摘要:
An optical recording element having a transparent substrate and on the surface of said substrate, a recording layer, a light reflecting layer is disclosed. The recording layer comprises (i) a metallized azo ether dye having an azo group linking a substituted 3-hydroxypyridine nucleus to a phenyl nucleus wherein the phenyl nucleus has an ether substituent ortho to the azo group and said phenyl nucleus is free of strong electron withdrawing groups and (ii) a cyanine dye. The recording layer also has, when unrecorded a refractive index, at a selected wavelength from 400 to 660 nm, comprising a real part (n) greater than 1.8 and an imaginary part (k) less than 0.2.
摘要:
An optical recording element having a transparent substrate and on the surface of said substrate, a recording layer and a light reflecting layer. The recording layer comprises (i) a metallized carbamoylazo dye having an azo group linking a substituted 3-hydroxypyridine nucleus to a phenyl nucleus wherein the phenyl nucleus has a carbamoyl substituent ortho to the azo group and (ii) a cyanine dye. The unrecorded recording layer has a refractive index, at a selected wavelength from 400 to 660 nm, comprising a real part (n) greater than 1.8 and an imaginary part (k) less than 0.2.
摘要:
A dye mixture is disclosed. The mixture is useful in recording layers of optical recording elements. The mixture has:a) a real index of refraction of at least 1.8 in the 780 to 790 nm region of the spectra;b) an imaginary index (k) between 0.3 and 0.02 in the 780 to 790 nm region of the spectra;c) a metallized azo dye comprising an azo group linking a substituted 3-hydroxy-pyridine nucleus to a phenyl nucleus wherein the phenyl nucleus has an alkoxy or thioether substituent at its 2-position; andd) at least a second dye.
摘要:
Metallized azo thioether dyes having an azo group linking a substituted 3-hydroxypyridine nucleus to a phenyl nucleus are disclosed. The phenyl nucleus has an thioether substituent ortho to the azo group but does not have electron withdrawing substituents on the phenyl nucleus. The dyes are useful in optical recording elements.
摘要:
Metallized azo ether dyes having an azo group linking a substituted 3-hydroxypyridine nucleus to a phenyl nucleus are disclosed. The phenyl nucleus has an ether substituent ortho to the azo group. The phenyl nucleus is free of strong electron withdrawing substituents. The dyes are useful in optical recording elements.
摘要:
There is disclosed a recordable optical element that includes a recording layer. The element has a transparent substrate and on the surface of the substrate, a) a recording layer containing a light absorbing material and b) a light reflecting layer, the improvement wherein said light absorbing material has the structure: ##STR1## wherein; R is hydrogen, alkyl having from 1 to about 20 carbons, substituted or substituted aryl from about 6 to 10 carbon atoms;R.sub.1 represents hydrogen or an alkyl group of from 1 to about 6 carbon atoms;R.sub.2 represents a hydrogen, an alkyl group of from 1 to about 5 carbon atoms; SO.sub.2 R"' or SO.sub.2 NHR"' where R"' is an alkyl group from 1 to about 10 carbon atoms; an aryl group of from about 6 to 10 carbon atoms or a hetaryl group of from about 5 to about 10 carbon atoms or a halogen atom;R.sub.3 represents hydrogen, an alkyl group of from 1 to about 4 carbon atoms or a halogen atom;R.sub.4 represents alkyl group 1 to 10 carbon atoms; SO.sub.2 R"', SO.sub.2 NHR"' where R"' is an alkyl group from 1 to about 10 carbon atoms; an aryl group of from about 6 to 10 carbon atoms or a hetaryl group of from about 5 to about 10 carbon atoms or a halogen atom;R.sub.5 represents an electron withdrawing group such as NO.sub.2, CN, SO.sub.2 R"", SO.sub.2 NR.sup.V R.sup.VI where R"", R.sup.V or R.sup.VI each independently can represent a hydrogen, an alkyl group of from 1 to about 5 carbon atoms; an aryl group of from about 6 to about 10 carbon atoms; a hetaryl group of from about 5 to about 10 carbon atoms; or a cycloalkyl group of from about 5 to about 7 carbon atoms;R.sub.6 represents hydrogen; an alkyl group of from 1 to about 5 carbon atoms; or a halogen atom;X represents oxygen, sulfur or carboxyl or sulfo groups; andDye.sup.+ can be any dye that has one or more positive charges.
摘要翻译:公开了一种包括记录层的可记录光学元件。 该元件具有透明基板,并且在基板的表面上,a)包含光吸收材料的记录层和b)光反射层,其改进在于所述光吸收材料具有以下结构:其中: R为氢,具有1至约20个碳的烷基,取代或取代的碳原子数为6至10个的芳基; R1表示氢或1至约6个碳原子的烷基; R 2表示氢,1至约5个碳原子的烷基; SO 2 R“'或SO 2 NHR”',其中R“是1至约10个碳原子的烷基; 约6至10个碳原子的芳基或约5至约10个碳原子的杂芳基或卤素原子; R3表示氢,1〜约4个碳原子的烷基或卤素原子; R 4表示1〜10个碳原子的烷基; SO 2 R“',SO 2 NHR”',其中R“是1至约10个碳原子的烷基; 约6至10个碳原子的芳基或约5至约10个碳原子的杂芳基或卤素原子; R5表示吸电子基团,例如NO2,CN,SO2R“”,SO2NRVRVI,其中R“',RV或RVI各自独立地表示氢,1至约5个碳原子的烷基; 约6至约10个碳原子的芳基; 约5至约10个碳原子的杂芳基; 或约5至约7个碳原子的环烷基; R6代表氢; 1至约5个碳原子的烷基; 或卤素原子; X表示氧,硫或羧基或磺基; 染料+可以是任何具有一个或多个正电荷的染料。
摘要:
There is disclosed a recordable optical element that includes a metallized dye. The element has a transparent substrate and on the surface of the substrate, a dye containing recording layer and a light reflecting layer. The improvement is that the dye is a metal complex of a tridentate azo dye ligand containing, on one side of the azo linkage, an aminohydroxypyridine group and on the other side, an aromatic ring including an electron withdrawing substituent. The dyes that are used in the element are very light stable.
摘要:
Metallized carbamoylazo dyes having an azo group linking a substituted 3-hydroxypyridine nucleus to a phenyl nucleus are disclosed. The phenyl nucleus has a carbamoyl substituent ortho to the azo group. The dyes are useful in optical recording elements.
摘要:
An optical recording element having a transparent substrate and on the surface of said substrate, a recording layer and a light reflecting layer. The recording layer comprises a metallized carbamoylazo dye having an azo group linking a substituted 3-hydroxypyridine nucleus to a phenyl nucleus. The phenyl nucleus has a carbamoyl substituent ortho to the azo group. The unrecorded recording layer has a refractive index, at a selected wavelength from 400 to 660 nm, comprising a real part (n) greater than 1.8 and an imaginary part (k) less than 0.2.
摘要:
Disclosed is a dye combination and a thermal dye transfer yellow donor element containing the combination of dyes useful for forming a light stable yellow image comprising a yellow dye having the formula: wherein: R1 and R2 each independently represents an alkyl group of from 1 to 10 carbons atoms or a cycloalkyl group of from 5 to 7 carbon atoms; R3 and R4 each independently represents hydrogen, or an unsubstituted lower alkyl group of 1 to 4 carbon atoms; each Y independently represents halogen, or a lower alkyl or alkoxy group of 1 to 4 carbon atoms; and m is 0 to 4. Such a dye combination and element provide improved color and stability, especially for proofing.
摘要翻译:公开了染料组合和热染料转移黄供体元件,其含有用于形成光稳定黄色图像的染料组合,所述染料组合物包含具有下式的黄色染料:其中:R 1和R 2各自独立地表示烷基 1至10个碳原子的基团或5至7个碳原子的环烷基; R 3和R 4各自独立地表示氢或1至4个碳原子的未取代的低级烷基;每个Y独立地 表示卤素,或1〜4个碳原子的低级烷基或烷氧基; andm为0至4.这种染料组合和元素提供了改善的颜色和稳定性,特别是用于校样。