公开(公告)号：US08465874B2

公开(公告)日：2013-06-18

申请号：US11398638

申请日：2006-04-06

申请人： Naoto Nishimura ,  Motoaki Nishijima ,  Shinsuke Kobayashi

发明人： Naoto Nishimura ,  Motoaki Nishijima ,  Shinsuke Kobayashi

IPC分类号： H01M4/13 ,  H01M4/58 ,  H01M4/62 ,  H01M4/80

CPC分类号： H01M4/806 ,  H01M4/0404 ,  H01M4/0416 ,  H01M4/0471 ,  H01M4/133 ,  H01M4/364 ,  H01M4/587 ,  H01M4/661 ,  H01M10/052 ,  H01M2004/021 ,  H01M2004/027 ,  Y02T10/7011 ,  Y10T29/49108

摘要： In a lithium-ion secondary battery of the present invention, the electrical resistivity of the mixture of a positive electrode active material, an electrically conductive member, and a binder is 0.1 Ωcm or more but 1 Ωcm or less. The positive and negative electrodes each have an electrical capacity of 10 mAh or more but 50 mAh or less per volume of a rectangular parallelepiped that has a 1 cm2 square base on a face of the electrode of one polarity facing the electrode of the other polarity and that has a height equal to the thickness of the electrode of the one polarity at the square base. Used as the negative electrode thereof is a negative electrode formed by sintering graphite powder, non-graphitizing carbon, and fibrous powder retained in the pores of a porous metal structure in an inert gas atmosphere at a temperature of between 600 and 1000° C.

摘要翻译： 在本发明的锂离子二次电池中，正极活性物质，导电性构件和粘合剂的混合物的电阻率为0.1Ω·cm以上，为1〜1μmacm以下。 正极和负极各自具有10mAh以上但为50mAh以下的电容量，该体积的长方体的面积为与另一极性的电极相对的一极性的电极的表面上具有1cm 2的正方形基底， 其高度等于在正方形基极处的一个极性的电极的厚度。 作为其负极使用的是通过在惰性气体气氛中在600〜1000℃的温度下烧结石墨粉末，非石墨化碳和保留在多孔金属结构的孔中的纤维粉末而形成的负极。

公开(公告)号：US20070003837A1

公开(公告)日：2007-01-04

申请号：US11398638

申请日：2006-04-06

申请人： Naoto Nishimura ,  Motoaki Nishijima ,  Shinsuke Kobayashi

发明人： Naoto Nishimura ,  Motoaki Nishijima ,  Shinsuke Kobayashi

IPC分类号： H01M4/62 ,  H01M4/80 ,  H01M4/04

CPC分类号： H01M4/806 ,  H01M4/0404 ,  H01M4/0416 ,  H01M4/0471 ,  H01M4/133 ,  H01M4/364 ,  H01M4/587 ,  H01M4/661 ,  H01M10/052 ,  H01M2004/021 ,  H01M2004/027 ,  Y02T10/7011 ,  Y10T29/49108

摘要： In a lithium-ion secondary battery of the present invention, the electrical resistivity of the mixture of a positive electrode active material, an electrically conductive member, and a binder is 0.1 Ωcm or more but 1 Ωcm or less. The positive and negative electrodes each have an electrical capacity of 10 mAh or more but 50 mAh or less per volume of a rectangular parallelepiped that has a 1 cm2 square base on a face of the electrode of one polarity facing the electrode of the other polarity and that has a height equal to the thickness of the electrode of the one polarity at the square base. Used as the negative electrode thereof is a negative electrode formed by sintering graphite powder, non-graphitizing carbon, and fibrous powder retained in the pores of a porous metal structure in an inert gas atmosphere at a temperature of between 600 and 1000° C.

摘要翻译： 在本发明的锂离子二次电池中，正极活性物质，导电性构件和粘合剂的混合物的电阻率为0.1Ω·cm以上，为1〜1μmacm以下。 正极和负极各自具有每个体积的一个极性的电极的表面上具有1cm 2·正方形基底的长方体的10mAh以上但50mAh以下的电容 面对另一极性的电极，其高度等于在正方形基极处的一极性的电极的厚度。 作为其负极使用的是通过在惰性气体气氛中在600〜1000℃的温度下烧结石墨粉末，非石墨化碳和保留在多孔金属结构的孔中的纤维粉末而形成的负极。

公开(公告)号：US09293234B2

公开(公告)日：2016-03-22

申请号：US13809551

申请日：2011-06-16

申请人： Motoaki Nishijima ,  Koji Ohira ,  Toshitsugu Sueki ,  Shougo Esaki ,  Isao Tanaka ,  Yukinori Koyama ,  Katsuhisa Tanaka ,  Koji Fujita ,  Shunsuke Murai

发明人： Motoaki Nishijima ,  Koji Ohira ,  Toshitsugu Sueki ,  Shougo Esaki ,  Isao Tanaka ,  Yukinori Koyama ,  Katsuhisa Tanaka ,  Koji Fujita ,  Shunsuke Murai

IPC分类号： H01B1/08 ,  H01M4/00 ,  C01B25/45 ,  C01B33/20 ,  H01M4/485 ,  H01M4/58 ,  H01M4/136 ,  H01M4/36 ,  H01M4/131 ,  H01M4/525 ,  H01M4/62

CPC分类号： H01B1/08 ,  C01B25/45 ,  C01B33/20 ,  H01M4/131 ,  H01M4/136 ,  H01M4/364 ,  H01M4/485 ,  H01M4/525 ,  H01M4/5825 ,  H01M4/625 ,  Y02E60/122

摘要： Provided is a positive electrode active material giving nonaqueous-electrolyte secondary batteries superior in cycle characteristics. The positive electrode active material according to the present invention includes a lithium-containing composite metal oxide having the composition represented by the following General Formula (1): LizFe1-xMxP1-ySiyO4  (1) (wherein M is at least one metal element selected from Zr, Sn, Y, and Al, 0.05 z>0.9 to 0.75 or 0.25 to 0.1>z>0; the positive electrode active material has two crystalline phases of the lithium-containing composite oxides represented by the following General Formulae (2) and (3) when 0.9 to 0.75>z>0.25 to 0.1: LiaFe1-xMxP1-ySiyO4  (2) (wherein 0.75 to 0.9≦a≦1.00, 0.05

摘要翻译： 提供了具有优异的循环特性的非水电解质二次电池的正极活性物质。 根据本发明的正极活性物质包括具有以下通式（1）表示的组成的锂复合金属氧化物：LizFe1-xMxP1-ySiyO4（1）（其中M是选自以下的至少一种金属元素： Zr，Sn，Y和Al，0.05 z> 0.9至0.75或0.25至0.1> z> 0时; 当0.9〜0.75> z> 0.25〜0.1：LiaFe1-xMxP1-ySiyO4（2）（2）时，正极活性物质由以下通式（2）和（3）表示的含锂复合氧化物的两个结晶相 0.75至0.9＆nlE; a＆nlE; 1.00,0.05

公开(公告)号：US20130115514A1

公开(公告)日：2013-05-09

申请号：US13809551

申请日：2011-06-16

申请人： Motoaki Nishijima ,  Koji Ohira ,  Toshitsugu Sueki ,  Shougo Esaki ,  Isao Tanaka ,  Yukinori Koyama ,  Katsuhisa Tanaka ,  Koji Fujita ,  Shunsuke Murai

发明人： Motoaki Nishijima ,  Koji Ohira ,  Toshitsugu Sueki ,  Shougo Esaki ,  Isao Tanaka ,  Yukinori Koyama ,  Katsuhisa Tanaka ,  Koji Fujita ,  Shunsuke Murai

IPC分类号： H01M4/58 ,  H01M4/136 ,  H01M4/36

CPC分类号： H01B1/08 ,  C01B25/45 ,  C01B33/20 ,  H01M4/131 ,  H01M4/136 ,  H01M4/364 ,  H01M4/485 ,  H01M4/525 ,  H01M4/5825 ,  H01M4/625 ,  Y02E60/122

摘要： Provided is a positive electrode active material giving nonaqueous-electrolyte secondary batteries superior in cycle characteristics. The positive electrode active material according to the present invention includes a lithium-containing composite metal oxide having the composition represented by the following General Formula (1): LizFe1-xMxP1-ySiyO4   (1) (wherein M is at least one metal element selected from Zr, Sn, Y, and Al, 0.05 z>0.9 to 0.75 or 0.25 to 0.1>z>0; the positive electrode active material has two crystalline phases of the lithium-containing composite oxides represented by the following General Formulae (2) and (3) when 0.9 to 0.75>z>0.25 to 0.1: LiaFe1-xMxP1-ySiyO4   (2) (wherein 0.75 to 0.9≦a≦1.00, 0.05

摘要翻译： 提供了具有优异的循环特性的非水电解质二次电池的正极活性物质。 根据本发明的正极活性物质包括具有以下通式（1）表示的组成的锂复合金属氧化物：LizFe1-xMxP1-ySiyO4（1）（其中M是选自以下的至少一种金属元素： Zr，Sn，Y和Al，0.05 z> 0.9至0.75或0.25至0.1> z> 0时; 当0.9〜0.75> z> 0.25〜0.1：LiaFe1-xMxP1-ySiyO4（2）（2）时，正极活性物质由以下通式（2）和（3）表示的含锂复合氧化物的两个结晶相 0.75至0.9 @ a @ 1.00,0.05

公开(公告)号：US20120040248A1

公开(公告)日：2012-02-16

申请号：US13265437

申请日：2010-04-26

申请人： Takeshi Yao ,  Shogo Esaki ,  Motoaki Nishijima ,  Mitsuhiro Hibino ,  Kohei Hiroe

发明人： Takeshi Yao ,  Shogo Esaki ,  Motoaki Nishijima ,  Mitsuhiro Hibino ,  Kohei Hiroe

IPC分类号： H01M4/505

CPC分类号： H01M4/505 ,  C01G45/12 ,  C01G45/1242 ,  C01P2002/32 ,  C01P2002/72 ,  C01P2002/74 ,  C01P2002/77 ,  C01P2006/40 ,  H01M4/624 ,  H01M10/052

摘要： A positive active material according to the present invention used in a nonaqueous secondary battery, includes a lithium-containing transition metal oxide containing manganese, as a crystal structure of a main crystalline phase, and a sub oxide and tin (IV) oxide, each of which having an oxygen arrangement identical to that of the lithium-containing transition metal oxide however has a different element composition, the sub oxide and tin (IV) oxide being included in a state in which presence of the sub oxide and tin (IV) oxide is confirmable by diffractometry.

摘要翻译： 在非水二次电池中使用的本发明的正极活性物质包括含有锰的含锂过渡金属氧化物，作为主结晶相的结晶结构，以及副氧化物和氧化锡（IV），各自为 其具有与含锂过渡金属氧化物相同的氧排列，但是具有不同的元素组成，在氧化亚锡和氧化锡（IV））存在的状态下，包含氧化亚锡和氧化锡（IV） 可以通过衍射验证。

公开(公告)号：US09090470B2

公开(公告)日：2015-07-28

申请号：US13416169

申请日：2012-03-09

申请人： Toshitsugu Sueki ,  Motoaki Nishijima

发明人： Toshitsugu Sueki ,  Motoaki Nishijima

IPC分类号： H01M4/04 ,  C01B25/37 ,  H01M4/136 ,  H01M4/1397 ,  H01M4/36 ,  H01M4/505 ,  H01M4/58 ,  H01M4/62 ,  C01B25/45

CPC分类号： C01B25/37 ,  C01B25/45 ,  C01P2002/72 ,  C01P2006/40 ,  H01M4/136 ,  H01M4/1397 ,  H01M4/366 ,  H01M4/505 ,  H01M4/5825 ,  H01M4/625 ,  Y02E60/122

摘要： A method of producing a positive electrode active substance comprising steps of: dissolving a lithium source, an M source, a phosphorus source and an X source in amounts needed to form a lithium-containing composite oxide having an olivine structure and represented by the following general formula (1): LixMyP1−zXzO4  (1) wherein, in the formula, M is at least one kind of element selected from the group of Fe, Ni, Mn, Zr, Sn, Ti, Nb, V, Al and Y; X is at least one kind selected from the group of Si and Al; 0

摘要翻译： 一种制造正极活性物质的方法，包括以下步骤：将形成具有橄榄石结构的含锂复合氧化物所需的量的锂源，M源，磷源和X源溶解，并由以下通式 式（1）：LixMyP1-zXzO4（1）其中，在该式中，M为选自Fe，Ni，Mn，Zr，Sn，Ti，Nb，V，Al和Y中的至少一种元素; X是选自Si和Al中的至少一种; 0

公开(公告)号：US09083046B2

公开(公告)日：2015-07-14

申请号：US13427416

申请日：2012-03-22

申请人： Koji Ohira ,  Motoaki Nishijima

发明人： Koji Ohira ,  Motoaki Nishijima

IPC分类号： H01M4/131 ,  H01M4/58 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  C01B25/45 ,  C01B31/04 ,  H01M10/052

CPC分类号： H01M4/5825 ,  C01B25/45 ,  C01B32/225 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M10/052

摘要： A cathode active material comprising a composition represented by the following general formula (1): LiaM1xM2yM3zPmSinO4  (1) wherein M1 is at least one kind of element selected from the group of Mn, Fe, Co and Ni; M2 is any one kind of element selected from the group of Zr, Sn, Y and Al; M3 is at least one kind of element selected from the group of Zr, Sn, Y, Al, Ti, V and Nb and different from M2; “a” satisfies 0

摘要翻译： 包含由以下通式（1）表示的组合物的正极活性材料：LiaM1xM2yM3zPmSinO4（1）其中M1是选自Mn，Fe，Co和Ni中的至少一种元素; M2是选自Zr，Sn，Y和Al组中的任何一种元素; M3是选自Zr，Sn，Y，Al，Ti，V和Nb中的至少一种元素，不同于M2; “a”满足0

公开(公告)号：US20130209886A1

公开(公告)日：2013-08-15

申请号：US13807967

申请日：2011-06-27

申请人： Koji Ohira ,  Motoaki Nishijima

发明人： Koji Ohira ,  Motoaki Nishijima

IPC分类号： H01M4/505

CPC分类号： H01M4/505 ,  C01B25/37 ,  C01B25/45 ,  H01M4/5825

摘要： A cathode active material having a composition represented by the following formula (1) LiMn1−xMxP1−ySiyO4   (1) wherein M is at least one kind of element selected from the group consisting of Zr, Sn, Y and Al; x is within a range of 0

摘要翻译： 具有由下式（1）表示的组成的正极活性物质LiMn1-xMxP1-ySiyO4（1）其中M是选自Zr，Sn，Y和Al中的至少一种元素; x在0

公开(公告)号：US20120034527A1

公开(公告)日：2012-02-09

申请号：US13198010

申请日：2011-08-04

申请人： Takeshi Yao ,  Shogo Esaki ,  Motoaki Nishijima

发明人： Takeshi Yao ,  Shogo Esaki ,  Motoaki Nishijima

IPC分类号： H01M4/131 ,  H01M4/505

CPC分类号： H01M4/505 ,  C01G19/00 ,  C01G45/1221 ,  C01G45/1242 ,  C01P2002/32 ,  C01P2002/52 ,  C01P2002/85 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/1391 ,  H01M10/052

摘要： A cathode active material of the present invention for use in a nonaqueous secondary battery includes: a main crystalline phase including a lithium-containing transition metal oxide containing manganese and having a spinel structure; and a sub crystalline phase which is in a layer shape and which is contained in the main crystalline phase, the sub crystalline phase being identical in oxygen arrangement to the lithium-containing transition metal oxide and different in elementary composition from the lithium-containing transition metal oxide, the main crystalline phase being in an octahedral shape having a plurality of edges, the plurality of edges including a longest edge having a length of not greater than 300 nm.

摘要翻译： 本发明用于非水二次电池的正极活性物质包括：主结晶相，其包含含锰的含锂过渡金属氧化物并具有尖晶石结构; 和亚结晶相，其为主晶相中包含的亚结晶相，所述亚结晶相的氧排列与含锂过渡金属氧化物相同，并且元素组成与含锂过渡金属不同 氧化物，所述主晶相为具有多个边缘的八面体形状，所述多个边缘包括具有不大于300nm的长度的最长边缘。

公开(公告)号：US20080241672A1

公开(公告)日：2008-10-02

申请号：US12056629

申请日：2008-03-27

申请人： Hisayuki UTSUMI ,  Motoaki Nishijima ,  Shinsuke Kobayashi

发明人： Hisayuki UTSUMI ,  Motoaki Nishijima ,  Shinsuke Kobayashi

IPC分类号： H01M2/02 ,  H01M10/36

CPC分类号： H01M2/0275 ,  H01M2/0267 ,  H01M2/1653 ,  H01M2/361 ,  H01M10/052

摘要： To provide a secondary battery that is capable of shortening injecting time for injecting an electrolytic solution, and infiltrating the electrolytic solution uniformly, during a process for preparing the secondary battery. Also, to provide the secondary battery in which discordance of layers of positive-electrode plates, negative-electrode plates, and separators does not easily occur during a process for laminating them and the following process.A nonaqueous electrolytic solution secondary battery of the present invention comprises: negative-electrode plates which are rectangular; positive-electrode plates which each have a pair of opposed sides shorter than a pair of opposed sides of each negative-electrode plate; separators which each are formed of a porous resin film enclosing each positive-electrode plate; an enclosure which encloses the negative-electrode plates and separators which are laminated alternately, in which a direction of the sides of the negative-electrode plates aligns with a direction of the shorter sides of the positive-electrode plates; and an injection pathway for the nonaqueous electrolytic solution, which the pathway being formed between the negative-electrode plates between which the separator is sandwiched, the pathway being formed at edges of opposed sides of the negative-electrode plates.

摘要翻译： 为了提供二次电池，其能够缩短用于注入电解液的注入时间，并且在制备二次电池的过程中均匀地渗透电解液。 此外，为了提供在层压它们的过程中不容易发生正极板，负极板和隔板的不一致的二次电池和以下过程。 本发明的非水电解液二次电池包括：矩形的负极板; 正极板各自具有比每个负极板的一对相对侧短的一对相对侧; 分离器各自由包围每个正极板的多孔树脂膜形成; 围绕负极板和隔板交替包围的外壳，其中负极板的侧面方向与正极板的短边方向对齐; 以及用于非水电解液的注入通路，该通路形成在负极板之间，该隔离件夹在该负极板之间，该通路形成在负极板的相对侧的边缘处。