, the dynamic solution viscosity at 25° C. and 80° being measured as 1% aqueous solution, is useful for modifying the viscosity of a composition selected from the group consisting of wellbore servicing fluids, cementitious formulations, ceramics, metal working fluids and cutting fluids.

    摘要翻译: 一种纤维素醚,其具有(i)一个或多个选自甲基,羟乙基和羟丙基的取代基,(ii)一个或多个疏水性取代基,和(iii)一个或多个阳离子,叔氨基或阴离子取代基,并具有 保留的动态粘度%eta80 / 25为至少30%,其中%eta80 / 25 = [在80℃下的动态溶液粘度/ 25℃下的动态溶液粘度]×100,25℃时的动态溶液粘度 °C和80°测量为1%水溶液,可用于改变选自井筒维修流体,水泥配方,陶瓷,金属加工液和切削液的组合物的粘度。

    Nitrogen-containing derivatives of carboxymethylcellulose, their
synthesis and their use in cosmetic preparations
    4.
    发明授权
    Nitrogen-containing derivatives of carboxymethylcellulose, their synthesis and their use in cosmetic preparations 失效
    羧甲基纤维素的含氮衍生物,其合成及其在化妆品制剂中的应用

    公开(公告)号:US4988806A

    公开(公告)日:1991-01-29

    申请号:US365612

    申请日:1989-06-13

    摘要: Derivatives of carboxymethylcellulose are disclosed in which all or a portion of the carboxymethyl groups are replaced by groups of the general formula ##STR1## in which R.sup.1 is a hydrogen or methyl group,R.sup.2 is a divalent aliphatic hydrocarbon group with 2 to 5 carbon atoms,R.sup.3, R.sup.4 are alkyl groups with 1 to 4 carbon atoms,R.sup.5 is an alkyl group with 1 to 4 carbon atoms or a benzyl group,X is a halogen or sulfate group or a sulfonic acid group,with the proviso that, on the average, at least 0.1 quaternary ammonium groups are contained per anhydroglucose unit of the polymeric molecule.The invention furthermore relates to derivatives of carboxymethylcellulose, in which all or a portion of the carboxymethyl groups are replaced by groups of the general formula ##STR2## in which the substituents R.sup.1, R.sup.2, R.sup.3 and R.sup.4 have the above meaning, with the proviso that, on the average, at least 0.1 tertiary amino groups are contained per anhydroglucose unit of the polymeric molecule, as intermediates for the synthesis of the aforementioned derivatives.The invention furthermore is directed to a method for the synthesis of the derivatives of carboxymethylcellulose and their use in cosmetic preparations, especially for the care of hair.

    摘要翻译: 公开了羧甲基纤维素的衍生物,其中全部或部分羧甲基被R 1为氢或甲基的通式为“IMAGE”的基团取代,R 2为具有2至5个碳原子的二价脂族烃基, R3,R4是具有1至4个碳原子的烷基,R5是具有1至4个碳原子的烷基或苄基,X是卤素或硫酸根或磺酸基,条件是平均 ,聚合物分子中每个脱水葡萄糖单元含有至少0.1个季铵基团。 本发明还涉及羧甲基纤维素的衍生物,其中全部或部分羧甲基被由通式“IMAGE”的基团取代,其中取代基R 1,R 2,R 3和R 4具有上述含义,条件是 平均来说,作为合成上述衍生物的中间体,聚合物分子中每个脱水葡萄糖单元含有至少0.1个叔氨基。 此外,本发明涉及一种合成羧甲基纤维素衍生物的方法及其在化妆品制剂中的用途,特别是用于护理头发。

    Acetals useful for the preparation of polysaccharide derivatives
    5.
    发明授权
    Acetals useful for the preparation of polysaccharide derivatives 失效
    用于制备多糖衍生物的缩醛

    公开(公告)号:US4983748A

    公开(公告)日:1991-01-08

    申请号:US290934

    申请日:1988-12-28

    摘要: Polysaccharide aldehydes having the formula Sacch--O--CH.sub.2 --CH.dbd.CH--CHO, Saach--O--CH.sub.2 --C.tbd.C--CHO, ##STR1## starch, cellulose, and gum aldehydes, are useful for imparting wet, dry, or temporary wet strength to paper. They are prepared by a non-oxidative method which involves reacting the polysaccharide base, in the presence of alkali, with a derivatizing acetal reagent having the general structure ##STR2## and then hydrolyzing the acetal by adjusting the pH to less than 7, preferably 2-4. In the formulas, n is 1-3; R.sup.11 and R.sup.12 are independently an alkyl, aryl, aralkyl, or alkaryl group when n is 1, R.sup.11 or R.sup.12 is one of the groups when n is 2, or R.sup.11 and R.sup.12 are not present when n is 3; R.sup.13 is an alkyl group, optionally containing an ether linkage, or an aralkyl group; R.sup.14 and R.sup.15 are individually a hydrogen or a methyl group; R.sup.16, R.sup.17, and R.sup.18 are individually an alkyl group; Y.sup.- is an anion; Z is an organic group capable of reacting with the polysaccharide base to form an ether derivative and selected from the group consisting of an epoxide, ethylenically unsaturated group, halohydrin, and halogen; R.sup.19, if present, is a divalent organic group containing no reactive substiuents; and A and A' are lower alkyls or together form at least a 5-membered cyclic acetal.

    摘要翻译: 具有式Sacch-O-CH2-CH = CH-CHO,Saach-O-CH2-C 3BOND C-CHO的多糖醛,图像>< IMAGE>< IMAGE>>淀粉 ,纤维素和醛醛可用于赋予纸张湿,干或临时湿强度。 它们通过非氧化方法制备,其包括在碱存在下使多糖碱与具有一般结构“IMAGE”的衍生化缩醛试剂反应,然后通过将pH调节至小于7,优选2来水解缩醛 -4。 在式中,n为1-3; 当n为1时,R11和R12独立地为烷基,芳基,芳烷基或烷芳基,当n为2时,R11或R12为基团之一,当n为3时,R11和R12不存在; R13是任选含有醚键或芳烷基的烷基; R 14和R 15分别为氢或甲基; R16,R17和R18各自为烷基; Y-是阴离子; Z是能够与多糖基反应形成醚衍生物并选自环氧化物,烯属不饱和基,卤代醇和卤素的有机基团; R19如果存在,是不含反应性残基的二价有机基团; 并且A和A'是低级烷基或一起形成至少5元环缩醛。