公开(公告)号：US5098791A

公开(公告)日：1992-03-24

申请号：US565609

申请日：1990-08-10

Applicant: Kou-Chang Liu ,  Fulvio J. Vara ,  James A. Dougherty

Inventor： Kou-Chang Liu ,  Fulvio J. Vara ,  James A. Dougherty

IPC: C08G59/14 ,  C08G59/62

CPC classification number: C08G59/62 ,  C08G59/1444 ,  Y10T428/31525 ,  Y10T428/31529

Abstract: This invention relates to epoxy vinyl ethers having the formula: ##STR1## wherein R is a polyvalent linear, branched or cyclic hydrocarbon radical having from 2 to 20 carbon atoms, optionally substituted with alkyleneoxy; n has a value of from 1 to 20; p has a value of from 1 to 6; and at least one of Y and Y' is ##STR2## while any remaining Y and Y' can be ##STR3## The invention also relates to the synthesis and uses of the above polyphenyl vinyl ethers.

Abstract translation: 本发明涉及具有下式的环氧乙烯基醚：其中R是具有2至20个碳原子的多价直链，支链或环状烃基，任选被亚烷基氧基取代; n的值为1〜20; p的值为1到6; Y和Y'中的至少一个是“IMAGE”，而任何剩余的Y和Y'可以是“IMAGE”。本发明还涉及上述聚苯基乙烯基醚的合成和用途。

公开(公告)号：US5045572A

公开(公告)日：1991-09-03

申请号：US470487

申请日：1990-01-26

Applicant: Jeffrey S. Plotkin ,  James A. Dougherty ,  Fulvio J. Vara ,  Paul D. Taylor

Inventor： Jeffrey S. Plotkin ,  James A. Dougherty ,  Fulvio J. Vara ,  Paul D. Taylor

IPC: C07F7/04 ,  C08F2/46 ,  C08F8/42 ,  C08G59/40 ,  C08G65/336 ,  C09D4/00

CPC classification number: C08G65/336 ,  C07F7/045 ,  C08F8/42 ,  C08G59/4085 ,  C09D4/00

Abstract: This invention relates to a radiation curable crosslinkable composition containing (a) from about 0.1 to about 5 wt. % of an initiator containing at least 25% cationic initiator, (b) from about 0 to about 60 wt. % of a polymerizable vinyl ether, epoxide, vinyloxy alkyl urethane or acrylate and (c) from about 35 to about 99.9% wt. % of a polyfunctional alkenyl ether having the formulaA[(CH.sub.2 O).sub.m (Z).sub.r CH.dbd.CHR].sub.nwherein A is a carbon atom, --OCH.dbd.CHR or [C.sub.1 to C.sub.10 alkyl].sub.4-n ; R is C.sub.1 to C.sub.6 alkyl; Z is C.sub.2 to C.sub.8 alkyleneoxy; r has a value of from 0 to 6; m has a value of from 0 to 1 and at least one of r and m has a positive value; n has a value of from 1 to 4, with the proviso that m is 0 and n is one when A is --OCH.dbd.CHR, n has a value of 2 or 3 when A is [C.sub.1 to C.sub.10 alkyl].sub.4-n and n has a value of 4 when A is carbon. The invention also relates to the process of curing said composition and to a cured film on a substrate coated with the above composition.

Abstract translation: 本发明涉及可辐射固化的可交联组合物，其包含（a）约0.1至约5wt。 ％的引发剂含有至少25％的阳离子引发剂，（b）约0至约60wt。 ％的可聚合乙烯基醚，环氧化物，乙烯基氧基烷基氨基甲酸酯或丙烯酸酯和（c）约35-约99.9重量％ ％的具有式A [（CH 2 O）m（Z）r CH = CHR] n的多官能烯基醚其中A是碳原子，-OCH = CHR或[C1-C10烷基] 4-n; R为C1至C6烷基; Z为C2〜C8亚烷氧基; r的值为0到6; m具有0至1的值，并且r和m中的至少一个具有正值; n的值为1至4，条件是m为0且当A为-OCH = CHR时n为1，当A为[C 1至C 10烷基] 4-n时，n为2或3的值，n为 当A为碳时，n的值为4。 本发明还涉及在涂覆有上述组合物的基材上固化所述组合物和固化膜的方法。

公开(公告)号：US4954593A

公开(公告)日：1990-09-04

申请号：US395687

申请日：1989-08-18

Applicant: Fulvio J. Vara ,  James A. Dougherty ,  Jeffrey S. Plotkin

Inventor： Fulvio J. Vara ,  James A. Dougherty ,  Jeffrey S. Plotkin

IPC: C08F224/00

CPC classification number: C08F224/00 ,  Y10T428/31855

Abstract: The invention relates to a copolymer having the structure ##STR1## wherein R.sub.3 is lower alkyl or hydrogen; x is an integer having a value of from 100 to 15,000; R.sub.1 is a saturated radical or a radical having a terminal vinyl group and is selected from the group consisting of alkoxylated vinyl; alkoxylated alkanol; alkyl optionally substituted with one or more vinyl ether, alkylate,hydroxy or alkoxylated vinyl groups and phenyl optionally substituted with one or more lower alkyl, hydroxy, alkoxylate or alkoxylated vinyl groups. The invention also relates to the use of said copolymer as a protective coating.

Abstract translation: 本发明涉及一种具有结构“IMAGE”的共聚物，其中R3是低级烷基或氢; x是值为100至15,000的整数; R1是饱和基团或具有末端乙烯基的基团，并且选自烷氧基化乙烯基; 烷氧基化链烷醇 任选被一个或多个乙烯基醚，烷基化物，羟基或烷氧基化乙烯基取代的烷基和任选被一个或多个低级烷基，羟基，烷氧基化或烷氧基化乙烯基取代的苯基。 本发明还涉及所述共聚物作为保护涂层的用途。

公开(公告)号：US5262450A

公开(公告)日：1993-11-16

申请号：US635039

申请日：1990-12-28

Applicant: Fulvio J. Vara ,  James A. Dougherty ,  Geoffrey J. Wilkins

Inventor： Fulvio J. Vara ,  James A. Dougherty ,  Geoffrey J. Wilkins

IPC: C08F2/46 ,  C09D4/00

CPC classification number: C09D4/00

Abstract: A radiation curable composition is provided herein which comprises suitably about 50-90 parts, preferably about 60-80 parts, by weight, of a multifunctional acrylate monomer, suitably with 3-6 acrylate groups, preferably pentaerythritol triacrylate or trimethylolpropane triacrylate, about 10-50 parts by weight, preferably about 20-40 parts, by weight, of a divinyl ether monomer having both a hydrophobic backbone and an abrasion-resistant moiety, which is preferably the divinylether of cyclohexane dimethanol, and a radiation curing initiator, suitably a cationic initiator, and preferably, in combination with a free radical initiator.

Abstract translation: 本文提供了一种可辐射固化的组合物，其包含合适地约50-90份，优选约60-80份重量的多官能丙烯酸酯单体，适宜地具有3-6个丙烯酸酯基，优选季戊四醇三丙烯酸酯或三羟甲基丙烷三丙烯酸酯， 50重量份，优选约20-40重量份具有疏水主链和耐磨损部分的二乙烯基醚单体，其优选为环己烷二甲醇的二乙烯基醚，以及辐射固化引发剂，合适地为阳离子 引发剂，优选与自由基引发剂组合。

公开(公告)号：US5096783A

公开(公告)日：1992-03-17

申请号：US565610

申请日：1990-08-10

Applicant: Kou-Chang Liu ,  Fulvio J. Vara ,  James A. Dougherty

Inventor： Kou-Chang Liu ,  Fulvio J. Vara ,  James A. Dougherty

IPC: C08F290/06 ,  C08G59/14 ,  C08G59/68

CPC classification number: C08G59/1444 ,  C08F290/06 ,  C08G59/68 ,  Y10T428/31525 ,  Y10T428/31529

Abstract: This invention relates to epoxy vinyl ethers having the formula: ##STR1## wherein R is a polyvalent linear, branched or cyclic hydrocarbon radical having from 2 to 20 carbon atoms, optionally substituted with alkyleneoxy; A is branched or linear C.sub.1 to C.sub.4 alkylene; B is halogen or lower alkyl; m has a value of from 0 to 4; n has a value of from 0 to 20; p has a value of from 1 to 5; and Y is ##STR2## when p is one, and is ##STR3## or a mixture of ##STR4## when p is greater than one.

Abstract translation: 本发明涉及具有下式的环氧乙烯基醚：其中R是具有2至20个碳原子的多价直链，支链或环状烃基，任选被亚烷基氧基取代; A是支链或直链的C1至C4亚烷基; B是卤素或低级烷基; m的值为0〜4; n的值为0〜20; p的值为1到5; 而当p为1时，Y为，当p大于1时，则为或的混合。

公开(公告)号：US5055357A

公开(公告)日：1991-10-08

申请号：US670649

申请日：1991-03-18

Applicant: Jeffrey S. Plotkin ,  James A. Dougherty ,  Fulvio J. Vara ,  Paul D. Taylor

Inventor： Jeffrey S. Plotkin ,  James A. Dougherty ,  Fulvio J. Vara ,  Paul D. Taylor

IPC: C07F7/04 ,  C08F2/46 ,  C08F8/42 ,  C08G59/40 ,  C08G65/336 ,  C09D4/00

CPC classification number: C08G65/336 ,  C07F7/045 ,  C08F8/42 ,  C08G59/4085 ,  C09D4/00 ,  Y10T428/31511 ,  Y10T428/31855

Abstract: This invention realtes to a radiation curable cross linkable composition containing (a) from about 0.1 to about 5 wt. % of an initiator containing at least 25% cationic initiator, (b) from about 0 to about 60 wt. % of a polymerizable vinyl ether, expoxide, vinyloxy alkyl urethane or acrylate and (c) from about 35 to about 99.9 wt. % of a polyfunctional alkenyl ether having the formulaA[(CH.sub.2 O).sub.m (Z).sub.r CH.dbd.CHR].sub.nwherein A is a carbon atom, --OCH.dbd.CHR or [C.sub.1 to C.sub.10 alkyl].sub.4-n ; R is C.sub.1 to C.sub.6 alkyl; Z is C.sub.2 to C.sub.8 alkyleneoxy; r has a value of from 0 to 6; m has a value of from 0 to 1 and at least one of r and m has a positive value; n has a value of from 1 to 4, with the proviso that m is 0 and n is one when A is --OCH.dbd.CHR, n has a value of 2 or 3 when A is [C.sub.1 to C.sub.10 alkyl].sub.4-n and n has a value of 4 when A is carbon. The invention also relates to the process of curing said composition and to a cured film on a substrate coated with the above composition.

Abstract translation: 本发明涉及可辐射固化的可交联组合物，其包含（a）约0.1至约5wt。 ％的引发剂含有至少25％的阳离子引发剂，（b）约0至约60wt。 ％的可聚合乙烯基醚，过氧化物，乙烯基氧基烷基氨基甲酸酯或丙烯酸酯和（c）约35-约99.9重量％ ％的具有式A [（CH 2 O）m（Z）r CH = CHR] n的多官能烯基醚其中A是碳原子，-OCH = CHR或[C1-C10烷基] 4-n; R为C1至C6烷基; Z为C2〜C8亚烷氧基; r的值为0到6; m具有0至1的值，并且r和m中的至少一个具有正值; n的值为1至4，条件是m为0且当A为-OCH = CHR时n为1，当A为[C 1至C 10烷基] 4-n时，n为2或3的值，n为 当A为碳时，n的值为4。 本发明还涉及在涂覆有上述组合物的基材上固化所述组合物和固化膜的方法。

公开(公告)号：US4983425A

公开(公告)日：1991-01-08

申请号：US401693

申请日：1989-09-01

Applicant: Fulvio J. Vara ,  James A. Dougherty

Inventor： Fulvio J. Vara ,  James A. Dougherty

IPC: B05D3/04 ,  B27K3/15 ,  C03C17/32 ,  C04B41/48 ,  C04B41/83 ,  C09D4/06

CPC classification number: C04B41/83 ,  B05D3/046 ,  C03C17/32 ,  C04B41/48 ,  C09D4/06

Abstract: This invention relates to a process for hardening a curable normally liquid hydrocarbon compound optionally substituted with an alkyloxy, ester aldehyde, amido, halo, sulfonate, sulfate, sulfite, mercapto or nitro group and containing at least one functional radical selected from the group of ##STR1## and--(X)C.dbd.C(Z)--Y--(CH.sub.2)--wherein Y is --O--, --S-- or --NH-- and X and Z are each independently hydrogen, alkylene having from 1 to 20 carbon atoms, aryl or a mixture thereof, which process comprises contacting said liquid for less than one minute with a hardening amount of a volatilized hard Lewis acid under anhydrous conditions and at a hardening temperature below the deformation temperature of any substrate material which may be used to support said liquid.

Abstract translation: 本发明涉及一种用于固化任选被烷氧基，酯醛，酰胺基，卤代，磺酸根，硫酸根，亚硫酸根，巯基或硝基取代的可固化的常规液体烃化合物的方法，并含有至少一种选自以下的官能团： 和（X）C = C（Z）-Y-（CH 2） - ，其中Y是-O - ， - S-或-NH-，X和Z各自独立地为氢，具有1至20个碳的亚烷基 原子，芳基或其混合物，该方法包括在无水条件下将所述液体与硬化量的挥发的硬路易斯酸接触少于1分钟，并且在低于任何可用于 支持液体。

公开(公告)号：US4980430A

公开(公告)日：1990-12-25

申请号：US481037

申请日：1990-02-16

Applicant: Kou-Chang Liu ,  Fulvio J. Vara ,  James A. Dougherty

Inventor： Kou-Chang Liu ,  Fulvio J. Vara ,  James A. Dougherty

IPC: C08G59/14 ,  C08G59/62

CPC classification number: C08G59/1444 ,  C08G59/62

Abstract: This invention relates to epoxy vinyl ethers having the formula: ##STR1## where R is a polyvalent linear, branched or cyclic hydrocarbon radical having from 2 to 20 carbon atoms, optionally substituted with alkyleneoxy; A is branched or linear C.sub.1 to C.sub.4 alkylene; B is halogen or lower alkyl; m has a value of from 0 to 4; n has a value of from 0 to 20; p has a value of from 1 to 5; and T is ##STR2## when p is one, and is ##STR3## or a mixture of ##STR4## and ##STR5## when p is greater than one.

Abstract translation: 本发明涉及具有下式的环氧乙烯基醚：其中R是具有2至20个碳原子的多价直链，支链或环状烃基，任选被亚烷基氧基取代; A是支链或直链的C1至C4亚烷基; B是卤素或低级烷基; m的值为0〜4; n的值为0〜20; p的值为1到5; 当p为1时，T为，当p大于1时，T为或和的混合。

公开(公告)号：US4908227A

公开(公告)日：1990-03-13

申请号：US237489

申请日：1988-08-29

Applicant: James A. Dougherty ,  Fulvio J. Vara ,  Lowell R. Anderson

Inventor： James A. Dougherty ,  Fulvio J. Vara ,  Lowell R. Anderson

IPC: C07C43/16 ,  C07D303/22 ,  C07D303/24 ,  C08F16/32

CPC classification number: C07D303/22 ,  C07C43/16 ,  C07D303/24 ,  C08F16/32

Abstract: This invention relates to divinyl epoxy ethers having the formula ##STR1## wherein x and x' are integers each having a value of from 0 to 3 and to the preparation and use of the above divinyl epoxy ethers for metal, wood or plastic coatings which possess high resistance to solvents and improved flexibility over saturated epoxy compounds.

Abstract translation: 本发明涉及具有式“IMAGE”的二乙烯基环氧醚，其中x和x'各自具有0至3的整数，以及制备和使用上述二乙烯基环氧醚用于金属，木材或塑料涂料，其具有 高耐溶剂性和饱和环氧化合物的柔韧性提高。

公开(公告)号：US4885319A

公开(公告)日：1989-12-05

申请号：US282527

申请日：1988-12-12

Applicant: James A. Dougherty ,  Fulvio J. Vara

Inventor： James A. Dougherty ,  Fulvio J. Vara

IPC: B05D3/06 ,  B05D7/24 ,  C08F2/50 ,  C08F283/00 ,  C08F283/10 ,  C08F290/06 ,  C08G59/68 ,  C08J7/04 ,  C09D4/00 ,  C09D4/06

CPC classification number: C08J7/047 ,  C08F290/062 ,  C08G59/68 ,  C09D4/00 ,  C08J2323/06 ,  C08J2451/00

Abstract: The invention relates to a blend of divinyl ethers and their use as diluents for irradiation curable resins, which blend comprises between about 65 wt. % and about 35 wt. % of a hydrophobic divinyl ether containing from 6 to 30 carbon atoms and having a Tg of from about 20.degree. C. to about 150.degree. C. and between about 35 wt. % and about 65 wt. % of a hydrophilic polyethylene glycol divinyl ether.

Abstract translation: 本发明涉及二乙烯基醚的混合物及其作为照射固化树脂稀释剂的用途，该共混物包含约65wt。 ％和约35wt。 ％的含有6至30个碳原子并具有约20℃至约150℃的Tg和约35重量％的疏水性二乙烯基醚。 ％和约65wt。 ％的亲水性聚乙二醇二乙烯基醚。