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26 条记录 (耗时 0.023 秒)

    Preparation of hydrogenated product of cyclic olefin ring-opening metathesis polymer
    21.
    发明授权
    Preparation of hydrogenated product of cyclic olefin ring-opening metathesis polymer 失效
    环烯烃开环复分解聚合物氢化产物的制备

    公开(公告)号：US06197894B1

    公开(公告)日：2001-03-06

    申请号：US09084593

    申请日：1998-05-27

    申请人： Tadahiro Sunaga ,  Masumi Okita ,  Tadashi Asanuma

    发明人： Tadahiro Sunaga ,  Masumi Okita ,  Tadashi Asanuma

    IPC分类号： C08F804

    CPC分类号： C08G61/08

    摘要： An olefin ring-opening metathesis polymer is hydrogenated to obtain a hydrogenated product thereof in high yield. A specialized olefin ring-opening metathesis polymer is hydrogenated in the presence of hydrogen using a catalyst consisting of an amine compound and a metallic complex of an organic phosphorous compound represented by the general formula (1): MHkQmTpZq  (1) wherein k is an integer of 0 or 1, m is an integer of 1 to 3, p is an integer of 0 or 1, q is an integer of 2 to 4, M is ruthenium, rhodium, osmium, iridium, palladium, platinum or nickel atom, H is hydrogen atom, Q is a halogen atom, T is CO, NO, toluene, acetonitrile or tetrahydrofuran, Z is an organic phosphorous compound represented by the general formula (2): PR′1R′2R′3  (2) wherein P is phosphorous atom, R′1, R′2 and R′3 may be the same or different from each other and are individually selected from the group consisting of a linear, branched or cyclic alkyl group, a linear, branched or cyclic alkenyl group, a linear, branched or cyclic aryl group, a linear, branched or cyclic alkoxy group and a linear, branched or cyclic aryloxy group.

    摘要翻译： 将烯烃开环易位聚合物氢化得到其高产率的氢化产物。 使用由胺化合物和由通式（1）表示的有机磷化合物的金属络合物组成的催化剂在氢存在下氢化特定的烯烃开环易位聚合物：其中k为0或1的整数 m为1〜3的整数，p为0或1的整数，q为2〜4的整数，M为钌，铑，锇，铱，钯，铂或镍原子，H为氢原子， Q是卤原子，T是CO，NO，甲苯，乙腈或四氢呋喃，Z是由通式（2）表示的有机磷化合物：其中P是磷原子，R'1，R'2和R'3 可以相同或不同，并且分别选自直链，支链或环状烷基，直链，支链或环状烯基，直链，支链或环状芳基，直链，支链或环状 环状烷氧基和直链，支链或环状芳氧基。

    OPTICAL MATERIAL AND MOLDED PRODUCT THEREOF
    22.
    发明申请
    OPTICAL MATERIAL AND MOLDED PRODUCT THEREOF 有权
    光学材料及其模制产品

    公开(公告)号：US20130030136A1

    公开(公告)日：2013-01-31

    申请号：US13639124

    申请日：2011-04-04

    申请人： Tadahiro Sunaga ,  Takashi Oda ,  Hirofumi Io ,  Keisuke Kawashima ,  Yasuhiro Koike

    发明人： Tadahiro Sunaga ,  Takashi Oda ,  Hirofumi Io ,  Keisuke Kawashima ,  Yasuhiro Koike

    IPC分类号： C08F232/08

    CPC分类号： G02B1/04 ,  C08G2261/3324 ,  C08G2261/3325 ,  C08G2261/418 ,  C08G2261/724 ,  C08L23/18

    摘要： Disclosed is an optical material including a cyclic olefin copolymer containing at least a repeating structural unit [A] represented by the general formula (1) and a repeating structural unit [B] represented by the general formula (2) and having a molar ratio [A]/[B] of from 95/5 to 1/99, wherein the absolute value of the ratio ΔOB/ΔF is from 0.001 to 0.250 in which ΔOB represents the amount of a change in the absolute value of the orientation birefringence calculated from the phase difference (nm) at a wavelength of 633 nm/film thickness (μm) in a stretched film obtained from the optical material, and ΔF represents the amount of a change in the absolute value of the orientation coefficient determined from the dichroic ratio of parallel light intensity I∥ to perpendicular light intensity I⊥, each relative to the orientation direction according to Raman spectroscopy.

    摘要翻译： 公开了一种光学材料，其包括至少含有由通式（1）表示的重复结构单元[A]和由通式（2）表示的重复结构单元[B]并具有摩尔比[ A] / [B]为95/5〜1/99，其中，比率＆Dgr; OB /＆Dgr; F的绝对值为0.001〜0.250，其中Dgr; OB表示绝对值的变化量 由从光学材料获得的拉伸膜中的波长633nm /膜厚度（μm）的相位差（nm）计算出的取向双折射，＆Dgr; F表示从光学材料获得的拉伸膜中的 取向系数由平行光强度I∥的二向色度与垂直光强度I⊥确定，各自相对于根据拉曼光谱的取向方向。

    Metallocene compound, and process for preparing polyolefin by using it
    26.
    发明授权
    Metallocene compound, and process for preparing polyolefin by using it 有权
    茂金属化合物，以及使用它制备聚烯烃的方法

    公开(公告)号：US06342568B1

    公开(公告)日：2002-01-29

    申请号：US09300289

    申请日：1999-04-27

    申请人： Tadahiro Sunaga ,  Kenji Michiue ,  Masahiro Yamashita ,  Yukio Ishii

    发明人： Tadahiro Sunaga ,  Kenji Michiue ,  Masahiro Yamashita ,  Yukio Ishii

    IPC分类号： C08F444

    CPC分类号： C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/00 ,  C08F110/06 ,  Y10S526/943 ,  C08F4/65927 ,  C08F2500/16

    摘要： There are herein disclosed a novel metallocene compound represented by the formula [1] and a process for preparing a polyolefin comprising the step of polymerizing an olefin in a catalytic system including the metallocene compound. The metallocene compound of the present invention particularly permits the preparation of a polyolefin having a high stereoregularity and a low molecular weight, and it is industrially extremely valuable: wherein R1 and R2 are each selected from the group consisting of an alkyl group, an aryl group and a silicon-containing alkyl group; M is a metal selected from the group IV of the periodic table; Q is carbon or silicon; X is a halogen, an alkyl group or an anionic ligand, and they may be selected so as to be the same or a combination of different ones; i is an integer of 1 to 10; n is an integer of 1 to 4; m is an integer of 0 to 4; and h is an integer of 1 to 3.

    摘要翻译： 本文公开了由式[1]表示的新颖的茂金属化合物和制备聚烯烃的方法，包括在包括茂金属化合物的催化体系中使烯烃聚合的步骤。 本发明的茂金属化合物特别可以制备具有高立构规整性和低分子量的聚烯烃，在工业上是非常有价值的：其中R1和R2各自选自烷基，芳基 和含硅烷基; M是选自周期表第IV族的金属; Q是碳或硅; X是卤素，烷基或阴离子配体，它们可以选择为相同或不同的组合; 我是1到10的整数; n为1〜4的整数， m为0〜4的整数。 h为1〜3的整数。