摘要:
An oxygen plasma process for treating a dielectric oxide layer, particularly an anodic oxide, subsequent to its incorporation into an electrolytic capacitor is described. The present treatment reduces DC leakage and improves shelf life stability of the resulting capacitor in comparison to anodic oxides treated in a conventional manner. This is important for critical applications such as implantable cardioverter defibrillators where capacitor charging time and charge/discharge energy efficiency are critical.
摘要:
An electrical energy storage device such as a wet tantalum electrolytic capacitor or an electrochemical cell such as a lithium/silver vanadium oxide cell is described. The enclosure comprises a drawn casing portion having a planar face wall supporting a surrounding sidewall and is shaped to nest the anode, cathode and intermediate separator components. A mating cover is a stamped planar piece of similar material having a periphery edge welded to the edge of the casing portion surrounding sidewall. In order to prevent heat generated during the welding process from damaging the separator, the anode portion adjacent to the weld site is contoured. This provides sufficient space between the weld and the separator supported on the anode at the contour so that what heat is transmitted to the separator by convection and conduction mechanism will not damage the separator.
摘要:
Deposition of a metal-containing reagent solution or suspension onto a conductive substrate by various pad-printing techniques is described. The result in a pseudocapacitive oxide coating, nitride coating, carbon nitride coating, or carbide coating having an acceptable surface area for incorporation into an electrolytic capacitor, such as one have a tantalum anode.
摘要:
An enclosure for an electrical energy storage device such as a wet tantalum electrolytic capacitor or an electrochemical cell such as a lithium/silver vanadium oxide cell is described. The enclosure comprises two metallic casing components or portions. The first is a drawn member having a planar face wall supporting a surrounding sidewall and is shaped to nest the anode, cathode and intermediate separator components. The surrounding sidewall has an annular flange at its outer periphery. A mating cover is a stamped planar piece of similar material whose periphery fits inside the annular flange or rim as a complementary piece.
摘要:
A capacitor working electrolyte containing water and a silicate additive is described. The silicate additive does not alter the electrolyte properties and/or cause any separation of the electrolyte composition. Instead, it stabilizes capacitor long-term performance.
摘要:
An anode for an electrolytic capacitor is described. The anode is of a valve metal in powdered form, for example tantalum powder, that has been pressed into a pellet and sintered under a vacuum at high temperatures. Preferably, a poly(alkylene) carbonate binder is used to promote cohesion with the pressed powder body. The binder adds green strength to the pressed body and helps with powder flow before pressing. The poly(alkylene) carbonate binders are superior in that they leave virtually no residual carbon behind when burnt out during the sintering process. The pressed valve metal powder structure is then anodized to a desired voltage in a formation electrolyte to form a continuous dielectric oxide film on the sintered body as well as a terminal lead/anode lead weld extending therefrom.
摘要:
Deposition of a metal-containing reagent solution or suspension onto a conductive substrate by various pad-printing techniques is described. The result in a pseudocapacitive oxide coating, nitride coating, carbon nitride coating, or carbide coating having an acceptable surface area for incorporation into an electrolytic capacitor, such as one have a tantalum anode.
摘要:
A capacitor comprised of a casing; a cathode comprising an active material of at least an oxide of a first metal provided on a substrate, wherein the active material is characterized as comprising a substantially homogeneous coating formed by sputtering a target comprised of the first metal in a vacuum chamber; an anode spaced from the cathode coating; and an electrolyte in contact with the cathode coating and the anode, the casing containing the anode, the cathode and the electrolyte. A method and apparatus for providing the sputtered coating is also disclosed.
摘要:
An electrolytic capacitor comprising a plurality of polymeric structures molded about the periphery of the anode pellet is described. The polymeric structures contact between a weld strap surrounding the butt seam between mating “clamshell” casing portions and the anode pellet sidewall. That way, the anode pellet is restrained from moving along both an x- and y-axes inside the casing. Having the cathode active material contacting the opposed major casing sidewalls being in a closely spaced relationship with the anode pellet through an intermediate separator prevents movement along the z-axis. The resulting capacitor is particularly well suited for use in high shock and vibration conditions.
摘要:
A method for improving the electrical conductivity of a substrate of metal, metal alloy or metal oxide comprising directing a high energy beam of doping ions from Group VIII onto a substrate. This causes an intermixing of the doping ions with the native oxide of the substrate metal or metal alloy. The native oxide layer is changed from being electrically insulating to electrically conductive. The high-energy beam is an ion beam from a high-energy ion source. The thusly-treated substrate is useable in the manufacture of electrodes for devices such as capacitors and batteries.