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公开(公告)号：US5028519A
公开(公告)日：1991-07-02
申请号：US446313
申请日：1989-12-05
申请人： Masakazu Morigaki , Nobuo Seto
发明人： Masakazu Morigaki , Nobuo Seto
CPC分类号： G03C7/39244 , Y10S430/132
摘要： A silver halide color photosensitive material is disclosed. The photosensitive material comprises a support and a photographic layer. According to the present invention, the photographic layer contains a heterocyclic compound. The heterocyclic compound is, for example, represented by the following formula [I]: ##STR1## in which n is 1, 2 or 3; and each of Ra and Rb independently is an acyl group, a sulfonyl group, a sulfinyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, a phosphoryl group, a sulfamoyl group or a carbamoyl group. The other heterocyclic compounds represented by the formulas [II], [III], [IV], [V], and [VI] are also disclosed.
摘要翻译： 公开了一种卤化银色感光材料。 感光材料包括支撑体和照相层。 根据本发明，照相层含有杂环化合物。 杂环化合物例如由下式[I]表示：其中n为1,2或3;其中n为1,2或3; R a和R b各自独立地为酰基，磺酰基，亚磺酰基，烷氧基羰基，芳氧基羰基，磷酰基，氨磺酰基或氨基甲酰基。 还公开了由式[II]，[III]，[IV]，[V]和[VI]表示的其它杂环化合物。
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公开(公告)号：US5004678A
公开(公告)日：1991-04-02
申请号：US375712
申请日：1989-07-05
申请人： Nobuo Seto , Masakazu Morigaki
发明人： Nobuo Seto , Masakazu Morigaki
CPC分类号： G03C7/301 , Y10S430/132
摘要： A silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer, the silver halide color photographic material containing at least one pyrazoloazole type coupler represented by general formula (I) described below and at least one compound represented by general formula (II) described below. ##STR1## wherein R.sub.1 represents a hydrogen atom or a substituent; X represents a hydrogen atom or a group capable of being released upon a coupling reaction with an oxidation product of an aromatic primary amine developing agent; Za, Zb and Zc each represents a methine group, a substituted methine group, .dbd.N-- or --NH--, one of the Za--Zb bond and the Zb--Zc bond being a double bond and the other being a single bond; when the Zb--Zc bond is carbon-carbon double bond, the Zb-Zc bond may be a part of a condensed aromatic ring; R.sub.1 or X may also form a polymer including a dimer or more; and when Za, Zb or Zc is a substituted methine group, the substituted methine group may form a polymer including a dimer or more; ##STR2## wherein R.sub.10 and R.sub.11, which may be the same or different, each represents an aliphatic group or an aromatic group; R.sub.12 and R.sub.13, which may be the same or different, each represents an aliphatic group, an aliphatic oxy group, an aromatic oxy group, and aliphatic thio group, an aromatic thio group, a nitrogen-containing heterocyclic group, an acylamino group, an aliphatic amino group or an aromatic amino group, or R.sub.12 and R.sub.13 may combine with each other to form a 5-membered or 6-membered hetero ring; and the aliphatic group or the aromatic group described above may be substituted.The silver halide color photographic material provides magenta color images having improved fastness to light, and to humidity and heat.
摘要翻译： 一种卤化银彩色照相材料，包括其上具有至少一个卤化银乳剂层的载体，所述卤化银彩色照相材料含有至少一种由下述通式（I）表示的吡唑并唑型偶联剂和至少一种由通式 （II）。 式（I）：其中R 1表示氢原子或取代基; X表示氢原子或与芳族伯胺显影剂的氧化产物偶联反应时能够释放的基团; Za，Zb和Zc各自表示次甲基，取代的次甲基，= N-或-NH-，Za-Zb键和Zb-Zc键之一为双键，另一个为单键; 当Zb-Zc键为碳 - 碳双键时，Zb-Zc键可以是稠合芳环的一部分; R1或X也可以形成包含二聚体或更多的聚合物; 当Za，Zb或Zc是取代的次甲基时，取代的次甲基可以形成包含二聚体或更多的聚合物; 式（II）：其中R10和R11可以相同或不同，各自表示脂族基团或芳族基团; R 12和R 13可以相同或不同，各自表示脂族基团，脂族氧基，芳香族氧基和脂肪族硫基，芳香族硫基，含氮杂环基，酰氨基， 脂族氨基或芳香族氨基，R12和R13可以相互结合形成5元或6元杂环; 并且上述脂族基团或芳族基团可以被取代。 卤化银彩色照相材料提供具有改善的耐光牢度和湿度和热量的洋红色彩色图像。
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公开(公告)号：US4808515A
公开(公告)日：1989-02-28
申请号：US911172
申请日：1986-09-24
申请人： Masakazu Morigaki , Nobuo Seto
发明人： Masakazu Morigaki , Nobuo Seto
CPC分类号： G03C7/39284
摘要： A silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer, the silver halide color photographic material containing at least one pyrazoloazole type coupler represented by the general formula (I) and at least one compound represented by the general formula (II). ##STR1## wherein R.sub.1 represents a hydrogen atom or a substituent; X represents a hydrogen atom or a group capable of being released upon coupling reacti1 Za, Zb and Zc each represents a methine group, a substituted methine grou .dbd.N-- or --NH--, one of the Za--Zb bond and the Zb--Zc bond being a double bond and the other being a single bond; when the Zb--Zc bond is a carbon-carbon double bond, the Zb--Zc bond may be a part of a condensed aromatic ring; R.sub.1 or X may also form a polymer including a dimer or more; and when Za, Zb or Zc is a substituted methine group, the substituted methine group may form a polymer including a dimer or more, with the proviso that when Za and Zb are nitrogen atoms and Zc is a methine group or a substituted methine group, X is not a hydrogen atom, ##STR2## wherein M represents nickel, cobalt, maganese, copper, iron, zinc, palladium or platinum; an R.sub.5 and R.sub.6, each represesnts an alkyl group, aryl group, alkoxy group, alkylthio group, aryloxy group or an arylthio group.The silver halide color photographic material provides magenta color image having improved fastness to light, humidity and heat without accompanying with coloration of white background.
摘要翻译： 一种卤化银彩色照相材料，包括其上具有至少一个卤化银乳剂层的载体，所述卤化银彩色照相材料含有至少一种由通式（I）表示的吡唑并唑型偶联剂和至少一种由通式 （二）。 （I）其中R1表示氢原子或取代基; X表示氢原子或在偶联反应时能够释放的基团Za，Zb和Zc各自表示次甲基，取代的次甲基团= N或-NH-，Za-Zb键和Zb-Zc之一 债券是双重债券，另一个是单一债券; 当Zb-Zc键为碳 - 碳双键时，Zb-Zc键可以是稠合芳环的一部分; R1或X也可以形成包含二聚体或更多的聚合物; 当Za，Zb或Zc为取代的次甲基时，取代的次甲基可以形成包含二聚体以上的聚合物，条件是当Za和Zb为氮原子且Zc为次甲基或取代的次甲基时， X不是氢原子，其中M代表镍，钴，锰，铜，铁，锌，钯或铂; R 5和R 6各自表示烷基，芳基，烷氧基，烷硫基，芳氧基或芳硫基。 卤化银彩色照相材料提供具有改善的耐光性，耐湿性和耐热性的品红色图像，而不伴随着白色背景的着色。
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24.发明授权
公开(公告)号：US4559297A
公开(公告)日：1985-12-17
申请号：US699091
申请日：1985-02-07
CPC分类号： G03C7/39288 , C07F7/0812 , C07F7/0818
摘要： A silver halide photographic light-sensitive material is described, the material comprising a support having thereon at least one photographic layer containing at least one compound represented by formula (I): ##STR1## wherein R represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted heterocyclic group, ##STR2## a substituted or unsubstituted silyl group, a substituted or unsubstituted phosphoric acid group, or a divalent group derived from the above-described groups which forms a ring together with the oxygen atom linking to --R and the carbon atom which is in the ortho-position to --O--R and to which ##STR3## is not bonded; R.sub.1, R.sub.2 and R.sub.3 which may be the same or different each represents a hydrogen atom, an alkyl group, an alkenyl group, a cycloalkyl group, an aralkyl group, an aryl group or a substituent thereof; Q represents an atomic group necessary to form a substituted or unsubstituted aromatic ring; R.sub.4 represents a hydrogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, an aryl group, an alkoxy group, an aryloxy group, an amino group, a cycloamino group, an alkylthio group, an arylthio group, an acyl group, an alkoxycarbonyl group or a substituent thereof; and R.sub.5 represents an H atom, an alkyl group, a cycloalkyl group, an alkenyl group, an aryl group or a substituent thereof.
摘要翻译： 描述了一种卤化银照相感光材料，该材料包括其上具有至少一个含有至少一种由式（I）表示的化合物的照相层的载体：其中R表示氢原子，取代的 或未取代的烷基，取代或未取代的烯基，取代或未取代的环烷基，取代或未取代的芳基，取代或未取代的杂环基，取代或未取代的甲硅烷基，取代或未取代的磷酸基 或衍生自上述基团的二价基团，其与连接到-R的氧原子和与-OR邻位并且未键合的碳原子一起形成环; 可以相同或不同的R 1，R 2和R 3表示氢原子，烷基，烯基，环烷基，芳烷基，芳基或其取代基; Q表示形成取代或未取代的芳环所必需的原子团; R4表示氢原子，烷基，环烷基，烯基，芳基，烷氧基，芳氧基，氨基，环氨基，烷硫基，芳硫基，酰基， 烷氧基羰基或其取代基; R5代表H原子，烷基，环烷基，烯基，芳基或取代基。
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公开(公告)号：US5352573A
公开(公告)日：1994-10-04
申请号：US982439
申请日：1992-11-27
CPC分类号： G03C7/301
摘要： A silver halide color photographic light-sensitive material having an improved color forming property, color reproducibility and image preservative performance is described. The light-sensitive material comprises a support having provided thereon at least one silver halide emulsion layer comprising (a) a cyan dye-forming coupler represented by the following formulas (I) or (II): ##STR1## wherein Za, Zb, R.sub.1, R.sub.2 and X represent substituents described herein; (b) a compound represented by the following formula (A): ##STR2## wherein R.sub.a1 -R.sub.a6 represent substituents described herein.
摘要翻译： 描述了具有改进的成色性，颜色再现性和图像保存性能的卤化银彩色照相感光材料。 感光材料包括其上设置有至少一个卤化银乳剂层的载体，其包含（a）由下式（I）或（II）表示的形成青色染料的成色剂： （II）其中Za，Zb，R1，R2和X表示本文所述的取代基; （b）由下式（A）表示的化合物：其中Ra1-Ra6表示本文所述的取代基。
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公开(公告)号：US5300419A
公开(公告)日：1994-04-05
申请号：US888858
申请日：1992-05-27
申请人： Nobuo Seto , Hiroyuki Yoneyama , Masakazu Morigaki , Hidekazu Sakai , Hidetoshi Kobayashi , Shigeru Yamazaki
发明人： Nobuo Seto , Hiroyuki Yoneyama , Masakazu Morigaki , Hidekazu Sakai , Hidetoshi Kobayashi , Shigeru Yamazaki
CPC分类号： G03C7/3006
摘要： Disclosed is a silver halide color photographic material containing at least one cyan dye forming coupler of the following general formula (C-1) and at least one compound of the following general formula (I) in the same layer of the material: ##STR1## where R.sub.0 represents an alkyl group, an alkenyl group, an aryl group, or a heterocyclic group;X represents a hydrogen atom, or a group capable of being split off by a coupling reaction with the oxidation product of an aromatic primary amine color developing agent; andAr represents an aromatic group; ##STR2## where R.sub.1, R.sub.2 and R.sub.3 each represent an aliphatic group, an aryl group, or a heterocyclic group;R.sub.4 represents a hydrogen atom, an aliphatic group, an aryl group, or a heterocyclic group;R.sub.1 and R.sub.2, or R.sub.3 and R.sub.4 may be bonded to each other to form a 5-membered to 8-membered ring along with the nitrogen atom in the formula;the compound of formula (I) may form a dimer or a higher polymer at the position of R.sub.1, R.sub.2, R.sub.3 or R.sub.4 ;provided that R.sub.1 and R.sub.3, or R.sub.2 and R.sub.4 are not bonded to each other to form a ring, and that the sum of the carbon atoms of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 is 6 or more.
摘要翻译： 公开了在同一层材料中含有至少一种以下通式（C-1）的青色染料形成成色剂和至少一种以下通式（I）的化合物的卤化银彩色照相材料：（* CHEMICAL 结构*）（C-1）其中R 0表示烷基，烯基，芳基或杂环基; X表示氢原子或能够通过与芳族伯胺显色剂的氧化产物的偶联反应而分裂的基团; Ar表示芳香族基团。 （*化学结构*）（I）其中R 1，R 2和R 3各自表示脂族基，芳基或杂环基; R4表示氢原子，脂族基，芳基或杂环基; R 1和R 2，或者R 3和R 4可以彼此键合以与式中的氮原子一起形成5元至8元环; 式（I）化合物可以在R 1，R 2，R 3或R 4的位置上形成二聚体或更高级的聚合物; 条件是R1和R3或R2和R4彼此不结合形成环，并且R 1，R 2，R 3和R 4的碳原子之和为6以上。
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27.发明授权Silver halide color photographic materials containing image stabilizer and anti-staining agent and color photographs containing the same 失效含有图像稳定剂和防污染剂的卤化银彩色照相材料和含有相同的彩色照片
公开(公告)号：US5212055A
公开(公告)日：1993-05-18
申请号：US553839
申请日：1990-07-18
申请人： Masakazu Morigaki , Nobuo Seto , Kozo Aoki
发明人： Masakazu Morigaki , Nobuo Seto , Kozo Aoki
摘要： A silver halide color photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer comprising a dispersion of silver halide grains in a binder, wherein the silver halide emulsion layer contains (a) at least one coupler represented by formula (I), (b) at least one compound represented by the formula (II), and (c) at least one compound represented by formula (III), and the photographic material contains (d) at least one compound represented by formulae (IV), (V) or (VI): ##STR1## wherein R, Y, Za, Zb and Zc each is as defined in the specification; ##STR2## wherein R.sub.1, R.sub.2, R.sub.5 and R.sub.6, and R.sub.7 each is as defined in the specification ##STR3## wherein R.sub.11, R.sub.12 and R.sub.13, R.sub.14, R.sub.15, R.sub.16 and R.sub.17 each is as defined in the specification; ##STR4## wherein R.sub.21, R.sub.22 A, B, X, Y.sub.1 and n each is as defined in the specification; andR.sub.30 --Z (VI)R.sub.30 and Z is as defined in the specification; and a photograph containing (i) a magenta dye derived from the magenta coupler represented by formula (I), (ii) a compound represented by formula (II), a compound represented by formula (III), and at least one compound represented by formula (IV), (V) or (VI).
摘要翻译： 一种卤化银彩色照相材料，其包含其上具有至少一个感光卤化银乳剂层的载体，所述感光卤化银乳剂层包括在粘合剂中的卤化银颗粒分散体，其中所述卤化银乳剂层含有（a）至少一种由式 I），（b）至少一种由式（II）表示的化合物和（c）至少一种由式（III）表示的化合物，并且照相材料含有（d）至少一种由式（IV）表示的化合物 ），（V）或（VI）：其中R，Y，Za，Zb和Zc各自如说明书中所定义; （II）其中R 1，R 2，R 5和R 6以及R 7各自如说明书中所定义，其中R 11，R 12和R 13，R 14，R 15，R 16和R 17各自如 规范; （IV）其中R21，R22A，B，X，Y1和n各自如说明书中所定义; 和R30-Z（VI）R30和Z如说明书中所定义; 和（i）由式（I）表示的品红色成色剂衍生的品红色染料的染色照片，（ii）由式（II）表示的化合物，式（III）表示的化合物和至少一种由 式（IV），（V）或（VI）。
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28.发明授权
公开(公告)号：US5139931A
公开(公告)日：1992-08-18
申请号：US540970
申请日：1990-06-20
申请人： Nobuo Seto , Masakazu Morigaki
发明人： Nobuo Seto , Masakazu Morigaki
CPC分类号： G03C7/301
摘要： A silver halide color photographic material is disclosed having at least one coupler of the following formula (I), at least one compound of the following formula (II), and at least one compound of the following formula (III) in the same layer: ##STR1## wherein the substituent groups are as defined in the specification. The material resists fogging and forms a color image having excellent light-fastness.
摘要翻译： 公开了卤化银彩色照相材料，其具有至少一种下式（I）的成色剂，至少一种下式（II）的化合物和至少一种下式（III）的化合物在同一层中： （Ⅰ）
（II） （III）其中取代基如说明书中所定义。 该材料抵抗雾化，并形成具有优异耐光性的彩色图像。 -
公开(公告)号：US5108876A
公开(公告)日：1992-04-28
申请号：US489641
申请日：1990-03-07
申请人： Masakazu Morigaki , Nobuo Seto , Osamu Takahashi , Hideaki Naruse
发明人： Masakazu Morigaki , Nobuo Seto , Osamu Takahashi , Hideaki Naruse
IPC分类号： G03C7/26 , C07D263/56 , G03C7/30 , G03C7/392
CPC分类号： G03C7/39236
摘要： A color photograph comprising a support having provided thereon at least one photographic layer, wherein said at least one photographic layer contains a storage stability improving compound which forms a chemically inert and substantially colorless compound by combining chemically with the oxidation product of an aromatic amine color developing agent remaining in said color photograph after color development processing.
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公开(公告)号：US4491630A
公开(公告)日：1985-01-01
申请号：US460512
申请日：1983-01-24
CPC分类号： G03C7/39252 , G03C7/384
摘要： A silver halide color photographic light-sensitive material comprising a support having thereon a silver halide emulsion layer containing at least one kind of compound represented by the following general formula (I): ##STR1## wherein each substituent represented by R.sub.1, R.sub.2, R.sub.3, X, or Ar and m are defined within the specification, said silver halide color photographic light-sensitive material comprises a compound represented by the following general formula (II) in the silver halide emulsion layer containing the compound represented by the above general formula (I) and/or a hydrophilic colloid layer which is positioned at the remoter side than the silver halide emulsion layer from the support: ##STR2## wherein each substituent represented by Y, R.sub.4, R.sub.5, R.sub.6, R.sub.7 or Ar is defined within the specification.The silver halide color photographic light-sensitive material can provide a magenta color image having excellent photographic properties without the occurrence of stain, even when the color photographic material is processed in a processing solution under the running condition.A method of forming a color image using the silver halide color photographic light-sensitive material is also disclosed.
摘要翻译： 一种卤化银彩色照相感光材料，其包含其上具有卤化银乳剂层的载体，所述卤化银乳剂层含有由以下通式（I）表示的至少一种化合物：其中每个由R 1，R 2表示的取代基 所述卤化银彩色照相感光材料包含由以上通式表示的化合物的卤化银乳剂层中的由以下通式（II）表示的化合物：其中，R 3，X或Ar和m定义在本说明书中， 式（I）和/或位于距离载体的卤化银乳剂层更远侧的亲水胶体层：其中由Y，R4，R5，R6，R7或Ar表示的每个取代基 在规范内定义。 卤化银彩色摄影感光材料即使当在运行状态下在处理溶液中处理彩色照相材料时，也可以提供具有优异的照相性能的品红色图像，而不会发生污渍。 还公开了使用卤化银彩色照相感光材料形成彩色图像的方法。
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