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公开(公告)号：US08115039B2
公开(公告)日：2012-02-14
申请号：US11887195
申请日：2006-03-24
IPC分类号： C07C21/00
CPC分类号： C07C17/23 , A61K8/20 , A61Q17/04 , C07C17/10 , C07C17/358 , C07C17/383 , C07C41/16 , C11D1/72 , C11D11/0082 , Y02P20/127 , C07C19/075 , C07C43/04
摘要： A process for making primary haloalkanes by catalytic distillation of internal haloalkanes which comprises a) introducing an internal haloalkane feed into a catalytic distillation column; b) isomerizing at least a portion of the internal haloalkane feed in the presence of an internal haloalkane isomerization catalyst at a temperature at or above the boiling point of the internal haloalkanes and below the temperature and pressure at which hydrogen halide is formed to form primary haloalkanes; and removing the primary haloalkanes from the catalytic distillation column.
摘要翻译： 通过内部卤代烷烃的催化蒸馏制备主要卤代烷烃的方法，其包括：a）将内部卤代烷烃进料引入催化蒸馏塔; b）在内部卤代烷烃异构化催化剂的存在下，在内部卤代烷烃的沸点或高于内部卤代烷的沸点的温度和低于形成卤化氢的温度和压力下形成主要的卤代烷烃，异构化内部卤代烷烃进料的至少一部分 ; 并从催化蒸馏塔中除去主卤代烷烃。
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公开(公告)号：US20110028359A1
公开(公告)日：2011-02-03
申请号：US12866249
申请日：2009-02-06
IPC分类号： C09K8/60
CPC分类号： C09K8/584
摘要： A method of treating a hydrocarbon containing formation, comprising (a) providing a composition to at least a portion of the hydrocarbon containing formation, wherein the composition comprises a derivative selected from the group consisting of a carboxylate or a sulfate or glycerol sulfonate of an ethoxylated/propoxylated primary alcohol having a branched aliphatic group with an average carbon number from 10 to 24 and having an average number of branches per aliphatic group of from 0.7 to 2.5 and having at least 0.5 moles of propylene oxide per mole of primary alcohol and having at least 0.5 moles of ethylene oxide per mole of primary alcohol; and (b) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation.
摘要翻译： 一种处理含烃地层的方法，包括（a）向所述含烃地层的至少一部分提供组合物，其中所述组合物包含选自乙氧基化的羧酸盐或硫酸盐或甘油磺酸盐的衍生物 具有平均碳数为10〜24的支链脂族基团的丙氧基化伯醇，每个脂肪族基团的平均分支数为0.7〜2.5，并且每摩尔伯醇具有至少0.5摩尔环氧丙烷，并具有 每摩尔伯醇至少0.5摩尔环氧乙烷; 和（b）允许组合物与含烃地层中的烃相互作用。
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公开(公告)号：US20110017462A1
公开(公告)日：2011-01-27
申请号：US12866246
申请日：2009-02-06
CPC分类号： C09K8/584
摘要： A method of treating a hydrocarbon containing formation, comprising (a) providing a composition to at least a portion of the hydrocarbon containing formation, wherein the composition comprises a glycerol sulfonate of a propoxylated primary alcohol having a branched aliphatic group with an average carbon number from 10 to 24 and having an average number of branches per aliphatic group of from 0.7 to 2.5 and having at least 0.5 moles of propylene oxide per mole of primary alcohol; and (b) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation.
摘要翻译： 一种处理含烃地层的方法，包括（a）向所述含烃地层的至少一部分提供组合物，其中所述组合物包含具有平均碳数的支链脂族基团的丙氧基化伯醇的甘油磺酸盐， 10至24，并且每个脂族基团的平均支链数为0.7至2.5，并且每摩尔伯醇具有至少0.5摩尔环氧丙烷; 和（b）允许组合物与含烃地层中的烃相互作用。
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公开(公告)号：US20090270655A1
公开(公告)日：2009-10-29
申请号：US11887194
申请日：2006-03-24
IPC分类号： C07C41/01
摘要： A process for converting alkyl halides to alkyl alcohol alkoxylates is described. This is a direct alkoxylation because the alkyl alcohol alkoxylates are made without going through an alkyl alcohol intermediate. The process comprises direct alkoxylation coupling of alkyl halides with a nucleophilic material in the presence of a homogeneous catalyst system to produce alkyl alcohol alkoxylates, wherein the homogeneous catalyst system comprises at least one metal or metal compound which has the ability to form metal-halogen bonds. A process for converting alkanes (paraffins) to alkyl alcohol alkoxylates is also described. This method comprises a) halogenation of at least one alkane to produce at least one alkyl halide; and b) direct alkoxylation coupling of at least a portion of the alkyl halide with a nucleophilic material in the presence of a homogeneous catalyst system to produce alkyl alcohol alkoxylates, wherein the homogeneous catalyst system comprises at least one metal or metal compound which has the ability to form metal-halogen bonds.
摘要翻译： 描述了将烷基卤转化为烷基醇烷氧基化物的方法。 这是直接烷氧基化，因为烷基醇烷氧基化物不经过烷基醇中间体而制备。 该方法包括在均相催化剂体系存在下烷基卤与亲核材料的直接烷氧基化偶合以产生烷基醇烷氧基化物，其中均相催化剂体系包含至少一种具有形成金属 - 卤素键的能力的金属或金属化合物 。 还描述了将烷烃（链烷烃）转化成烷基醇烷氧基化物的方法。 该方法包括a）至少一种烷烃的卤化以产生至少一种烷基卤; 和b）在均相催化剂体系存在下，烷基卤化物与亲核材料的至少一部分直接烷氧基化偶联以产生烷基醇烷氧基化物，其中均相催化剂体系包含至少一种具有能力的金属或金属化合物 以形成金属 - 卤素键。
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公开(公告)号：US20090054274A1
公开(公告)日：2009-02-26
申请号：US11887169
申请日：2006-03-24
摘要： A process by which alkyl halides may be reacted (coupled) with nucleophilic materials in the presence of a homogeneous catalyst system. The process comprises reacting (coupling) alkyl halides with a nucleophilic material in the presence of a homogeneous catalyst system to produce derivatives of alkyl halides, wherein the homogeneous catalyst system comprises at least one metal or metal compound which has the ability to form metal-halogen bonds.
摘要翻译： 在均相催化剂体系存在下，烷基卤化物可与亲核材料反应（偶联）的方法。 该方法包括在均相催化剂体系的存在下使烷基卤与亲核材料反应（偶合）以产生烷基卤化物的衍生物，其中均相催化剂体系包含至少一种具有形成金属卤素的能力的金属或金属化合物 债券。
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