摘要:
Disclosed is an optical material including a cyclic olefin copolymer containing at least a repeating structural unit [A] represented by the general formula (1) and a repeating structural unit [B] represented by the general formula (2) and having a molar ratio [A]/[B] of from 95/5 to 1/99, wherein the absolute value of the ratio ΔOB/ΔF is from 0.001 to 0.250 in which ΔOB represents the amount of a change in the absolute value of the orientation birefringence calculated from the phase difference (nm) at a wavelength of 633 nm/film thickness (μm) in a stretched film obtained from the optical material, and ΔF represents the amount of a change in the absolute value of the orientation coefficient determined from the dichroic ratio of parallel light intensity I∥ to perpendicular light intensity I⊥, each relative to the orientation direction according to Raman spectroscopy.
摘要:
A polymer having a rate of dissolution in an alkaline developer that increases under the action of acid is provided. The polymer is prepared by reacting a hydrogenated ROMP polymer with an O-alkylating agent in the presence of a base.
摘要:
A hydrogenated ring-opening metathesis polymer which contains at least a structural unit [B] of the following general formula [3] and/or a structural unit [C] of the following general formula [4]: wherein, R8 to R11 and R13 to R16 each independently represent a hydrogen atom or a linear, branched or cyclic alkyl group having 1 to 10 carbon atoms, and X2s and X3s are the same or different and represent —O— or —CR122— wherein, R12 represents a hydrogen atom or a linear or branched alkyl group having 1 to 10 carbon atoms). One of Y1 and Y2 represents —(C═O)— and the other of Y1 and Y2 represents —CR182— wherein, R18 represents a hydrogen atom or a linear or branched alkyl group having 1 to 10 carbon atoms and m and n represent an integer of 0 or 1 to 3.
摘要:
A composite oxide catalyst represented by the general formula: Mo-V-P-X-Y (wherein X represents at least one element selected from the group consisting of Sb, Cu, Co, Bi and As; Y represents at least one element selected from the group consisting of K, Rb, Cs and Tl) and a method for preparing methacrylic acid through gas phase catalytic oxidation of methacrolein with molecular oxygen in the presence of the foregoing catalyst are herein disclosed. The catalyst exhibits excellent catalytic activity, selectivity to methacrylic acid, catalytic stability and lifetime.
摘要:
Disclosed is an optical material including a cyclic olefin copolymer containing at least a repeating structural unit [A] represented by the general formula (1) and a repeating structural unit [B] represented by the general formula (2) and having a molar ratio [A]/[B] of from 95/5 to 1/99, wherein the absolute value of the ratio ΔOB/ΔF is from 0.001 to 0.250 in which ΔOB represents the amount of a change in the absolute value of the orientation birefringence calculated from the phase difference (nm) at a wavelength of 633 nm/film thickness (μm) in a stretched film obtained from the optical material, and ΔF represents the amount of a change in the absolute value of the orientation coefficient determined from the dichroic ratio of parallel light intensity I∥ to perpendicular light intensity I⊥, each relative to the orientation direction according to Raman spectroscopy.
摘要:
The present invention is to provide a fluorine-containing polymer having excellent light transmission in the vacuum ultraviolet region of not more than 193 nm, a monomer favorably used for preparing the fluorine-containing polymer, a process for preparing the fluorine-containing polymer, and uses of the fluorine-containing polymer. The fluorine-containing polymer has at least a repeated unit structure represented by the following formula (1) and has an absorption coefficient of not more than 3.0 μm−1 at 157 nm of ultraviolet rays. wherein R1 to R12 are each fluorine, a fluorine-containing alkyl group of 1 to 20 carbon atoms, or the like; X1 is —CRaRb—, —NRa— or —PRa— (Ra and Rb are each fluorine, a fluorine-containing alkyl group of 1 to 20 carbon atoms, hydrogen, —O—, —S—, an alkyl group of 1 to 20 carbon atoms, or the like); at least one of R1 to R12 and X1 is fluorine or a fluorine-containing group; and n is 0 or an integer of 1 to 3.
摘要翻译:本发明提供一种在不大于193nm的真空紫外区域中具有优异透光性的含氟聚合物,有利地用于制备含氟聚合物的单体,制备含氟聚合物的方法,以及 使用含氟聚合物。 含氟聚合物至少具有由下式(1)表示的重复单元结构,并且在157nm处的紫外线具有不大于3.0μm-1的吸收系数。其中R 1至R“ 12>各自为氟,碳原子数1〜20的含氟烷基等; X 1为-CR a R b - , - NR a - 或-PR a - (R 5'和R b各自为氟,含氟烷基为 1〜20个碳原子,氢,-O - , - S-,1〜20个碳原子的烷基等); R 1至R 12和X 1中的至少一个为氟或含氟基团; n为0或1〜3的整数。
摘要:
A polymer having a rate of dissolution in an alkaline developer that increases under the action of acid is provided. The polymer is prepared by reacting a hydrogenated ROMP polymer with an O-alkylating agent in the presence of a base.