Metallized azo dianion with two cationic dye counter ions for optical
information recording medium
    24.
    发明授权
    Metallized azo dianion with two cationic dye counter ions for optical information recording medium 失效
    金属化偶氮二阴离子与两种阳离子染料反离子用于光学信息记录介质

    公开(公告)号:US5426015A

    公开(公告)日:1995-06-20

    申请号:US137331

    申请日:1993-10-18

    摘要: There is disclosed a recordable optical element that includes a recording layer. The element has a transparent substrate and on the surface of the substrate, a) a recording layer containing a light absorbing material and b) a light reflecting layer, the improvement wherein said light absorbing material has the structure: ##STR1## wherein; R is hydrogen, alkyl having from 1 to about 20 carbons, substituted or substituted aryl from about 6 to 10 carbon atoms;R.sub.1 represents hydrogen or an alkyl group of from 1 to about 6 carbon atoms;R.sub.2 represents a hydrogen, an alkyl group of from 1 to about 5 carbon atoms; SO.sub.2 R"' or SO.sub.2 NHR"' where R"' is an alkyl group from 1 to about 10 carbon atoms; an aryl group of from about 6 to 10 carbon atoms or a hetaryl group of from about 5 to about 10 carbon atoms or a halogen atom;R.sub.3 represents hydrogen, an alkyl group of from 1 to about 4 carbon atoms or a halogen atom;R.sub.4 represents alkyl group 1 to 10 carbon atoms; SO.sub.2 R"', SO.sub.2 NHR"' where R"' is an alkyl group from 1 to about 10 carbon atoms; an aryl group of from about 6 to 10 carbon atoms or a hetaryl group of from about 5 to about 10 carbon atoms or a halogen atom;R.sub.5 represents an electron withdrawing group such as NO.sub.2, CN, SO.sub.2 R"", SO.sub.2 NR.sup.V R.sup.VI where R"", R.sup.V or R.sup.VI each independently can represent a hydrogen, an alkyl group of from 1 to about 5 carbon atoms; an aryl group of from about 6 to about 10 carbon atoms; a hetaryl group of from about 5 to about 10 carbon atoms; or a cycloalkyl group of from about 5 to about 7 carbon atoms;R.sub.6 represents hydrogen; an alkyl group of from 1 to about 5 carbon atoms; or a halogen atom;X represents oxygen, sulfur or carboxyl or sulfo groups; andDye.sup.+ can be any dye that has one or more positive charges.

    摘要翻译: 公开了一种包括记录层的可记录光学元件。 该元件具有透明基板,并且在基板的表面上,a)包含光吸收材料的记录层和b)光反射层,其改进在于所述光吸收材料具有以下结构:其中: R为氢,具有1至约20个碳的烷基,取代或取代的碳原子数为6至10个的芳基; R1表示氢或1至约6个碳原子的烷基; R 2表示氢,1至约5个碳原子的烷基; SO 2 R“'或SO 2 NHR”',其中R“是1至约10个碳原子的烷基; 约6至10个碳原子的芳基或约5至约10个碳原子的杂芳基或卤素原子; R3表示氢,1〜约4个碳原子的烷基或卤素原子; R 4表示1〜10个碳原子的烷基; SO 2 R“',SO 2 NHR”',其中R“是1至约10个碳原子的烷基; 约6至10个碳原子的芳基或约5至约10个碳原子的杂芳基或卤素原子; R5表示吸电子基团,例如NO2,CN,SO2R“”,SO2NRVRVI,其中R“',RV或RVI各自独立地表示氢,1至约5个碳原子的烷基; 约6至约10个碳原子的芳基; 约5至约10个碳原子的杂芳基; 或约5至约7个碳原子的环烷基; R6代表氢; 1至约5个碳原子的烷基; 或卤素原子; X表示氧,硫或羧基或磺基; 染料+可以是任何具有一个或多个正电荷的染料。

    Carbamoyloxy substituted couplers in a photothermographic element and
process
    26.
    发明授权
    Carbamoyloxy substituted couplers in a photothermographic element and process 失效
    卡波酰氧基取代的成色剂在光热敏成像元件和工艺中

    公开(公告)号:US4469773A

    公开(公告)日:1984-09-04

    申请号:US504754

    申请日:1983-06-15

    摘要: A coupler containing in the coupling position a carbamoyloxy group ##STR1## upon oxidative coupling, releases a carbamic acid fragment that, in turn, is capable of thermally releasing ammonia or an amine. Such a carbamoyloxy substituted coupler and carbamic acid fragment are useful in imaging such as in photothermography and thermography. Ammonia or an amine released from the carbamic acid fragment enables imaging in imaging materials that are responsive to ammonia or an amine. The carbamoyloxy substituted coupler also generally is a dye-forming coupler that reacts with the oxidized form of a color developing agent to form a dye. An image is produced in an exposed photothermographic material comprising the carbamoyloxy substituted coupler by thermal development. An image is produced in a thermographic material comprising the carbamoyloxy substituted coupler and a color developing agent by imagewise heating the thermographic material.

    摘要翻译: 在偶联位置含有氨基甲酰氧基“IMAGE”的成色剂在氧化偶联时,释放氨基甲酸片段,而氨基甲酸片段又能够热释放氨或胺。 这样的氨基甲酰氧基取代的成色剂和氨基甲酸片段可用于成像,例如光热照相法和热成像法。 从氨基甲酸片段释放的氨或胺使得能够对对氨或胺有响应的成像材料进行成像。 氨基甲酰氧取代的成色剂还通常是与成色染料形成的染料形成成色剂,其与氧化形式的彩色显影剂反应形成染料。 通过热显影在包含氨基甲酰氧基取代的成色剂的暴露的光热敏成像材料中产生图像。 通过成像加热热成像材料,在包含氨基甲酰氧取代的成色剂和彩色显影剂的热成像材料中产生图像。