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33 条记录 (耗时 0.02 秒)

    Process for selective hydrogenation of unsaturated compounds
    22.
    发明授权
    Process for selective hydrogenation of unsaturated compounds 有权
    不饱和化合物的选择性氢化方法

    公开(公告)号：US06255548B1

    公开(公告)日：2001-07-03

    申请号：US09182659

    申请日：1998-10-30

    申请人： Blaise Didillon ,  Fabienne Le Peltier

    发明人： Blaise Didillon ,  Fabienne Le Peltier

    IPC分类号： C07C503

    CPC分类号： C10G70/02 ,  B01J23/62 ,  B01J23/6567

    摘要： A process for selective hydrogenation of unsaturated compounds such as acetylenic compounds or diolefins is carried out in the presence of a catalyst comprising at least one support, at least one metal from group VIII of the periodic table and at least one additional element M selected from the group formed by germanium, tin, lead, rhenium, gallium, indium, gold, silver and thallium. The process is characterized in that the catalyst is prepared using a process in which said metal M is introduced in an aqueous solvent, in the form of at least one organometallic compound comprising at least one carbon-M bond.

    摘要翻译： 不饱和化合物如炔属化合物或二烯烃的选择性氢化方法是在催化剂存在下进行的，所述催化剂包含至少一种载体，至少一种来自元素周期表第VIII族的金属和至少一种选自 由锗，锡，铅，铼，镓，铟，金，银和铊组成的组。 该方法的特征在于，使用其中所述金属M以包含至少一个碳-M键的至少一种有机金属化合物的形式引入水性溶剂的方法制备催化剂。

    Process for the dehydrogenation of aliphatic hydrocarbons saturated into olefinic hydrocarbons
    23.
    发明授权
    Process for the dehydrogenation of aliphatic hydrocarbons saturated into olefinic hydrocarbons 失效
    饱和到烯烃中的脂肪烃脱氢的方法

    公开(公告)号：US5436383A

    公开(公告)日：1995-07-25

    申请号：US299001

    申请日：1994-08-31

    申请人： Fabienne Le Peltier ,  Sylvie Robert ,  Jean Paul Boitiaux ,  Gerard Leger ,  Jean Pierre Burzynski

    发明人： Fabienne Le Peltier ,  Sylvie Robert ,  Jean Paul Boitiaux ,  Gerard Leger ,  Jean Pierre Burzynski

    IPC分类号： C07C5/32 ,  C07C5/333 ,  C07C5/327

    CPC分类号： C07C5/325 ,  C07C5/3337

    摘要： Process for the dehydrogenation of a charge incorporating saturated aliphatic hydrocarbons essentially having 3 to 5 carbon atoms per molecule, in which the charge, previously heated to the reaction temperature and without premixing with the hydrogen, is introduced at the inlet of at least one reactor, where the dehydrogenation reaction is performed in the presence of a catalyst, preferably incorporating a support having at least one oxide of an element chosen from among the groups IIA, IIB, IIIA, IIIB, IVA and IVB of the periodic classification of elements, at least one noble metal from the platinum family, at least one promotor metal and at least one alkali metal or alkaline earth metal.

    摘要翻译： 每分子基本上具有3至5个碳原子的饱和脂族烃的电荷的脱氢方法，其中预先加热到反应温度并且不与氢预混合的电荷在至少一个反应器的入口处引入， 其中脱氢反应在催化剂存在下进行，优选掺入具有选自元素周期分类的组IIA，IIB，IIIA，IIIB，IVA和IVB中的元素的至少一种氧化物的载体，至少 来自铂族的一种贵金属，至少一种助催化剂金属和至少一种碱金属或碱土金属。

    Supported bimetallic catalyst with a strong interaction between a group VIII metal and tin, and its use in a catalytic reforming process
    27.
    发明授权
    Supported bimetallic catalyst with a strong interaction between a group VIII metal and tin, and its use in a catalytic reforming process 有权
    具有VIII族金属和锡之间强相互作用的负载双金属催化剂及其在催化重整过程中的应用

    公开(公告)号：US06605566B2

    公开(公告)日：2003-08-12

    申请号：US09934656

    申请日：2001-08-23

    申请人： Fabienne Le Peltier ,  Blaise Didillon ,  Jean-Claude Jumas ,  Josette Olivier-Fourcade

    发明人： Fabienne Le Peltier ,  Blaise Didillon ,  Jean-Claude Jumas ,  Josette Olivier-Fourcade

    IPC分类号： B01J2300

    CPC分类号： B01J37/0203 ,  B01J23/626 ,  B01J37/0205 ,  C10G35/09

    摘要： A novel supported bimetallic catalyst comprises a group VIII metal such as platinum, and tin, at least a portion of which interacts strongly with the group VIII metal in the catalyst in the reduced state. In the partially oxidized state, the catalyst of the invention contains at least 10% of tin in the form of a reduced tin species with oxidation state 0, said species having an isomer shift in the range 0.80 to 2.60 mm/s and a quadrupolar splitting in the range 0.65 to 2.00 mm/s. The invention also concerns the preparation of said catalyst, and processes using said catalyst for transforming hydrocarbons into aromatic compounds, such as gasoline reforming processes and aromatic production processes.

    摘要翻译： 一种新型的负载型双金属催化剂包括Ⅷ族金属如铂，和锡，其中至少一部分与还原态催化剂中的Ⅷ族金属强烈相互作用。 在部分氧化状态下，本发明的催化剂含有氧化态为0的还原锡物质形式的至少10％的锡，所述物质具有在0.80至2.60mm / s范围内的异构体移动和四极分裂 在0.65-2.00mm / s的范围内。 本发明还涉及所述催化剂的制备，以及使用所述催化剂将烃转化为芳族化合物的方法，例如汽油重整方法和芳族生产方法。

    Homogeneous bed of catalyst and a process for transforming hydrocarbons into aromatic compounds using said bed
    29.
    发明授权
    Homogeneous bed of catalyst and a process for transforming hydrocarbons into aromatic compounds using said bed 有权
    催化剂的均相床和使用所述床将烃转化为芳族化合物的方法

    公开(公告)号：US06511593B1

    公开(公告)日：2003-01-28

    申请号：US09502797

    申请日：2000-02-11

    申请人： Fabienne Le Peltier ,  Jean-Marie Deves ,  Olivier Clause ,  Frédéric Kolenda ,  Nathalie Brunard

    发明人： Fabienne Le Peltier ,  Jean-Marie Deves ,  Olivier Clause ,  Frédéric Kolenda ,  Nathalie Brunard

    IPC分类号： C10G3506

    CPC分类号： B01J35/002 ,  B01J23/56 ,  B01J23/626 ,  B01J23/6527 ,  B01J23/6567 ,  C10G35/095

    摘要： The invention relates to a homogeneous bed of catalyst particles comprising at least one amorphous matrix, at least one noble metal, at least one additional metal M and at least one halogen, and in which, for a catalyst particle: CPt is the local concentration of noble metal; CM is the local concentration of additional metal M; Cx is the local concentration of halogen; in which catalyst particle bed the local dispersion of the value of CPt/CM or CPt/Cx is termed homogeneous along the diameter of the particle, which corresponds to at least 70% of the values CPt/CM or CPt/Cx deviating by a maximum of 30% from the local average ratio. The invention also relates to a process for transforming hydrocarbons into aromatic compounds with the catalyst, such as a gasoline reforming process and a process for producing aromatic compounds.

    摘要翻译： 本发明涉及包含至少一种无定形基质，至少一种贵金属，至少一种另外的金属M和至少一种卤素的催化剂颗粒的均匀床，其中对于催化剂颗粒：CPt是局部浓度 贵金属; CM是附加金属M的局部浓度; Cx是卤素的局部浓度;其中催化剂颗粒床中，CPt / CM或CPt / Cx值的局部分散体沿粒子的直径称为均匀的， 其对应于CPt / CM或CPt / Cx的值与局部平均比偏差最多为30％的值的至少70％。本发明还涉及用催化剂将烃转化为芳族化合物的方法，例如 汽油重整方法和芳香族化合物的制造方法。

    Homogeneous catalyst bed and process of transforming hydrocarbons into aromatic compounds with the bed
    30.
    发明授权
    Homogeneous catalyst bed and process of transforming hydrocarbons into aromatic compounds with the bed 有权
    均相催化剂床和将烃转化成芳香族化合物的方法

    公开(公告)号：US06451199B1

    公开(公告)日：2002-09-17

    申请号：US09499698

    申请日：2000-02-08

    申请人： Hervé Cauffriez ,  Fabienne Le Peltier ,  Elisabeth Rosenberg

    发明人： Hervé Cauffriez ,  Fabienne Le Peltier ,  Elisabeth Rosenberg

    IPC分类号： C10G35085

    CPC分类号： C10G35/09 ,  B01J23/56 ,  B01J23/62 ,  B01J23/626 ,  B01J23/6527 ,  B01J23/6567 ,  B01J35/0073

    摘要： For transforming hydrocarbons into aromatic compounds, the reaction is conducted on a homogeneous bed of catalyst particles, said catalyst comprising at least one amorphous matrix, at least one noble metal, at least two additional metals M1 and M2 and at least one halogen, and in which, for a catalyst particle, Cpt is the local concentration of platinum; CM1 is the local concentration of additional metal M1; CM2 is the local concentration of additional metal M2; in which the standard deviation of the distribution of the local ratios of the concentrations of the additional metals, CM1/CM2, measured along the particle diameter, is better than 25% relative.

    摘要翻译： 为了将烃转化为芳族化合物，反应在均匀的催化剂颗粒床上进行，所述催化剂包含至少一种无定形基质，至少一种贵金属，至少两种另外的金属M1和M2以及至少一个卤素，以及 对于催化剂颗粒，Cpt是铂的局部浓度; CM1是附加金属M1的局部浓度; CM2是附加金属M2的局部浓度; 其中沿着颗粒直径测量的附加金属浓度CM1 / CM2的局部比率分布的标准偏差优于25％。