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公开(公告)号：US5358978A
公开(公告)日：1994-10-25
申请号：US13269
申请日：1993-02-03
申请人： Jeffrey S. Plotkin , Fulvio J. Vara , James A. Dougherty , Paul D. Taylor , Kolazi S. Narayanan
发明人： Jeffrey S. Plotkin , Fulvio J. Vara , James A. Dougherty , Paul D. Taylor , Kolazi S. Narayanan
IPC分类号： C07C43/23 , C07C69/96 , C08F2/50 , C08F220/18 , C08F220/26
摘要： This invention relates to alkenyl ether polycarbonates having the formula ##STR1## wherein A is selected from the group consisting of lower alkyl and R'HC.dbd.CHOR--, R and R" are each independently a divalent radical having from 2 to 20 carbon atoms and are selected from the group of alkylene, mono- or poly- alkoxylated alkylene, alkenylene, alkynylene, arylene, alkarylene and aralkylene radicals, which radicals are optionally substituted with halo, alkyl, cyano, nitro or alkoxy; R' is hydrogen or lower alkyl; (n) has a value of from 1 to 10 and (m) has a value of from 0 to 10; with the proviso that R" contains at least 3 carbon atoms when m is zero. The invention also concerns the preparation and use of said alkenyl ether polycarbonates.
摘要翻译： 本发明涉及具有式“IMAGE”的烯基醚聚碳酸酯，其中A选自低级烷基和R'HC = CHOR-，R和R“各自独立地为具有2-20个碳原子的二价基团 选自亚烷基，单 - 或多 - 烷氧基化亚烷基，亚烯基，亚炔基，亚芳基，亚烷芳基和亚芳基，该基团任选被卤素，烷基，氰基，硝基或烷氧基取代; R'是氢或低级烷基; （n）的值为1〜10，（m）为0〜10的数值。 条件是当m为0时，R“至少包含3个碳原子。 本发明还涉及所述烯基醚聚碳酸酯的制备和用途。
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公开(公告)号：US5094917A
公开(公告)日：1992-03-10
申请号：US672249
申请日：1991-03-20
申请人： Fulvio J. Vara , James A. Dougherty , Jeffrey S. Plotkin , Kolazi S. Narayanan , Paul D. Taylor
发明人： Fulvio J. Vara , James A. Dougherty , Jeffrey S. Plotkin , Kolazi S. Narayanan , Paul D. Taylor
CPC分类号： C08G65/336 , C07F7/045 , C08F8/42 , C08G59/4085 , C09D4/00
摘要： Subject invention relates to alk-1-enyl ether silicates having the formula[X].sub.4-n Si[OR.sub.1 OCH.dbd.CH--R.sub.2 ].sub.nwherein X is halogen or --OR wherein R is lower alkyl or a mixture of halogen and OR, a mixture of OR and hydrogen or a mixture of halogen and hydrogen;R.sub.1 contains from 1 to 8 carbon atoms and is alkylene, alkenylene, alkynylene, optionally alkoxylated with up to 20 units of ##STR1## wherein Y is hydrogen or methyl and R.sub.2 is each hydrogen or lower alkyl and n has a value of from 1 to 4. The invention also relates to the process for preparing the above vinyl ether silicates and to their use as chemically resistant coatings.
摘要翻译： 本发明涉及具有式[X] 4-nSi [OR 1 OCH = CH-R 2] n的烷-1-烯基醚硅酸盐，其中X是卤素或-OR，其中R是低级烷基或卤素与OR的混合物， 的OR和氢或卤素和氢的混合物; R1含有1至8个碳原子，并且是亚烷基，亚烯基，亚炔基，任选被至多20个单元的烷氧基化，其中Y是氢或甲基，R 2各自为氢或低级烷基，n的值为1至 本发明还涉及制备上述乙烯基醚硅酸盐的方法及其作为耐化学腐蚀涂料的用途。
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公开(公告)号：US5200437A
公开(公告)日：1993-04-06
申请号：US817218
申请日：1992-01-06
申请人： James A. Dougherty , Fulvio J. Vara , Jeffrey S. Plotkin , Paul D. Taylor , Kolazi S. Narayanan
发明人： James A. Dougherty , Fulvio J. Vara , Jeffrey S. Plotkin , Paul D. Taylor , Kolazi S. Narayanan
IPC分类号： C08F2/46 , C08F214/18 , C09D4/00
CPC分类号： C08F214/188 , C09D4/00
摘要： This invention relates to coating compositions containing the alk-1-enyl ether reaction product of a hydroxylated compound, an alk-1-enyloxy oxirane and from 0 to 95% of an alkyl epoxide.
摘要翻译： 本发明涉及包含羟基化化合物，烷-1-烯氧基环氧乙烷和0至95％烷基环氧化物的烷-1-烯基醚反应产物的涂料组合物。
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4.发明授权Radiation curable cross linkable compositions containing an aliphatic polyfunctional alkenyl ether 失效含有脂肪族多官能烯基醚的可辐射固化交联组合物
公开(公告)号：US5045572A
公开(公告)日：1991-09-03
申请号：US470487
申请日：1990-01-26
CPC分类号： C08G65/336 , C07F7/045 , C08F8/42 , C08G59/4085 , C09D4/00
摘要： This invention relates to a radiation curable crosslinkable composition containing (a) from about 0.1 to about 5 wt. % of an initiator containing at least 25% cationic initiator, (b) from about 0 to about 60 wt. % of a polymerizable vinyl ether, epoxide, vinyloxy alkyl urethane or acrylate and (c) from about 35 to about 99.9% wt. % of a polyfunctional alkenyl ether having the formulaA[(CH.sub.2 O).sub.m (Z).sub.r CH.dbd.CHR].sub.nwherein A is a carbon atom, --OCH.dbd.CHR or [C.sub.1 to C.sub.10 alkyl].sub.4-n ; R is C.sub.1 to C.sub.6 alkyl; Z is C.sub.2 to C.sub.8 alkyleneoxy; r has a value of from 0 to 6; m has a value of from 0 to 1 and at least one of r and m has a positive value; n has a value of from 1 to 4, with the proviso that m is 0 and n is one when A is --OCH.dbd.CHR, n has a value of 2 or 3 when A is [C.sub.1 to C.sub.10 alkyl].sub.4-n and n has a value of 4 when A is carbon. The invention also relates to the process of curing said composition and to a cured film on a substrate coated with the above composition.
摘要翻译： 本发明涉及可辐射固化的可交联组合物，其包含（a）约0.1至约5wt。 ％的引发剂含有至少25％的阳离子引发剂，（b）约0至约60wt。 ％的可聚合乙烯基醚，环氧化物，乙烯基氧基烷基氨基甲酸酯或丙烯酸酯和（c）约35-约99.9重量％ ％的具有式A [（CH 2 O）m（Z）r CH = CHR] n的多官能烯基醚其中A是碳原子，-OCH = CHR或[C1-C10烷基] 4-n; R为C1至C6烷基; Z为C2〜C8亚烷氧基; r的值为0到6; m具有0至1的值，并且r和m中的至少一个具有正值; n的值为1至4，条件是m为0且当A为-OCH = CHR时n为1，当A为[C 1至C 10烷基] 4-n时，n为2或3的值，n为 当A为碳时，n的值为4。 本发明还涉及在涂覆有上述组合物的基材上固化所述组合物和固化膜的方法。
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公开(公告)号：US5055357A
公开(公告)日：1991-10-08
申请号：US670649
申请日：1991-03-18
CPC分类号： C08G65/336 , C07F7/045 , C08F8/42 , C08G59/4085 , C09D4/00 , Y10T428/31511 , Y10T428/31855
摘要： This invention realtes to a radiation curable cross linkable composition containing (a) from about 0.1 to about 5 wt. % of an initiator containing at least 25% cationic initiator, (b) from about 0 to about 60 wt. % of a polymerizable vinyl ether, expoxide, vinyloxy alkyl urethane or acrylate and (c) from about 35 to about 99.9 wt. % of a polyfunctional alkenyl ether having the formulaA[(CH.sub.2 O).sub.m (Z).sub.r CH.dbd.CHR].sub.nwherein A is a carbon atom, --OCH.dbd.CHR or [C.sub.1 to C.sub.10 alkyl].sub.4-n ; R is C.sub.1 to C.sub.6 alkyl; Z is C.sub.2 to C.sub.8 alkyleneoxy; r has a value of from 0 to 6; m has a value of from 0 to 1 and at least one of r and m has a positive value; n has a value of from 1 to 4, with the proviso that m is 0 and n is one when A is --OCH.dbd.CHR, n has a value of 2 or 3 when A is [C.sub.1 to C.sub.10 alkyl].sub.4-n and n has a value of 4 when A is carbon. The invention also relates to the process of curing said composition and to a cured film on a substrate coated with the above composition.
摘要翻译： 本发明涉及可辐射固化的可交联组合物，其包含（a）约0.1至约5wt。 ％的引发剂含有至少25％的阳离子引发剂，（b）约0至约60wt。 ％的可聚合乙烯基醚，过氧化物，乙烯基氧基烷基氨基甲酸酯或丙烯酸酯和（c）约35-约99.9重量％ ％的具有式A [（CH 2 O）m（Z）r CH = CHR] n的多官能烯基醚其中A是碳原子，-OCH = CHR或[C1-C10烷基] 4-n; R为C1至C6烷基; Z为C2〜C8亚烷氧基; r的值为0到6; m具有0至1的值，并且r和m中的至少一个具有正值; n的值为1至4，条件是m为0且当A为-OCH = CHR时n为1，当A为[C 1至C 10烷基] 4-n时，n为2或3的值，n为 当A为碳时，n的值为4。 本发明还涉及在涂覆有上述组合物的基材上固化所述组合物和固化膜的方法。
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公开(公告)号：US5254710A
公开(公告)日：1993-10-19
申请号：US13270
申请日：1993-02-03
申请人： Jeffrey S. Plotkin , Fulvio J. Vara , James A. Dougherty , Paul D. Taylor , Kolazi S. Narayanan
发明人： Jeffrey S. Plotkin , Fulvio J. Vara , James A. Dougherty , Paul D. Taylor , Kolazi S. Narayanan
摘要： This invention relates to alkenyl ether polycarbonates having the formula ##STR1## wherein A is selected from the group consisting of lower alkyl and R'HC.dbd.CHOR--; R and R" are each independently a divalent radical having from 2 to 20 carbon atoms and are selected from the group of alkylene, mono- or poly- alkoxylated alkylene, alkenylene, alkynylene, arylene, alkarylene and aralkylene radicals, which radicals are optionally substituted with halo, alkyl, cyano, nitro or alkoxy; R' is hydrogen or lower alkyl; (n) has a value of from 1 to 10 and (m) has a value of from 0 to 10; with the proviso that R" contains at least 3 carbon atoms when m is zero. The invention also concerns the preparation and use of said alkenyl ether polycarbonates.
摘要翻译： 本发明涉及具有式“IMAGE”的烯基醚聚碳酸酯，其中A选自低级烷基和R'HC = CHOR-; R和R“各自独立地为具有2至20个碳原子的二价基团，并且选自亚烷基，单烷氧基或多烷氧基化亚烷基，亚烯基，亚炔基，亚芳基，亚烷基和亚芳基，该基团任选地 被卤素，烷基，氰基，硝基或烷氧基取代; R'是氢或低级烷基; （n）的值为1〜10，（m）为0〜10的数值。 条件是当m为0时，R“至少包含3个碳原子。 本发明还涉及所述烯基醚聚碳酸酯的制备和用途。
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7.发明授权Alk-1-enyl ether silicates and radiation curable composition containing alk-1-enyl ether silicates 失效烷基-1-烯基醚硅酸盐和含有1-丁烯基醚硅酸盐的可辐射固化组合物
公开(公告)号：US5039716A
公开(公告)日：1991-08-13
申请号：US470489
申请日：1990-01-26
申请人： Fulvio J. Vara , James A. Dougherty , Jeffrey S. Plotkin , Kolazi S. Narayanan , Paul D. Taylor
发明人： Fulvio J. Vara , James A. Dougherty , Jeffrey S. Plotkin , Kolazi S. Narayanan , Paul D. Taylor
CPC分类号： C08G65/336 , C07F7/045 , C08F8/42 , C08G59/4085 , C09D4/00
摘要： Subject invention relates to alk-1-enyl ether silicates having the formula[X].sub.4-n Si[OR.sub.1 OCH.dbd.CH--R.sub.2 ].sub.nwhereinX is halogen or --OR wherein R is lower alkyl or a mixture of halogen and OR, a mixture of OR and hydrogen or a mixture of halogen and hydrogen;R.sub.1 contains from 1 to 8 carbon atoms and is alkylene, alkenylene, alkynylene, optionally alkoxylated with up to 20 units of ##STR1## wherein Y is hydrogen or methyl and R.sub.2 is each hydrogen or lower alkyl and n has a value of from 1 to 4. The invention also relates to the process for preparing the above vinyl ether silicates and to their use as chemically resistant coatings.
摘要翻译： 本发明涉及具有式[X] 4-nSi [OR 1 OCH = CH-R 2] n的烷-1-烯基醚硅酸盐，其中X是卤素或-OR，其中R是低级烷基或卤素与OR的混合物， 的OR和氢或卤素和氢的混合物; R1含有1至8个碳原子，并且是亚烷基，亚烯基，亚炔基，任选被至多20个单元的烷氧基化，其中Y是氢或甲基，R 2各自为氢或低级烷基，n的值为1至 本发明还涉及制备上述乙烯基醚硅酸盐的方法及其作为耐化学腐蚀涂料的用途。
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公开(公告)号：US4954593A
公开(公告)日：1990-09-04
申请号：US395687
申请日：1989-08-18
IPC分类号： C08F224/00
CPC分类号： C08F224/00 , Y10T428/31855
摘要： The invention relates to a copolymer having the structure ##STR1## wherein R.sub.3 is lower alkyl or hydrogen; x is an integer having a value of from 100 to 15,000; R.sub.1 is a saturated radical or a radical having a terminal vinyl group and is selected from the group consisting of alkoxylated vinyl; alkoxylated alkanol; alkyl optionally substituted with one or more vinyl ether, alkylate,hydroxy or alkoxylated vinyl groups and phenyl optionally substituted with one or more lower alkyl, hydroxy, alkoxylate or alkoxylated vinyl groups. The invention also relates to the use of said copolymer as a protective coating.
摘要翻译： 本发明涉及一种具有结构“IMAGE”的共聚物，其中R3是低级烷基或氢; x是值为100至15,000的整数; R1是饱和基团或具有末端乙烯基的基团，并且选自烷氧基化乙烯基; 烷氧基化链烷醇 任选被一个或多个乙烯基醚，烷基化物，羟基或烷氧基化乙烯基取代的烷基和任选被一个或多个低级烷基，羟基，烷氧基化或烷氧基化乙烯基取代的苯基。 本发明还涉及所述共聚物作为保护涂层的用途。
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公开(公告)号：US5262449A
公开(公告)日：1993-11-16
申请号：US936470
申请日：1992-08-28
CPC分类号： C07D317/36 , C09D4/00
摘要： This invention relates to a coating composition which can be cured by exposure to radiation energy in the presence of a cationic photoinitiator. The composition comprises a mixture of between about 1 and about 75 wt. % of a reactive vinyl or alk-1-enyl ether cyclocarbonate having the formula ##STR1## wherein R is hydrogen or lower alkyl; R' is C.sub.2 to C.sub.4 alkylene; n has a value of from 0 to 4 and n' has a value of from 1 to 4 and between about 99 and about 25 wt. % of a polymerizable compound containing an onium salt initiator which is normally insoluble in said polymerizable compound or a mixture thereof. The invention also relates to the use of the composition as a protective coating on a substrate.
摘要翻译： 本发明涉及可在阳离子光引发剂存在下通过暴露于辐射能固化的涂料组合物。 组合物包含约1至约75wt。 ％的具有式“IMAGE”的反应性乙烯基或烷-1-烯基醚环碳酸酯，其中R是氢或低级烷基; R'是C 2至C 4亚烷基; n具有0至4的值，n'具有1至4的值和约99至约25重量％的值。 通常不溶于所述可聚合化合物或其混合物的含有鎓盐引发剂的可聚合化合物的％。 本发明还涉及组合物在基材上作为保护涂层的用途。
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公开(公告)号：US5036112A
公开(公告)日：1991-07-30
申请号：US470488
申请日：1990-01-26
CPC分类号： C09D4/00
摘要： This invention relates to a cross-linkable, cationic radiation curable composition comprising (a) a non-volatile vinyl ether, epoxide, acrylate or an oligomer thereof (b) a cationic photoinitiator and (c) a divinyl ether polyacetal oligomer having the formula ##STR1## wherein n has a value of from 1 to 50;X is uniformly sulfur or oxygen;R is C.sub.2 to C.sub.4 alkeneoxy alkylene, poly(alkyleneoxy) alkylene, or a branched, linear or cyclic C.sub.2 to C.sub.20 alkylene andR' is phenylene, diphenylene methane, diphenylene propane, xylylene, tolylene, or a branched, linear or cyclic C.sub.2 to C.sub.20 alkylene optionally substituted with an ether, ester, carbonate, carbamate, C.sub.2 to C.sub.4 alkyleneoxy alkylene or poly(C.sub.2 to C.sub.4 alkyleneoxy) alkylene radical. The invention also relates to the composition cured on a substrate.
摘要翻译： 本发明涉及可交联的阳离子可辐射固化组合物，其包含（a）非挥发性乙烯基醚，环氧化物，丙烯酸酯或其低聚物（b）阳离子光引发剂和（c）二乙烯基醚聚缩醛低聚物， IMAGE>其中n具有1至50的值; X均匀硫或氧; R为C 2至C 4烯氧基亚烷基，聚（亚烷基氧基）亚烷基或支链，直链或环状的C 2至C 20亚烷基，R'为亚苯基，二亚苯基甲烷，二亚苯基丙烷，亚二甲苯，甲苯或支链， 任选被醚，酯，碳酸酯，氨基甲酸酯，C 2至C 4亚烷氧基亚烷基或聚（C 2至C 4亚烷氧基）亚烷基取代的C 20亚烷基。 本发明还涉及在基材上固化的组合物。
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